• Title/Summary/Keyword: Cleaning Technology

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중금속 오염 토양 복원 및 바이오메스 생산량 증대를 위한 biosolid 활용 (Utilization of Biosolid for Enhanced Heavy Metal Removal and Biomass Production in Contaminated Soils)

  • 김권래;;김정규
    • 한국토양비료학회지
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    • 제43권5호
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    • pp.558-564
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    • 2010
  • Cleaning up the landfill soil by phytoremediation in association with biomass production and utilization of biosolid as a soil amendment will be an attractive green technology. In order to examine this integrated green technology, in the current study of pot trial, heavy metal removal rate and biomass production were determined following cultivation of three different plant species in the landfill soil incorporated with biosolid at two different levels (25 ton $ha^{-1}$ and 50 ton $ha^{-1}$). Among the three plant species including Indian mustard (Brassica juncea), giant sunflower (Helianthus giganteus. L), and giant cane (Arundo donax. L), sunflower appeared to produce the largest biomass yield (19.2 ton $ha^{-1}$) and the produced amounts were magnificently increased with biosolid treatment compared to the control (no biosoild treatment). The increased production associated with biosolid treatment was common for other plant species and this was attributed to the biosolid originated nutrients as well as the improved soil physical properties due to the organic matter from biosolid. The elevated heavy metals in soil which was originated from the incorporated biosolid were Cu and Zn. Based on the phytoavailable amount of heavy metals from biosolid, the removed amount by plant shoots were 95% and 165% for Cu and Zn, respectively, when sunflower was grown. This indicated that mitigation of heavy metal accumulation in soils achieved by the removal of metal through sunflower cultivation enables the successive treatment of biosolid to soils. Moreover, sunflower showed heavy metal stabilization ability in the rhizosphere resulting in alleviation of metal release to ground water.

Evaluation of the Feasibility of Phytoremediation of Soils Contaminated with Cd, Pb and Zn using Sunflower, Corn and Castor plants

  • Chae, Mi Jin;Jung, Goo-Bok;Kang, Seong Soo;Kong, Myung Suk;Kim, Yoo Hak;Lee, Deog Bae
    • 한국토양비료학회지
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    • 제47권6호
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    • pp.491-495
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    • 2014
  • Phytoremediation is a technology using plants and associated soil microbes to reduce the concentrations or toxic effects of contaminants in the environments. It is regarded as a cost-effective, efficient, eco-friendly, and solar-driven technology with good public acceptance. This study was conducted to find the plants accumulating heavy metals in soils contaminated with Cd and Pb. Experimental plots (plot size: $0.81m^2$) was artificially contaminated using a contaminated soil collected from a field in vicinity of Wondong mine (WD). Sunflower, corn and castor were tested for their potential to remove heavy metals from the contaminated soils. The results indicated that sunflower was most effective in accumulating heavy metals and thus remedying the soils among the three crops. Dry weight and heavy metal uptake of sunflower shoot differed with growth period. For example, the Cd content of shoots including leaf and stem were 0.31mg, 2.23 mg, and 0.96 mg per plot at 4, 8 and 12 weeks after planting in Cd4-WD treatment; in addition, the dry weight of the shoots in Cd8-WD treatment was reduced due to heavy metal toxicity. This experiment showed that sunflower absorbed Cd, Pb and Zn in their shoots up to 8 weeks of planting; thereafter heavy metals uptake was diminished. This implies that the efficiency of these plants in cleaning the contaminated soils may be high at the early stage of plant growth.

기능성 나노코팅 박막의 열처리 분위기에 따른 특성분석 및 오염방지 태양광 모듈제작 (Characteristic Analysis of Functional Nano-coating Films Synthesized according to the Annealing Ambient and Fabrication of Anti-pollution PV Module)

  • 강현일;신승권;김형철;임윤식;유영식;정연호;김정현;최원석
    • 전기학회논문지P
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    • 제64권3호
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    • pp.182-186
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    • 2015
  • We investigated that effects of annealing ambient on the characteristics of functional nano thin film synthesized on glass substrate. The functional nano thin films were annealed by using rapid thermal annealing (RTA) equipment in vacuum, oxygen and nitrogen ambient, respectively. The hardness of the functional nano thin films were measured by a standard hardness testing method (ASTM D3363) such as a H-9H, F, HB and B-6B pencil (Mitsubishi, Japan). Also, the adhesion of the functional nano thin films were measured by a standard adhesion testing method (ASTM D3359) using scotch tape (3M, Korea). The contact angle of the functional nano thin films was measured by a contact angle analyzer (Phoenix 300 Touch, S.E.O.). The optical property of functional nano thin films was measured via UV-visible spectroscopy (S-3100, Scinco).

