• Title/Summary/Keyword: Clay source

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Fabrication of Biodegradable Nanocomposite Using Microwave Melted Intercalation Method (마이크로파 용융삽입법을 이용한 생분해성 나노복합체의 제조)

  • Ha, Won Jo;Sin, Jun Sik;Song, Seung Uk;Kim, Jun Ho;Son, Se Mo;Park, Seong Su
    • Journal of Environmental Science International
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    • v.13 no.4
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    • pp.429-434
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    • 2004
  • The purpose of this study was to investigate the possibility of application of microwave energy for the fabrication of polymer/clay nanocomposite. APES/Clay nanocomposites were prepared at 13$0^{\circ}C$ for 30min with various content of clay by melt-intercalation method under classical and microwave heating source. APES/Clay samples were characterized by the means of X-ray diffractometry(XRD), thermal gravimetric analysis(TGA), and rheometric dynamic analysis(RDA). It was found that intercalated or exfoliated state was obtained in the samples according to the condition of organic modification, clay content, and heating source.

Variation of Rare Earth Element Patterns during Rock Weathering and Ceramic Processes: A Preliminary Study for Application in Soil Chemistry and Archaeology (암석의 풍화과정 및 도자기 제조과정에 따른 희토류원소 분포도의 변화: 토양화학 및 고고학적 응용을 위한 기초연구)

  • Lee, Seung-Gu;Kim, Kun-Han;Kim, Jin-Kwan
    • The Journal of the Petrological Society of Korea
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    • v.17 no.3
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    • pp.133-143
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    • 2008
  • On the basis of chemical composition of granite, gneiss and their weathering products, in this paper, rare earth elements (REEs) was estimated as tracer for clarifying a geochemical variance of earth surface material during weathering process. The chemical composition of clay, clay ware and pottery also were measured for testifying usefulness of REE geochemistry in clarifying the source material of pottery. It was observed that there was no systematic variation of chemical composition among source rock, weathered rock and soil during weathering process. The chemical composition of clay, clay ware and pottery also did not show systematic variation by baking pottery. However, PAAS (Post Archean Australian Shale)-normalized REE patterns of rock-weathered rock-soil and clay-clay ware-pottery are similar regardless of weathering process or ceramic art. Our results confirm that REE geochemistry is powerful tool for clarifying the source materials of surface sediment or archaeological ceramic products.

Clay Minerals of the Bottom Sediments on the Northwestern Continental Shelf in the East China Sea

  • Park, Yong-Ahn;Khim, Boo-Keun;Nam, Jung-Man;Youn, Jeung-Su
    • Journal of the Korean earth science society
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    • v.25 no.1
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    • pp.1-9
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    • 2004
  • The clay minerals of thirty-four bottom sediments collected from the northwestern continental shelf of the East China Sea have been determined by X-ray diffraction analysis. The clay mineral distribution is mainly controlled by the sediment source and the dominant circulation pattern. The predominant clay mineral in our study area is illite comprising more-than 70% of whole clay fraction. The highest concentration of illite (>72%) is found in the southeastern offshore parts beyond the reach of terrigenous input from the Cheju Island. It means that these illites are largely transported by the Kuroshio Current from the South China Sea. Smectite is highly concentrated in the northwest middle part and in the outer-shelf mud patch. It seems to be due to the high supply of smectite transported from China where the fine-grained sediments are discharged from the modern and ancient Huanghe River. The relatively high abundance of kaolinite is likely derived from the Changjiang River via Taiwan ·Warm Current. In contrast, the large amounts of chlorite and high chlorite/kaolinite ratios occur in the northwestern are, reflecting the transportation by the Huanghai Sea Coastal Current from the southern Yellow Sea.

