• 제목/요약/키워드: Cloud Temperature

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Interaction between Poly(L-lysine) and Poly(N-isopropyl acrylamide-co-acrylic acid) in Aqueous Solution

  • Sung, Yong-Kiel;Yoo, Mi-Kyong;Cho, Chong-Su
    • Macromolecular Research
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    • v.8 no.1
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    • pp.26-33
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    • 2000
  • A series of pH/temperature sensitive polymers were synthesized by copolymerizing N-isopro-pyl acrylamide(NIPAAm) and acrylic acid(AAc) . The influence of polyelectrolyte between poly(allyl amine) (PAA) and poly(L-lysine)(PLL) on the lower critical solution temperature(LCST) of pH/temperature sensitive polymer was compared in the range of pH 2∼12. The LCST of PNIPAAm/water in aqueous poly(NIPAAm-co-AAc) solution was determined by cloud point measurements. A polyelectrolyte complex was prepared by mixing poly(NIPAAm-co-AAc) with poly(allyl amine) (PAA) or poly(L-lysine) (PLL) solutions as anionic and cationic polyelectrolytes, respectively. The effect of polyelectrolyte complex formation on the conformation of PLL was studied as a function of temperature by means of circular dichroism(CD). The cloud points of PNIPAAm in the aqueous copolymers solutions were stongly affected by pH, the presence of polyelectrolyte solute, AAc content, and charge density. The polyelectrolyte complex was formed at neutral condition. The influence of more hydrophobic PLL as a polyelectrolyte on the cloud point of PNIPAAm in the aqueous copolymer solution was stronger than that of poly(allyl amine)(PAA). Although polymer-polymer complex was formed between poly(NIPAAm-co-AAc) and PLL, the conformational change of PLL did not occur due to steric hinderance of bulky N-isopropyl groups of PNIPAAm.

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The Impact of Interaction between Cloud and Longwave Radiation on the Asian Monsoon Circulation (구름-장파복사 상호작용이 아시아 몬순에 미치는 영향)

  • Ryu, Geun-Hyeok;Sohn, Byung-Ju
    • Journal of the Korean earth science society
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    • v.30 no.1
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    • pp.58-68
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    • 2009
  • Three-dimensional distributions of longwave radiation flux for the April-September 1998 period are generated from radiative transfer calculations using the GEWEX Asian Monsoon Experiment (GAME) reanalysis temperature and humidity profiles and International Satellite Cloud Climatology Project (ISCCP) cloudiness as inputs to understand the effect of cloud radiative forcing in the monsoon season. By subtracting the heating of the clear atmosphere from the cloudy radiative heating, cloud-induced atmospheric radiative heating has been obtained. Emphasis is placed on the impact of horizontal gradients of the cloud-generated radiative heating on the Asian monsoon. Cloud-induced heating exhibits its maximum heating areas within the Indian Ocean and minimum heating over the Tibetan Plateau, which establishes the north-south oriented differential heating gradient. Considering that the differential heating is a ultimate source generating the atmospheric circulation, the cloud-induced heating gradient established between the Indian Ocean and the Plateau can enhance the strength of the north-south Hadley-type monsoon circulation. Cooling at cloud top and warming at cloud bottom, which are the vertical distributions of cloud-induced heating, can exert on the monsoon circulation by altering the atmospheric stability.

Effect of Additives on the Cloud Point of Polyethylene Glycols

  • Han, Suk-Kyu;Jhun, Byung-Hak
    • Archives of Pharmacal Research
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    • v.7 no.1
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    • pp.1-9
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    • 1984
  • Polyethylene glycol 20, 000 and 6, 000 were found to have an upper consolute temperature, called "cloud point", and the effects of various additives on the polythylene glycols were investigated in this study. Electrolytes lowered the cloud point in proportion to their concentrations through dehydration and electrostriction. It was found that anions played a more important role than cations and the effects of both the cations and the anions clearly followed the classical Hofmeister series. However, the Schultze Hardy rule holds for the effect of anions, and fails for the effect of cations. Salts of large polarizable anions such as iodide and thiocynate rather raised the cloud point, and their effects were ascribed to the fact that they break the water structure and weaken hydrophobic bonding of the polyxyethylene moiety. Nitrates of polyvalent cations also raised the cloud point. This was ascribed to the complex formation between the polyvalent cations and ether oxygens of the polyoxyethylenes. This explained the failure 'of the Schultz-Hardy rule for cations. Uncharged aromatic compounds drastically lowered the clound point, while aliphatic alcohols slightly lowered the cloud point, This result suggests that there might be some interaction between ether oxygens and aromatic nucleus.c nucleus.

