• Title/Summary/Keyword: Co(III)/Co(II)

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PROCESS OF COMMUNITY-BASED SUSTAINABLE CO2 MANAGEMENT

  • Jaehyun Park;Taehoon Hong
    • International conference on construction engineering and project management
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    • 2011.02a
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    • pp.262-268
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    • 2011
  • According to the United Nations Framework Convention on Climate Change (UNFCCC), many countries around the world have been concerned with reducing Greenhouse Gas (GHG) emissions. Reducing the level of building energy consumption is particularly important in bringing GHG down. Because of this, many countries including the US and the EU are enforcing energy-related policies. However, these policies are focused on management of single types of buildings such as public buildings and office buildings, instead of management on a national level. Thus, although various policies have been enforced in many countries, CO2 management on a national level is still not an area of focus. Therefore, this study proposed a community-based CO2 management process that allows government-led GHG management. The minimum unit of the community in this study is a plot, and the process consists of three steps. First, the current condition of the GHG emission was identified by plot. Second, based on the identified results, the GHG emission reduction target was distributed per plot by reflecting the weighted value according to (i) the target CO2 reduction in the buildings in the standard year, (ii) region, and (iii) building usage and size. Finally, to achieve the allocated target reduction, building energy management was executed according to the properties of the building located on each plot. It can be expected that the proposed community-based CO2 management process will enable government-level GHG management, through which environment-friendly building construction can be promoted.

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Safety assessment of Generation III nuclear power plant buildings subjected to commercial aircraft crash Part I: FE model establishment and validations

  • Liu, X.;Wu, H.;Qu, Y.G.;Xu, Z.Y.;Sheng, J.H.;Fang, Q.
    • Nuclear Engineering and Technology
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    • v.52 no.2
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    • pp.381-396
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    • 2020
  • Investigations of the commercial aircraft impact effect on nuclear island infrastructures have been drawing extensive attention, and this paper aims to perform the safety assessment of Generation III nuclear power plant (NPP) buildings subjected to typical commercial aircrafts crash. At present Part I, finite element (FE) models establishment and validations for both the aircrafts and NPP buildings are performed. (i) Airbus A320 and A380 aircrafts are selected as the representative medium and large commercial aircrafts, and the corresponding fine FE models including the skin, beam, fuel and etc. are established. By comparing the numerically derived impact force time-histories with the existing published literatures, the rationality of aircrafts models is verified. (ii) Fine FE model of the Chinese Zhejiang Sanao NPP buildings is established, including the detailed structures and reinforcing arrangement of both the containment and auxiliary buildings. (iii) By numerically reproducing the existing 1/7.5 scaled aircraft model impact tests on steel plate reinforced concrete (SC) panels and assessing the impact process and velocity time-history of aircraft model, as well as the damage and the maximum deflection of SC panels, the applicability of the existing three concrete constitutive models (i.e., K&C, Winfrith and CSC) are evaluated and the superiority of Winfrith model for SC panels under deformable missile impact is verified. The present work can provide beneficial reference for the integral aircraft crash analyses and structural damage assessment in the following two parts of this paper.

Transition Metal Complexes Derived From 2-hydroxy-4-(p-tolyldiazenyl)benzylidene)-2-(p-tolylamino)acetohydrazide Synthesis, Structural Characterization, and Biological Activities

  • Alhakimi, Ahmed N.;Shakdofa, Mohamad M.E.;Saeed, S. El-Sayed;Shakdofa, Adel M.E.;Al-Fakeh, Maged S.;Abdu, Ashwaq M.;Alhagri, Ibrahim A.
    • Journal of the Korean Chemical Society
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    • v.65 no.2
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    • pp.93-105
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    • 2021
  • Mononuclear Cu(II), Ni(II), Co(II), Mn(II), Zn(II), Fe(III), Ru(III), and UO2(II) complexes of 2-hydroxy-4-(p-tolyldiazenyl)benzylidene)-2-(p-tolylamino)acetohydrazide (H2L) were prepared by direct method. The ligand and its complexes were isolated in solid state and characterized by analytical techniques such as elemental and thermal analyses, molar conductance, magnetic susceptibility measurements and spectroscopic techniques such as UV-Visible, IR, 1H-NMR and 13C-NMR. The spectral data indicated that the ligand acted as neutral/monobasic bidentate or monobasic/dibasic tridentate ligand bonded to the metal ions through the oxygen atom of ketonic or enolic carbonyl group, azomethine nitrogen atom and deprotonated/protonated phenolic oxygen atom forming either tetragonally distorted octahedral or octahedral. Antimicrobial activities of the ligand and its complexes were evaluated against Escherichia coli, Bacillus subtilis and Aspergillus niger by well diffusion method. The results of antifungal activity showed that the Fe(III) complex (10) exhibited higher antifungal against Aspergillus niger than the other complexes. However, the results of antibacterial activity revealed that Cu(II) complex (4) is the most active against Escherichia coli while the Cu(II) complex (5) and Fe(III) complex (10) exhibited higher antibacterial effect on Bacillus subtilis than the other complexes.