건축용 막구조 제품의 실리콘 기능성 코팅에 관한 연구 (A study on the functional coatings using silicone resin of Architectural membrane structures products)

  • 최윤성;이장훈;윤남식;김수홍;유구근
    • 한국염색가공학회:학술대회논문집
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    • 한국염색가공학회 2012년도 제46차 학술발표회
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    • pp.106-106
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    • 2012
  • 막구조(Membrane structure)란 건축분야에서 "fabric structure" 또는 tension structure"와 같이 사용되는 용어로 코팅된 직물(coated fabrics)을 주재료로 사용하는 구조를 말한다. 특히 구조체로서 연성의 막을 이용 이것에 초기 장력을 주어 강성을 늘림으로서 외부하중에 대하여 안정된 형태를 유지하는 장점을 갖고 있다. 초기 창안된 독일의 온화한 기후에 적용되는 반면 한국이나 일본에는 60m/sec를 넘나드는 태풍의 피해와 많은 적설량을 보이는 기후적 제약으로 발달되지 못하였다. 그러나 최근 새로운 소재의 막구조 제품 개발과 구조해석 방법 및 시공기술 등이 개발되어 보편화되어지고 있는 실정이다. 막구조용 재료로 사용되는 섬유소재는 주로 Polyester직물을 기재로 한 PVC 코팅 제품으로 일반 PVC 막재는 장력이 약하고, 광선에 의한 물성이 쉽게 변화되어 내구연한이 5~15년에 불과하다. 유리섬유나 아라미드섬유 등으로 제직한 기재에 고내열 실리콘이나 PTFE 수지를 코팅한 제품은 약품에 대한 내구성이 높고 자외선에 대해서는 매우 큰 저항성을 가지기 때문에 내구연한이 10년에서 30년 까지도 향상된다. 그러나 실리콘 코팅막은 세계적으로 가장 좋은 막재로 알려졌으나 자정능력(Self Cleaning)에 문제가 발생되어 사용량이 감소 추세라고 할 수 있다. 일반적인 코팅 가공의 경우 MEK, Toluene, DMF 등과 같은 유기용제를 다량 사용함에 따라 작업환경 및 대기오염, 화재 위험 등의 문제점이 있으며 특히 가공시 잔류되는 유기용제의 심각성이 대두되고 있는 상황이다. 이와 같이 코팅 가공제 자체를 친환경적인 물질로 대체하여 각종 환경규제에 대응하고 유해 폐기물의 발생을 줄일 수 있는 코팅 가공제 및 가공기술 개발이 절실하다. 이에 본 연구에서는 Glass-Fiber, Aramid 등의 슈퍼 섬유와 고 강력 섬유 등을 이용하여 PTFE 코팅제품과 비슷한 수준의 성능을 부여하는 무용제형 실리콘 코팅 수지를 개발하고 내구성능 향상, Self Cleaning성, 난연성, 자외선 차단, 인장강도 및 인열 강도의 향상 등 다양한 기능성을 부여하는 최적의 환경 친화적 코팅 공정 기술을 개발하여 차세대 건축용 막구조 제품을 개발하고자 한다.

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폐 RHDM 촉매의 재생 후 워시코팅에 의한 NOx 저감 효율 (The Efficiency of NOx Reduction by Regeneration and Wash Coating of Spent RHDM Catalyst)

  • 나우진;박해경
    • 한국응용과학기술학회지
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    • 제35권3호
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    • pp.876-885
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    • 2018
  • 폐 RHDM(Residue Hydrodemetallation) 촉매상에 침적된 비활성화 성분인 탄소, 황 을 고온배소 처리하여 제거한 후, 과량 침적되어 있는 바나듐은 초음파 교반기에서 5~15wt% 옥살산 수용액을 이용하여 $50^{\circ}C$, 5분 조건하에 바나듐 추출량을 조절함으로써 NOx 저감을 위한SCR(Selective Catalytic Reduction) 촉매로의 적용 가능성을 확인하고자 하였다. 폐촉매와 단계별 처리된 RHDM 촉매를 대상으로 상압반응기상에서 NOx 저감 효율을 측정하였고, 촉매의 성분분석은 ICP, C & S analyzer 및 XRF를 이용하여 분석하였다. 10wt% 옥살산 수용액으로 바나듐을 침출한 촉매가 가장 안정적이었으며 높은 NOx 저감 효율을 보였다. 이를 메탈폼 형태의 지지체에 워시코팅한 촉매는 상용 SCR 촉매와 동등 수준의 NOx 저감 효율을 나타내었다. 따라서 폐 RHDM 촉매의 처리 조건 조정에 관한 후속 연구를 통하여 각 적용처에 적합한 SCR 촉매로의 이용 가능성은 충분할 것으로 사료된다.

