• Journal of The Geomorphological Association of Korea
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• v.18 no.1
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• pp.57-71
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• 2011

Granitic regolith profile in Goseong, southern Korea, reveals various types of corestones from unweathered round fresh rocks to decomposed rock cores with unweathered spheroidal rock-layers on outer surface, deep weathering profile with 10m in depth, and red saprolite usually cited as related to high temperature climatic environment. In respect of this optical features such as the depth and the color of the profile, Goseong granitic profile may be regarded as products of paleoclimate with more high temperature and humidity than the present. But it is revealed that halloysite is a predominant clay mineral in upper part as well as lower part by XRD analysis. Halloysite is dominant mineral in hydrothermal alteration milieu. The leaching rate of chemical components is up to 97%, very high compared to common granite profiles with 60~70% in Korean peninsula. So, it is assumed that granitic red regolith in Goseong is a product of hydrothermal alteration, not meteoric weathering.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.21 no.4
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• pp.246-258
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• 1988

Semi-quantitative analysis of $less-than-2{\mu}m$ clay minerals in thirty-nine superficial sediments from the Chinju Bay, southern coast of Korea, was made to reveal the distribution, provenance and dispersal pattern of fine-grained sediments. Additional nine samples were also taken from the Choryang Cheon (a river draining the kaolin-rich Hadong area) to investigate the influence of river a discharge. Grain size analysis for the Chinju Bay sediment samples was performed simultaneously as an aid to understand the sediment types and depositional environments. Except for the northeastern part, clayey mud predominates the entire bay. Average relative abundance of the four major clay minerals, I. I., illite, kaolinite, chlorite and smectite, is $55.1\%,\;23\%,\;21.5\%\;and\;0.4\%$, respectively. Although illite dominant clay mineral, the average content is about $10\~20\%$ tourer than that of the nearby continental shelf area. On the contrary, kaolinite content in the bay is about $10\%$ higher than that of the shelf area. Recent clay minerals of the Chinju Bay are mainly derived from the nearby inland area through numerous rivers and streams. Transport from shelf area, however. also seems to be important.

• Economic and Environmental Geology
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• v.12 no.1
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• pp.41-49
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• 1979

A literature review is made on the physical and chemical characteristics of clay minerals in acidic solutions from the mineralogical and hydrometallurgical viewpoints. Some of the important characteristics of clays are their ability to cation exchange, swelling, and incongruent dissolution in acidic solutions. Various clay minerals can take up metallic ions from solution via cation exchange mechanism. Generally, cation exchange capacity increases in the following order : kaolinite, halloysite, illite, vermiculite, and montmorillonite. In acidic solutions, the cation uptake such as copper by clay minerals is strongly inhibited by hydrogen and aluminum ions and thus is not economically significant factor for recovery of metals such as uranium and copper. In acidic solutions, the cation uptake is substial. Swelling is minimal at lower pH, possibly due to lattice collapse. Swelling may be controllable with montmorillonite type clays by exchanging interlayer sodium with lithium and/or hydroxylated aluminum species. The effect of add on clay minerals are : 1. Division of aggregates into smaller plates with increase in surface area and porosity. 2. Clay-acid reactions occur in the following order: (i) $H^+$ replacement of interlayer cations, (ii) removal of octahedral cations, such as Al, Fe, and Mg, and (iii) removal of tetrahedral Al ions. Acid attack initiates, around the edges of the clay particles and continued inward, leaving hydrated silica gel residue around the edges. 3. Reaction rates of (ii) and (iii) are pseudo-1st order and proportional to acid concentration. Rate doubles for every temperature increment of $10^{\circ}C$. Implications in in-situ leaching of copper or uranium with acid are : 1. Over the life span of the operation for a year or more, clays attacked by acid will leave silica gel. If such gel covers the surface of valuable mineral surfaces being leached, recovery could be substantially delayed. 2. For a copper deposit containing 0.5% each of clay minerals and recoverable copper, the added cost due to clay-acid reaction is about 1.5c/lb of copper (or 0.93 lbs of $H_2SO_4/1b$ of copper). This acid consumption by clay may be a factor for economic evaluation of in-situ leaching of an oxide copper deposit.