Feasibility of clay-shielding material for low-energy photons (Gamma/X)

  • Tajudin, S.M.;Sabri, A.H.A.;Abdul Aziz, M.Z.;Olukotun, S.F.;Ojo, B.M.;Fasasi, M.K.
    • Nuclear Engineering and Technology
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    • v.51 no.6
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    • pp.1633-1637
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    • 2019
  • While considering the photon attenuation coefficient (${\mu}$) and its related parameters for photons shielding, it is necessary to account for its transmitted and reflected photons energy spectra and dose contribution. Monte Carlo simulation was used to study the efficiency of clay ($1.99g\;cm^{-3}$) as a shielding material below 150 keV photon. Am-241 gamma source and an X-ray of 150 kVp were calculated. The calculated value of ${\mu}$ for Am-241 is higher within 5.61% compared to theoretical value for a single-energy photon. The calculated half-value layer (HVL) is 0.9335 cm, which is lower than that of ordinary concrete for X-ray of 150 kVp. A thickness of 2 cm clay was adequate to attenuate 90% and 85% of the incident photons from Am-241 and X-ray of 150 kVp, respectively. The same thickness of 2 cm could shield the gamma source dose rate of Am-241 (1 MBq) down to $0.0528{\mu}Sv/hr$. For X-ray of 150 kVp, photons below 60 keV were significantly decreased with 2 cm clay and a dose rate reduction by ~80%. The contribution of reflected photons and dose from the clay is negligible for both sources.

A Study on the Characteristics of Heat Energy Distribution of Fire-Proof Clay with Microwave Heating Drying (MICROWAVE 가열 건조에 의한 내화 점토의 열에너지 분포 특성 연구)

  • Lee, S.J.;Kim, Y.J.
    • Proceedings of the KSME Conference
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    • 2001.11b
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    • pp.752-757
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    • 2001
  • The characteristics of heat energy distribution on the fire-proof clay with microwave heating drying are numerically investigated using finite element method. The modelled regular hexahedron chamber$(50cm\times50cm\times50cm)$ filled with air consists of vertical heat source and sink walls, a fire-proof clay model, and adiabatic plates on the top and bottom walls. With different geometrical aspect ratios of the fire-proof clay model, the heat energy distribution is throughly investigated. The model gave a good prediction of the microwave heating characteristics of fire-proof clay. The optimal shape of the fire-proof clay for given chamber geometry and microwave power is analyzed.

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A Study on the Characteristics of Heat transfer of Fire Clay with Microwave Heating (MICROWAVE 가열에 의한 내화 점토의 열전달 특성 연구)

  • Lee, S.J.;Kim, Y.J.;Kim, C.J.;Sung, K.
    • Proceedings of the KSME Conference
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    • 2001.06e
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    • pp.202-206
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    • 2001
  • The characteristics of heat transfer on the fire clay with microwave heating are numerically investigated using finite element method. The modelled regular hexahedron chamber($50cm{\times}50cm{\times}50cm$) filled with air consists of vertical heat source and sink walls, a fire clay model, and adiabatic plates at the top and bottom walls. With different geometrical aspect ratios of the fire clay model, the heat energy distribution is throughly investigated. The optimal shape of the fire clay for given chamber geometry and microwave power is analyzed.

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Preparation of Nanocomposite by Microwave Processing (마이크로파 공정을 이용한 나노복합체의 제조)

  • Kim, Tae-Hoon;Son, Se-Mo;Park, Ji-Hwan;Seo, Geum-Suk;Park, Seong-Soo
    • Journal of the Korean Graphic Arts Communication Society
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    • v.22 no.2
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    • pp.111-122
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    • 2004
  • The purpose of this study was to investigate the possibility of application of microwave energy for the fabrication of polymer/clay nanocomposite. APES/Clay nanocomposites were prepared at $130^{\circ}C$ for 30min with various amount of MMT or OMMT used the melt-intercalation method applied the classical and microwave heating source. APES/Clay samples were characterized by the means of X-ray diffractometry (XRD), transmitted electron microscopy (TEM) differential scanning calorimetry (DSC), and rheometric dynamic analysis (RDA). It was found that intercalated or exfoliated state of the samples could be controlled by the clay type, clay content, and heating type.