A Study on Etching of $UO_2$, Co, and Mo Surface with R.F. Plasma Using $CF_4\;and\;O_2$

  • Kim Yong-Soo;Seo Yong-Dae
    • Nuclear Engineering and Technology
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    • 제35권6호
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    • pp.507-514
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    • 2003
  • Recently dry decontamination/surface-cleaning technology using plasma etching has been focused in the nuclear industry. In this study, the applicability of this new dry processing technique are experimentally investigated by examining the etching reaction of $UO_2$, Co, and Mo in r.f. plasma with the etchant gas of $CF_4/O_2$ mixture. $UO_2$ is chosen as a representing material for uranium and TRU (TRans-Uranic) compounds while metallic Co and Mo are selected because they are the principal contaminants in the used metallic nuclear components such as valves and pipes made of stainless steel or inconel. Results show that in all cases maximum etching rate is achieved when the mole fraction of $UO_2\;in\;CF_4/O_2$ mixture gas is $20\%$, regardless of temperature and r.f. power. In case of $UO_2$, the highest etching reaction rate is greater than 1000 monolayers/min. at $370^{\circ}C$ under 150 W r.f. power which is equivalent to $0.4{\mu}m/min$. As for Co, etching reaction begins to take place significantly when the temperature exceeds $350^{\circ}C$. Maximum etching rate achieved at $380^{\circ}C\;is\;0.06{\mu}m/min$. Mo etching reaction takes place vigorously even at relatively low temperature and the reaction rate increases drastically with increasing temperature. Highest etching rate at $380^{\circ}C\;is\;1.9{\mu}m/min$. According to OES (Optical Emission Spectroscopy) and AES (Auger Electron Spectroscopy) analysis, primary reaction seems to be a fluorination reaction, but carbonyl compound formation reaction may assist the dominant reaction, especially in case of Co and Mo. Through this basic study, the feasibility and the applicability of plasma decontamination technique are demonstrated.

이온빔 스퍼터링법에 의한 다층막의 표면특성변화 (The surface propery change of multi-layer thin film on ceramic substrate by ion beam sputtering)

  • 이찬영;이재상
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 추계학술대회 논문집 Vol.21
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    • pp.259-259
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    • 2008
  • The LTCC (Low Temperature Co-fired Ceramic) technology meets the requirements for high quality microelectronic devices and microsystems application due to a very good electrical and mechanical properties, high reliability and stability as well as possibility of making integrated three dimensional microstructures. The wet process, which has been applied to the etching of the metallic thin film on the ceramic substrate, has multi process steps such as lithography and development and uses very toxic chemicals arising the environmental problems. The other side, Plasma technology like ion beam sputtering is clean process including surface cleaning and treatment, sputtering and etching of semiconductor devices, and environmental cleanup. In this study, metallic multilayer pattern was fabricated by the ion beam etching of Ti/Pd/Cu without the lithography. In the experiment, Alumina and LTCC were used as the substrate and Ti/Pd/Cu metallic multilayer was deposited by the DC-magnetron sputtering system. After the formation of Cu/Ni/Au multilayer pattern made by the photolithography and electroplating process, the Ti/Pd/Cu multilayer was dry-etched by using the low energy-high current ion-beam etching process. Because the electroplated Au layer was the masking barrier of the etching of Ti/Pd/Cu multilayer, the additional lithography was not necessary for the etching process. Xenon ion beam which having the high sputtering yield was irradiated and was used with various ion energy and current. The metallic pattern after the etching was optically examined and analyzed. The rate and phenomenon of the etching on each metallic layer were investigated with the diverse process condition such as ion-beam acceleration energy, current density, and etching time.