• The Journal of the Petrological Society of Korea
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• v.22 no.2
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• pp.137-151
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• 2013

This study is focused on element behaviors and mineral compositions of the fault rock developed in Yongdang-ri, Yangbuk-myeon, Gyeongju City, Korea, using XRF, ICP, XRD, and EPMA/BSE in order to better understand the chemical variations in fault rocks during the fault activity, with emphasis on dependence of chemical mobility on mineralogy across the fault zone. As one of the main components of the fault rocks, $SiO_2$ shows the highest content which ranges from 61.6 to 71.0%, and $Al_2O_3$ is also high as having the 10.8~15.8% range. Alkali elements such as $Na_2O$ and $K_2O$ are in the range of 0.22~4.63% and 2.02~4.89%, respectively, and $Fe_2O_3$ is 3.80~12.5%, indicating that there are significant variations within the fault rock. Based on the chemical characteristics in the fault rocks, it is evident that the fault gouge zone is depleted in $Na_2O$, $Al_2O_3$, $K_2O$, $SiO_2$, CaO, Ba and Sr, whereas enriched in $Fe_2O_3$, MgO, MnO, Zr, Hf and Rb relative to the fault breccia zone. Such chemical behaviors are closely related to the difference in the mineral compositions between breccia and gouge zones because the breccia zone consists of the rock-forming minerals including quartz and feldspar, whereas the gouge zone consists of abundant clay minerals such as illite and chlorite. The alteration of the primary minerals leading to the formation of the clay minerals in the fault zone was affected by the hydrothermal fluids involved in fault activity. Taking into account the fact that major, trace and rare earth elements were leached out from the precursor minerals, it is assumed that the element mobility was high during the first stage of the fault activity because the fracture zone is interpreted to have acted as a path of hydrothermal fluids. Moving toward the later stage of fault activity, the center of the fracture zone was transformed into the gouge zone during which the permeability in the fault zone gradually decreased with the formation of clay minerals. Consequently, elements were effectively constrained in the gouge zone mostly filled with authigenic minerals including clay minerals, characterized by the low element mobility.

• Economic and Environmental Geology
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• v.25 no.4
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• pp.397-416
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• 1992

In the present study, three clay deposits, named the Seongsan, Ogmaesan and Haenam deposits, were investigated. The altered zones are recognized in the hydrothermally altered rocks of the clay deposits from the center of the alteration to the margin: Kaolin, Kaolin-Quartz, Quartz, Sericite and Chlorite zones in the Seongsan deposits; Quartz zone, Alunite zone, Kaolin zone, Sericite zone and Chlorite zone in the Ogmaesan deposits; Quartz zone, Pyrophyllite zone, Sericite zone and Chlorite zone in the Haenam deposits. These zones can be grouped into two types of alteration: Acidic alteration such as Pyrophyllite zone, Alunite zone, Quartz zone, Kaolin zone, Kaolin-Quartz zone and a part of Sericite zone; Propylitic alteration such as Chlorite zone and a part of Sericite zone. All clay deposits belong to high-sulfidation (acid-sulfate) system. The rocks of the acidic alterations are composed of pyrophyllite, alunite, kaolin minerals, sericite, quartz and pyrite. On the basis of bulk chemical compositions, it was found that some components such as $SiO_2$, $TiO_2$, $Fe_2O_3$, FeO, MgO, CaO, $K_2O$ and $Na_2O$ were mobilized considerably from the original rocks. The mobility of these major elements is related to, and controls, mineral assemblages in each altered zone. Polytypes of sericite are determined as $2M_1$ and 1M by X-ray diffraction method. The amount of $2M_1$ is nearly equal to that of 1M in the Seongsan deposits whereas $2M_1$ is less and higher than that of 1M in the Ogmaesan and the Haenam deposits. These facts indicate that formation temperature of sericite is relatively high in the Haenam deposits, moderate in the Seongsan deposits, and low in the Ogmaesan deposits. The ratios of Na/(K+Na) for alunite in the Ogmaesan deposits determined by electron microprobe analyzer (EPMA) are higher than those in the Seongsan deposits. Thus, the alunite of the Ogmaesan deposits must have been formed from the solutions with relatively high aqueous Na/(K+Na) ratios and low pH at a high temperature rather than that of the Seongsan deposits. From all data, it is clarified that alunite is hypogene in origin, and has been formed by oxidation of hydrogen sulfide in the steam-heated environment, and that alunite has been produced by the spectacular solfataric alteration observed at the surface of some present-day hydrothermal systems.