Investigation of Color Mecchanism in Co-Doped Augite Purple for Color Glaze (Co-Doped Augite 보라색 유약의 발색기구)

  • Kwon, Young-Joo;Lee, Byung-Ha
    • Korean Journal of Materials Research
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    • v.23 no.5
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    • pp.271-275
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    • 2013
  • Cobalt (Co) compounds have been used for centuries to impart rich blue color to glass, glazes and ceramics. Cobalt monoxide (CoO), an oxide of Co, is an inorganic compound that has long been used as a coloring agent in the ceramic industry. Unlike other coloring agents, CoO can be used to develop colors other than blue, and several factors such as its concentration in the glaze and firing condition have been suggested as possible mechanisms. For example, CoO produces a typical blue color called "cobalt blue" at very low concentrations such as 1 wt% in both oxidation and reduction firing conditions; a higher concentration of CoO (5 wt%) develops a darker blue color under the same firing conditions. Interestingly, CoO also develops a purple color at high concentrations above 10 wt%. In this study, we examined the applicability and mechanism of a novel purple glaze containing cobalt(II, III) oxide, one of the well characterized cobalt oxides. Experimental results show that an Augite crystal isoform (Augite-Fe/Co) in which Fe was replaced with Co is the main component contributing to the formation of the purple color. Based on these results, we developed a glaze using chemically synthesized Augite-Fe/Co crystal as a color pigment. Purple color glaze was successfully developed by the addition of 6~15 wt% of $Co_3O_4$ to magnesia lime.

A RADIOGRAPHIC STUDY ON THE MANDIBULAR CONDYLE POSITION IN KOREAN MALOCCLUSION (부정교합자의 하악과두 위치에 관한 방사선적 연구)

  • Kang, Jeoung-Hee;Kim, Sang-Cheol
    • The korean journal of orthodontics
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    • v.22 no.1
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    • pp.109-121
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    • 1992
  • Temporomandibular joint is a major structure to play an important role in the function & stability of the occlusion as well as the stomatognathic system. Therefore, the TMJ is the structure that requires the complete analysis for diagnosing and planning treatment of pathologic changes by TMJ dysfunction and malocclusion. So, in this study, to evaluate TMJ situation in Korean malocclusion, based on the previous accomplishments, students of the dental college of Won-Kwang Univ. are surveyed and selected in terms of Angle's classification of malocclusion, whose TMJ radiographs were taken in the centric occlusion and centric relation. In each maiocclusion groups, the mean and standard deviation of anterior, posterior and superior joint space of the right, left and both side in CO & CR are evaluated and also those of the fossa height and the articular eminence angle of the right, left and both sides are evaluated. The obtained results were as follows: 1. In the correlation coefficient between the malocclusion groups, no other items except the posterior joint space of the right side in CR between in class I and class III are significant. 2. In the correlation coefficient between the right and left side, the each joint space in class I malocclusion group and class II malocclusion group are significant. 3. In the change of each joint space during the transmit from CO to CR, there is a tendency of increasing anterior joint space and decreasing posterior, superior joint spaces in class I, II malocclusion and increasing superior joint space and decreasing anterior, posterior joint space in class III malocclusion, which is significant in the correlation coefficient, but not significant in the T-test. 4. In each malocclusion group, the correlation coefficient between the posterior joint space and the superior joint space in C.R is highly significant. 5. The fossa height of class II malocclusion group is lesser than that of class I or class III, which is not significant in T-test. 6. In the correlation coefficient between Rt. and Lt. side in the fossa height, it is not significant in class I and class III group, but significant in class II malocclusion group. 7. The articular eminence angle of class II malocclusion group is larger then that of class I or class III groups, which is fairly significant. 8. In the correlation coefficient between Rt. and Lt. side in the articular eminence angle, it is significant in each malocclusion group.

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Acid-Catalyzed Hydrolysis of Hexacyanoferrate (III) to Prussian Blue via Sequential Mechanism

  • Youngjin Jeon
    • Journal of the Korean Chemical Society
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    • v.68 no.3
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    • pp.139-145
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    • 2024
  • This study aims to elucidate the mechanism involved in the hydrolysis of the hexacyanoferrate(III) complex ion (Fe(CN)63-) and the mechanism leading to the formation of Prussian blue (FeIII4[FeII(CN)6]3·xH2O, PB) in acidic aqueous solutions at moderately elevated temperatures. Hydrolysis constitutes a crucial step in generating PB through the widely used single-source or precursor method. Recent PB syntheses predominantly rely on the single-source method, where hexacyanoferrate(II/III) is the exclusive reactant, as opposed to the co-precipitation method employing bare metal ions and hexacyanometalate ions. Despite the widespread adoption of the single-source method, mechanistic exploration remains largely unexplored and speculative. Utilizing UV-vis spectrophotometry, negative-ion mode liquid chromatography-electrospray ionization-mass spectrometry (LC-ESI-MS), and a devised reaction, this study identifies crucial intermediates, including aqueous Fe2+/3+ ions and hydrocyanic acid (HCN) in the solution. These two intermediates eventually combine to form thermodynamically stable PB. The findings presented in this research significantly contribute to understanding the fundamental mechanism underlying the acid-catalyzed hydrolysis of the hexacyanoferrate(III) complex ion and the subsequent formation of PB, as proposed in the sequential mechanism introduced herein. This finding might contribute to the cost-effective synthesis of PB by incorporating diverse metal ions and potassium cyanide.