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다중재료 광조형장치 개발 (Development of a Multi-material Stereolithography System)

  • 김호찬;최재원
    • 한국정밀공학회지
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    • 제27권3호
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    • pp.135-141
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    • 2010
  • Researchers continue to explore possibilities for expanding additive manufacturing (AM) technologies into direct product manufacturing. One limitation is in the materials available for use in AM that can meet the needs of end-use applications. Stereolithography (SL) is an AM technology well known for its precision and high quality surface finish capabilities. SL builds parts by selectively crosslinking or solidifying photo-curable liquid resins, and the resin industry has been continuously developing new resins with improved performance characteristics. This paper introduces a unique SL machine that can fabricate parts out of multiple SL materials. The technology is based on using multiple vats positioned on a rotating vat carousel that contain different photo-curable materials. To change the material during the process, the build platform is raised out of the current vat, a new vat with a different material is rotated under the platform, and the platform is submerged into the new vat so that the new material can be used. This paper introduces a new vat exchange mechanism, cleaning process, recoating process, resin leveling mechanism and process planning technologies for the implementation of multiple material SL. An overview of the system framework is provided and the system integration and control software is described. In addition, several multiple material test parts are designed, fabricated, and described.

물통합형 정삼투 시스템을 이용한 파일럿 스케일 담수 공정 모사 (Pilot-Scale Simulation of Desalination Process Using Water Integrated Forward Osmosis System)

  • 김봉철;홍승관;최준석
    • 한국물환경학회지
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    • 제33권4호
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    • pp.403-408
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    • 2017
  • In these days, wastewater reclamation and seawater desalination play essential role in addressing the challenge of worldwide water scarcity. Particularly, reverse osmosis (RO) for seawater desalination process is commonly used due to less energy consumption than conventional thermodynamic systems. However, membrane fouling and electrical energy consumption during operation of RO system for seawater desalination haver continued to be a obstruction to its application. In this study, therefore, wastewater secondary effluent is used for osmotic dilution of seawater. Firstly, fouling behaviour of RO by simulating wastewater effluent in osmotic dilution process was measured and we calculated energy consumption of overall desalination process by theoretical equations and commercial program. Our results reveal that RO membrane fouling can be efficiently controlled by pre-treatment systems such as nano filtration (NF) or forward osmosis (FO) process. Especially FO system for osmotic dilution process is a non-pressurized membrane system and, therefore, the operating energy consumption of overall desalination system was the lowest. Moreover, fouling layer on FO membrane is comparatively weak and reversible enough to be disrupted by physical cleaning. Thus, RO system with low salinity feed water through FO process is possible as a less energy consuming desalination system with efficient membrane fouling control.

Estimation of Completeness of Cancer Registration for Patients Referred to Shiraz Selected Centers through a Two Source Capture Re-capture Method, 2009 Data

  • Sharifian, Roxana;SedaghatNia, Mohammad Hossein;Nematolahi, Mohtram;Zare, Najaf;Barzegari, Saeed
    • Asian Pacific Journal of Cancer Prevention
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    • 제16권13호
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    • pp.5549-5556
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    • 2015
  • Background: Cancer has important social consequences with cancer registration as the basis of moving towards prevention. The present study aimed to estimate the completeness of registration of the ten most common cancers in patients referred to selected hospitals in Shiraz, Iran by using capture-recapture method. Materials and Methods: This cross-sectional analytical study was performed in 2014 based on the data of 2009, on a total of 4,388 registered cancer patients. After cleaning data from two sources, using capture-recapture common findings were identified. Then, the percentage of the completeness of cancer registration was estimated using Chapman and Chao methods. Finally, the effects of demographic and treatment variables on the completeness of cancer registration were investigated. Results: The results showed that the percentages of completeness of cancer registration in the selected hospitals of Shiraz were 58.6% and 58.4%, and influenced by different variables. The age group between 40-49 years old was the highest represented and for the age group under 20 years old was the lowest for cancer registration. Breast cancer had the highest registration level and after that, thyroid and lung cancers, while colorectal cancer had the lowest registration level. Conclusions: According to the results, the number of cancers registered was very few and it seems that factors like inadequate knowledge of some doctors, imprecise diagnosis about the types of cancer, incorrectly filled out medical documents, and lack of sufficient accuracy in recording data on the computer cause errors and defects in cancer registration. This suggests a necessity to educate and teach doctors and other medical workers about the methods of documenting information related to cancer and also conduct additional measures to improve the cancer registration system.