• Korean Journal of Soil Science and Fertilizer
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• v.43 no.2
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• pp.217-223
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• 2010

This study was conducted to reclassify Dongsong series based on the second edition of Soil Taxonomy and to discuss the formation of Dongsong series distributed on the lava plain at Cheolweon in Korea. Morphological properties of typifying pedon of Dongsong series were investigated, and physico-chemical properties were analyzed according to Soil Survey Laboratory Methods Manual. The typifying pedon of Dongsong series has brown (7.5YR 4/2) silty clay loam Ap horizon (0-16 cm), brown (7.5YR 4/2) silty clay loam BA horizon (16-22 cm), brown (7.5YR 4/2) silty clay Bt1 horizon (22-50 cm), reddish brown (5YR 5/4) silty clay Bt2 horizon (50-92 cm), and brown (7.5YR 4/3) silty clay loam Bt3 horizon (92-120 cm). It occurs on lava plain derived from baslt materials. The typifying pedon has higher bulk density than 0.90 Mg $m^{-3}$. That can not be classified as Andisol. But it has an argillic horizon from a depth of 22 to more than 120 cm, and a base saturation (sum of cations) of less than 35% at 125 cm below the upper boundary of the argillic horizon. It can be classified as Ultisol, not as Andisol or Alfisol. It has aquic conditions for some time in normal years in one or more horizons within 50 cm of the mineral soil surface, redoximorphic features between a depth of 25 cm, and a depth of 40 cm from the mineral soil surface, and redox concentrations, and 50%or more redox depletions with chroma of 2 or less in the matrix within the upper 12.5 cm of the argillic horizon. Therefore it can be classified as Aquult. It has episaturation, and keys out as Epiaquult. It has 50% or more chroma of 3 or more in one or more horizons between a depth of 25 cm from the mineral soil surface, and a depth of 75 cm. It can be classified as Aeric Aquult. Dongsong series have 35%or more clay at the particle-size control section, and have mesic soil temperature regime. Therefore they can be classified as fine, mesic family of Aeric Epiaquults, not as fine, mesic family of Typic Epiaqualfs. The Quarternary volcanic activities occurred in Jeju Island, Ulrung Island, Baekryeong Island, Cheolweon area, and Mt. Paekdu et al. in the Korean Penninsula. Most of them belong to the central eruption type, but Cheolweon area may be of the fissure eruption type. Dongsong series occur on Cheolweon lava plains derived from basaltic materials. Most soils distributed in Jeju Island, and derived from mainly pyroclastics are developed as Andisols. But Dongsong series distributed in Cheolweon lava plains which have a relatively dry climate and derived from basaltic materials are developed as Ultisols.

• Economic and Environmental Geology
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• v.48 no.4
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• pp.325-335
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• 2015

This study examined the possibility to extract potential alteration zones and lithologic information based on ASTER band ratio techniques for mineralized area located in ${\ddot{O}}v{\ddot{o}}rkhangai$ province, Mongolia, and the effectiveness of remote sensing as a preliminary exploration tool for mineral exploration was tested. The results of ABRLO, PBRLO, and PrBRLO models indicated that the detection of argillic zone requires the verification of the samples to verify hydrothermal alteration minerals as clay minerals can formed by weathering process, whereas phyllic-propylitic zones were considerably related to the spatial distribution of the intrusive bodies, geological structures, and ore distribution. QI and MI results showed that QI is more useful for sedimentary rocks such as conglomerate and sandstone than meta-sedimentary like quartzite, and MI faced relatively uncertain in detection of felsic or mafic silicate rocks. QI and MI may require additional geologic information such as the characteristics of samples and geological survey data to improve extraction of lithologic information, and, if so, it is expected that remote sensing technique would contribute significantly as a preliminary geological survey method.