Styrene Epoxidation over Cobalt Cyclam Immobilized SBA-15 Catalyst

  • Sujandi;Prasetyanto, Eko Adi;Han, Sang-Cheol;Park, Sang-Eon
    • Bulletin of the Korean Chemical Society
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    • v.27 no.9
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    • pp.1381-1385
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    • 2006
  • Cobalt (cyclam) complex has been successfully immobilized onto SBA-15, and proven to be an active catalyst for the epoxidation of styrene with tert-butyl hydroperoxide as a terminal oxidant. The selectivity for styrene oxide was observed to be up to 66% with 40% styrene conversion after 12h reaction time. The reversible redox cycle between Co(III) and Co(II) couple which was supposed to play key role during the epoxidation reaction was supported by a cyclic voltametry analysis. The textural properties of the catalyst was characterized by XRD, N2 adsorption-desorption, and TEM analysis.

Color Stereo Matching Using Dynamic Programming (동적계획법을 이용한 컬러 스테레오 정합)

  • Oh, Jong-Kyu;Lee, Chan-Ho;Kim, Jong-Koo
    • Proceedings of the KIEE Conference
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    • 2000.11d
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    • pp.747-749
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    • 2000
  • In this paper, we proposed color stereo matching algorithm using dynamic programming. The conventional gray stereo matching algorithms show blur at depth discontinuities and non-existence of matching pixel in occlusion lesions. Also it accompanies matching error by lack of matching information in the untextured region. This paper defines new cost function makes up for the problems happening in conventional gray stereo matching algorithm. New cost function contain the following properties. I) Edge points are corresponded to edge points. ii) Non-edge points are corresponded to non-edge points. iii) In case of exiting the amount of edges, the cost function has some weight in proportion to path distance. Proposed algorithm was applied in various images obtained by parallel camera model. As the result, proposed algorithm showed improved performance in the aspect of matching error and processing in the occlusion region compared to conventional gray stereo matching algorithms.

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CoNSIST : Consist of New methodologies on AASIST, leveraging Squeeze-and-Excitation, Positional Encoding, and Re-formulated HS-GAL

  • Jae-Hoon Ha;Joo-Won Mun;Sang-Yup Lee
    • Proceedings of the Korea Information Processing Society Conference
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    • 2024.05a
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    • pp.692-695
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    • 2024
  • With the recent advancements in artificial intelligence (AI), the performance of deep learning-based audio deepfake technology has significantly improved. This technology has been exploited for criminal activities, leading to various cases of victimization. To prevent such illicit outcomes, this paper proposes a deep learning-based audio deepfake detection model. In this study, we propose CoNSIST, an improved audio deepfake detection model, which incorporates three additional components into the graph-based end-to-end model AASIST: (i) Squeeze and Excitation, (ii) Positional Encoding, and (iii) Reformulated HS-GAL, This incorporation is expected to enable more effective feature extraction, elimination of unnecessary operations, and consideration of more diverse information, thereby improving the performance of the original AASIST. The results of multiple experiments indicate that CoNSIST has enhanced the performance of audio deepfake detection compared to existing models.

Chemical Characteristics of Taurine Added Kimchi during Fermentation at Low Temperature (타우린 첨가 김치의 저온 저장 중 화학적 특성)

  • Yim, Seoung-Been;Kim, Mi-Sook;Kim, Eun-Kyung;Ko, Jae-Youn;Jeong, Yoon-Hwa
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.39 no.12
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    • pp.1814-1818
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    • 2010
  • The present study was carried out to elucidate the changes in the chemical characteristics of taurine added Kimchi during fermentation for 46 days at $6^{\circ}C$. Chinese cabbage was brined in a 10% salt solution for the control Kimchi and in a 10% salt solution containing 5% taurine for taurine added Kimchi (Taurine I, II, and III). One and three percent (w/w, based on Chinese cabbage) of taurine were added to make Taurine II and Taurine III, respectively. Reducing sugar and vitamin C contents for all the samples decreased after the 46-day fermentation. Taurine was not detected in the control, and the taurine contents, from the largest to the smallest, during the fermentation period were Taurine III, Taurine II and Taurine I. Amino nitrogen contents in all the samples studied proportionally increased during the 46-day fermentation. It is suggested that taurine does not affect the chemical characteristics of Kimchi during fermentation at low temperature ($6^{\circ}C$).