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STUDY OF THE MARINE CLOUD STRUCTURE WITH AQUA AMSR-E

  • Shoom, Mariya Yu.
    • Proceedings of the KSRS Conference
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    • v.2
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    • pp.1007-1010
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    • 2006
  • This study investigates the spatial structure of the total cloud liquid water content Q fields over the Northwest Pacific Ocean during winter monsoon. The distributions of Q have been estimated from the brightness temperatures of the ocean - atmosphere system $T_B(f)$, where f is frequency, measured by AQUA AMSR-E in January -March 2003. Marine strati (St) and stratocumuli (Sc) are typical for winter monsoon season. They were analysed using mainly high-frequency channel at f = 36.5 GHz, vertical polarisation. $T_B$ data were accompanied by the data on near surface wind speed, air temperature and humidity from the nearest meteorological stations. Tow one-dimensional spectra were computed for downwind and crosswind sections of Q fields. The AMSR-E antenna field of view (14-8 km) and the cloud field sizes (100-1000 km) restricted the spatial scales. The results of case study Jan 31 2003 are presented. Scale-invariant spectrum is typical. In the cases of extended St levels a spectral slope equals about -1.7, conforming to classical -5/3 of turbulence theory. For Sc cases the absolute magnitude of spectral slope is rather higher, as a rule. The value is about -2. In the case when cloud streets are presented, a strait line form of spectrum is less reliable with a slope being rather lower (about -1.4).

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Comparative Analysis of the Change Tendency between Climatic Elements and Electricity Generation of Building Integrated Photo Voltaic in Winter (동절기 기후 요소와 수직면 건물일체형 태양광발전시스템 발전량의 상관관계 분석)

  • Park, Kang-Hyun;Kim, Su-Min
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.24 no.8
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    • pp.599-604
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    • 2012
  • Most air pollution and smog are a result of the burning of fossil fuels. The use of fossil fuels also causes acid rain and global warming. So the need for solar energy utilization is increased. It is essentially important to make efforts to reduce usage of fossil energy resources. In this study, we analyzed the correlation between climatic elements(Cloud cover, Duration of sunshine, Temperature) and the photovoltaic power generation. Cloud cover of the correlation coefficient was 0.87. And duration of sunshine of the correlation coefficient was 0.93. The order of the correlation coefficient was duration of sunshine, cloud cover, temperature. To accurately analyze of the degree of correlation for the photovoltaic power generation, additional research about climatic elements that show a high correlation is needed.

Convective Cloud RGB Product and Its Application to Tropical Cyclone Analysis Using Geostationary Satellite Observation

  • Kim, Yuha;Hong, Sungwook
    • Journal of the Korean earth science society
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    • v.40 no.4
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    • pp.406-413
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    • 2019
  • Red-Green-Blue (RGB) imagery techniques are useful for both forecasters and public users because they are intuitively understood, have advantageous visualization, and do not lose observational information. This study presents a novel RGB convective cloud product and its application to tropical cyclone analysis using Communication, Oceanography, and Meteorology (COMS) satellite observations. The RGB convective cloud product was developed using the brightness temperature differences between WV ($6.75{\mu}m$) and IR1 ($10.8{\mu}m$), and IR2 ($12.0{\mu}m$) and IR1 ($10.8{\mu}m$) as well as the brightness temperature in the IR1 bands of the COMS, with the threshold values estimated from the Korea Meteorological Administration (KMA) radar observations and the EUMETSAT RGB recipe. To verify the accuracy of the convective cloud RGB product, the product was applied to the center positions analysis of two typhoons in 2013. Thus, the convective cloud RGB product threshold values were estimated for WV-IR1 (-20 K to 15 K), IR1 (210 K to 300 K), and IR1-IR2 (-4 K to 2 K). The product application in typhoon analysis shows relatively low bias and root mean square errors (RMSE)s of 23 and 28 km for DANAS in 2013, and 17 and 22 km for FRANCISCO in 2013, as compared to the best tracks data from the Regional Specialized Meteorological Center (RSMC) in Tokyo. Consequently, our proposed RGB convective cloud product has the advantages of high accuracy and excellent visualization for a variety of meteorological applications.