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점토로부터 철불순물의 생물학적 제거에 미치는 탄소원의 영향

  • Lee, Eun-Young;Cho, Kyung-Suk;Ryu, Hee-Wook;Bae, Moo
    • Microbiology and Biotechnology Letters
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    • v.25 no.6
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    • pp.552-559
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    • 1997
  • Fe (III) impurities in clay could be microbially removed by inhabitant dissimilatory Fe (III) reducing microorganisms. Insoluble Fe (III) in clay particles was leached out as soluble reductive form, Fe (II). The microorganisms removed from 10 to 45% of the initial Fe (III) when each sugar was supplemented to be in ranges of 1 - 5 % (w/w; sugar/clay). The microorganisms reduced 2.1 - 12.8 mol of Fe (III) per 100 mol of carbon in sugars metabolized when sugars such as glucose, maltose, and sucrose were used as sole carbon source. Bacillus sp. IRB-W and Pseudomonas sp. IRB-Y were isolated from the enrichment culture of the clay. The isolates were considered to participate in metabolizing organic compounds to fermentative intermediates with relatively little Fe (III) reduction at initial Fe (III) reduction process. By the microbial treatment, the whiteness of the clay was increased form 63.20 to 79.64, whereas the redness was obviously decreased form 13.47 to 3.55. This treatment did not cause any unfavorable modifications in mineralogical compositions of the clay.

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Carbon nanotubes formation on clay and fly ash from catalytic thermal decomposition of recycled polypropylene

  • Nur A. Atikah Kamaruddin;Norzilah A. Halif;Siti A. Hussin;Mohd. N. Mazlee
    • Advances in materials Research
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    • v.13 no.3
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    • pp.173-181
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    • 2024
  • Fly ash, plastic waste, and clay are mineral materials and residues commonly found in Malaysia. In this study, these materials were fully utilized as raw materials for synthesizing carbon nanotubes (CNTs). Recycled polypropylene, previously used as a food container, served as a carbon source. Fly ash and clay were explored as potential substrates for CNTs growth. The recycled polypropylene was thermally decomposed at 900 ℃ in an inert environment for 90 minutes. Carbon atoms released during this process were deposited on fly ash and clay substrates, which had been immersed in a ferrocene solution to provide a metal catalyst for CNTs growth. The deposited products were characterized using a Scanning Electron Microscope (SEM) and X-Ray Diffraction (XRD). Morphological analysis revealed that both fly ash and clay were coated with fiber-like structures, confirmed to be CNTs based on a diffraction peak around 26° from the XRD pattern. In conclusion, clay and fly ash demonstrate the potential to be utilized as substrates for CNTs formation.

Refinement of Low-grade Clay using Iron-reducing Bacteria [I] : Comparison of Traditional Ripening and Biotechnological Ripening (철환원세균을 이용한 저품위 점토의 개량[I] : 전통적 수비법과 생물공학적 숙성법의 비교)

  • 류희욱;조경숙;김민주;강석영;최희락
    • KSBB Journal
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    • v.15 no.2
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    • pp.201-207
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    • 2000
  • The traditional ripening method of clay was analyzed. An advanced refining method of clay using enrichment cultures of iron r reducing bacteria was developed. After the traditional ripening, the whiteness of the clay was increased due to removal of | iron impurities by inhabitant dissilmaltien with iron reducing bacteria. Other characteristics of the refined clay such as v viscosity, plasticity, and strength were also improved by iron reducing bacteria. An advanced method of clay refinement with a anaerobic enrichment cultivation of iron reducing bacteria supplemented with an extra carbon source such as glucose was s suggested. When the clay was treated by the advanced method. the refinement time could be reduced to 1/6 of that r required by the traditional method. The physical properties of the refined clay by the advanced method were better than t those of the traditionally refined clay.

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