• The Korean Journal of Quaternary Research
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• v.17 no.2
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• pp.167-168
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• 2003

The Upo wetland, the largest natural wetland in Korea, is located in Changnyeong-gun, Gyeongsannam Province ($35^{\circ}33'$ N, $128^{\circ}25'$ E), and 70 km upstream from the Nakdong River estuary. Unlike most other Korean wetlands that have been destroyed under the name of economic development, the Upo wetland has been able to preserve its precious ecosystem throughout the years. Thanks to increased public awareness about natural wetlands and environmental conservation, the Korean Ministry of Environment designated the Upo wetland an 'Ecological Conservation Area' on July 26th, 1997. On March 2nd of the following year, the Upo wetland (8.54 $\textrm{km}^2$) was designated a 'Protected Wetland' in accordance with the international Ramsar Treaty. A 4.49m long (from 9.73 to 5.24 m in altitude) UP-1 core ($35^{\circ}33'05"N$, $128^{\circ}25'17"E$), recovered in the marginal part of the Upo wetland, is divided into eight buried paleosol units of different ages on the basis of the abundance of color mottles and vertical color variations (Aslan et al., 1998). Radiocarbon datings suggested that the paleosol profile represent the last 5700 years. The entire section of the core was more or less subjected to pedogenetic processes, and shows very weak to moderate soil profile development. These Holocene paleosols are therefore regarded as synsedimentary soils of deluvium (deposits formed by floods) origin (Sycheva et al., 2003). Unit 1 to 5 paleosols are generally silt-rich and exhibit moderate profile development. The boundaries between the units are somewhat distinguishable, but not so clear cut. This is due to variable repeated combination of accumulation, denudation and soil forming processes within various periods. Mottle textures gradually decrease in abundance with increasing clay content in Unit 6, which results in weak profile development. The lower boundary of Unit 6 lies around about 2000 yrBP, the beginning of Subatlantic in Korea (Kim et al., 2001). Abrupt sediment textural change is detected in Unit 7, which is interpreted to indicate the human activities on the Upo wetland. Unit 8 represents the recent soil forming processes. The preliminary results of this ongoing study imply the primary factor for pedogenetic processes is the water table fluctuations related to the sedimentary textures like grain size distributions, and the geomorphological stability of the Upo wetland.o wetland.

• Journal of the Mineralogical Society of Korea
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• v.21 no.4
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• pp.383-395
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• 2008

To enhance the grade and recovery rate of the gold/silver ores which yield at Philippine Mankayan mine, we studied the characteristics which are the geologic and mineralogical features of gold and silver ore, the liberation by crushing and grinding, the separation by sieving and shaking table. Gold/silver ore is composed of the sulfide minerals like pyrite, sphalerite, galena; and the gangue minerals which is quartz, clay. Gold/silver element are mainly contained in a sulfide minerals like pyrite, sphalerite and galena. To increase the liberation rate of sulfide minerals containing gold/silver element, the gold/silver ore has to be grounded under $100{\mu}m$ very finely because the crystal size of sulfide minerals is distributed from $1{\mu}m$ to $100{\mu}m$. The liberation rate of gold/silver ore increases to 92% when the particle size ($d_{90}$) of ore is grounded below $100{\mu}m$ by jaw crusher $\to$ cone crusher $\to$ rod mill by steps. The grade and recovery of sulfide minerals could not be enhanced by sieving separation because those crystal size is distributed homogeneously below $100{\mu}m$. But, when we separated the sieved ore using shaking table, the gold and silver grade increased to 40 ppm and 140 ppm, respectively. Then the recovery rate of gold reach almost 100% but that of silver is no more that 50%.

• Geophysics and Geophysical Exploration
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• v.5 no.1
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• pp.56-63
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• 2002

Tracing the history of study, problems of seawater intrusion are commonly investigated with electrical techniques because seawater saturated zone is indicative of the low resistivity anomaly. There we, however, silt and mud layers in the western and southern coastal areas of Korea, so we may make a mistake in case we determine seawater intrusion only with resistivity survey. Hence, reference IP survey was carried out in Kimje, Jeollabuk-Do and Youngkwang, Jeollanam-Do in order to decide whether or not the area is under the influence of seawater intrusion. With the use of a electric field cable to minimize EM coupling, we obtained more accurate results by appling reference If technique measuring simultaneously wavelet of current as well as potential. With the aid of reference IP technique, it is possible that we can exactly evaluate seawater intrusion by discriminating seawater saturated area (no IP effect) from very highly conductive layer composed of clay mineral (high IP effect).