Future Changes in Surface Radiation and Cloud Amount over East Asia under RCP Scenarios (RCP 시나리오에 따른 미래 동아시아 지표복사에너지와 운량 변화 전망)

  • Lee, Cheol;Boo, Kyung-On;Shim, Sungbo;Byun, Youngwha
    • Journal of Climate Change Research
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    • v.7 no.4
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    • pp.433-442
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    • 2016
  • In this study, we examine future changes in surface radiation associated with cloud amount and aerosol emission over East Asia. Data in this study is HadGEM2-CC (Hadley Centre Global Environmental Model version 2, Carbon Cycle) simulations of the Representative Concentration Pathways (RCPs) 2.6/4.5/8.5. Results show that temperature and precipitation increase with rising of the atmosphere $CO_2$. At the end of $21^{st}$ century (2070~2099) relative to the end of $20^{st}$ century (1981~2005), changes in temperature and precipitation rate are expected to increase by $+1.85^{\circ}C/+6.6%$ for RCP2.6, $+3.09^{\circ}C/+8.5%$ for RCP4.5, $+5.49^{\circ}C/10%$ for RCP8.5. The warming results from increasing Net Down Surface Long Wave Radiation Flux (LW) and Net Down Surface Short Wave Radiation Flux (SW) as well. SW change increases mainly from reduced total Aerosol Optical Depth (AOD) and low-level cloud amount. LW change is associated with increasing of atmospheric $CO_2$ and total cloud amount, since increasing cloud amounts are related to absorb LW radiation and remit the energy toward the surface. The enhancement of precipitation is attributed by increasing of high-level cloud amount. Such climate conditions are favorable for vegetation growth and extension. Expansion of C3 grass and shrub is distinct over East Asia, inducing large latent heat flux increment.

The Characteristics of Air Temperature according to the Location of Automatic Weather System (AWS 설치장소에 따른 기온 특성)

  • Joo, Hyong-Don;Lee, Mi-Ja;Ham, In-Wha
    • Atmosphere
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    • v.15 no.3
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    • pp.179-186
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    • 2005
  • Due to several difficulties, a number of Automatic Weather Systems (AWS) operated by Korea Meteorological Administration (KMA) are located on the rooftop so that the forming of standard observation environment to obtain the accuracy is needed. Therefore, the air temperature of AWSs on the synthetic lawn and the concrete of the rooftop is compared with the standard observation temperature. The hourly mean temperature is obtained by monthly and hourly mean value and the difference of temperature is calculated according to the location, the weather phenomenon, and cloud amount. The maximum and the minimum temperatures are compared by the conditions, such as cloud amount, the existence of precipitation or not. Consequently, the temperature on the synthetic lawn is higher than it on the concrete so that it is difficult to obtain same effect from ASOS, on the contrary the installation of AWS on the synthetic lawn seem to be inadequate due to heat or cold source of the building.

Phase Behavior of Ternary Mixture of Poly(ethylene-co-octene) - Ethylene - 1-Octene (Poly(ethylene-co-octene) - Ethylene - 1-Octene 3성분계 혼합물의 상거동)

  • Lee, Sang-Ho;Sohn, Jin-Eun;Chung, Sung-Yoon;Han, Sang-Hoon
    • Elastomers and Composites
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    • v.41 no.2
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    • pp.116-124
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    • 2006
  • Cloud-point data to $160^{\circ}C$ and 1,000 bar are presented with poly(ethylene-co-15.3 mole% octene) copolymers ($PEO_{15}$) in pure 1-octene and mixtures of ethylene - 1-octene. The cloud-point curves for $PEO_{15}$ - ethylene - 1-octene mixture dramatically increase in pressure to as high as 1,000 bar with an increasing ethylene concentration. At ethylene concentrations less than 18 wt%, the ternary mixture has bubble- and cloud-point curves. As the ethylene concentration of the ternary mixture increases, the bubble-point curve and the single-phase region reduce. The reduction in the single phase region with increasing ethylene concentrations is the result of reduced dispersion interactions between $PEO_{15}$ and the mixed solvent. The single-phase region decreases with increasing temperatures when ethylene concentrations are lower than 36 wt%, whereas the single-phase region increases with temperatures at ethylene concentrations greater than 50 wt%. At ethylene concentrations greater than 50 wt% the effect of the polar interactions of the mixed solvent, which is unfavorable to dissolve PEO, is greater than the effect of the density of the mixed solvent. Therefore, the cloud-point pressures increase with a decreasing temperature. However, at ethylene concentrations less than 50 wt%, the cloud-point pressures decrease with temperature, because the effect of the polar interactions is less than the density effect.