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Properties of Polymer Light Emitting Diodes Using PFO : MEH-PPV Emission Layer and Hole Blocking Layer (PFO : MEH-PPV 발광층과 정공 차단층을 이용한 고분자 발광다이오드의 특성)

  • Lee, Hak-Min;Gong, Su-Cheol;Shin, Sang-Bae;Park, Hyung-Ho;Jeon, Hyeong-Tag;Chang, Ho-Jung
    • Journal of the Semiconductor & Display Technology
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    • v.7 no.2
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    • pp.49-53
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    • 2008
  • The yellow base polymer light emitting diodes(PLEDs) with double emission and hole blocking layers were prepared to improve the light efficiency. ITO(indium tin oxide) and PEDOT : PSS[poly(3,4-ethylenedioxythiophene) : poly(styrene sulfolnate)] were used as cathode and hole transport materials. The PFO[poly(9,9-dioctylfluorene)] and MEH-PPV[poly(2-methoxy-5(2-ethylhe xoxy)-1,4-phenylenevinyle)] were used as the light emitting host and guest materials, respectively. TPBI[Tpbi1,3,5-tris(N-phenylbenzimidazol-2-yl)benzene] was used as hole blocking layer. To investigate the optimization of device structure, we prepared four kinds of PLED devices with different structures such as single emission layer(PFO : MEH-PPV), two double emission layer(PFO/PFO : MEH-PPV, PFO : MEH-PPV/PFO) and double emission layer with hole blocking layer(PFO/PFO : MEH-PPV/TPBI). The electrical and optical properties of prepared devices were compared. The prepared PLED showed yellow emission color with CIE color coordinates of x = 0.48, y = 0.48 at the applied voltage of 14V. The maximum luminance and current density were found to be about 3920 cd/$m^2$ and 130 mA/$cm^2$ at 14V, respectively for the PLED device with the structure of ITO/PEDOT : PSS/PFO/PFO : MEH-PPV/TPBI/LiF/Al.

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Efficient White Organic Light-emitting Device by utilizing a Blue-emitter Doped with a Red Fluorescent Dopant

  • Lim, Jong-Tae;Ahn, Young-Joo;Kang, Gi-Wook;Lee, Nam-Heon;Lee, Mun-Jae;Kang, Hee-Young;Lee, Chang-Hee;Ko, Young-Wook;Lee, Jin-Ho
    • Journal of Information Display
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    • v.4 no.2
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    • pp.13-18
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    • 2003
  • We synthesized bis (2-methyl-8-quinolinolato)(triphenylsiloxy) aluminum (III) (SAlq), a blue-emitting material having a high luminous efficiency, through a homogeneous-phase reaction. The photoluminescence (PL) and electroluminescence (EL) spectra of SAlq show two peaks at 454 nm and 477 nm. Efficient white light-emitting devices are fabricated by doping SAlq with a red fluorescent dye of 4-dicyanomethylene-2-methyl-6-{2-(2,3,6,7-tetrahydro-1H,5H-benzo[i,j]quinolizin-8yl) vinyl}-4H-pyran (DCM2). The incomplete energy transfer from blue-emitting SAlq to red-emitting DCM2 results in light-emission of both blue and orange colors. Devices with the structure of ITO/TPD (50 nm)/SAlq:DCM2 (30 nm, 0.5 %)/$Alq_3$ (20 nm)/LiF (0.5 nmj/Al show EL peaks at 456 nm and 482 nm originating from SAlq and at 570 nm from DCM2, resulting in the Commission Internationale d'Eclairage (CIE) chromaticity coordinates of (0.32, 0.37). The device exhibits an external quantum efficiency of about 2.3 % and a luminous efficiency of about 2.41m/W at 100 $cd/m^2$. A maximum luminance of about 23,800 $cd/m^2$ is obtained at the bias voltage of 15 V.

A Comparative Study on Discomfort Glare Sensation in Entire Visual Field for Position Index (포지션 인덱스 작성을 위한 상·하부 시야의 불쾌글레어감 비교)

  • Kim, Won-woo;Park, Sung-Ryul;Kim, Jeong Tai
    • KIEAE Journal
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    • v.7 no.6
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    • pp.37-43
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    • 2007
  • Discomfort glare is an important factor influencing appraisal for lighting environment. Unified Glare Rating (UGR) which has been proposed by CIE is one of the formula for evaluating discomfort glare. Position index is an important factor in the UGR formula. Position index was proposed by Guth in 1949. It has been used until present limiting upper visual field. Lower visual field has different sensation of brightness in comparing with upper visual field. Therefore, it is necessary to propose position index about lower visual field. The objective of this study is to investigate the brightness sensation in upper and lower visual field. First, the visual field was measured on the self-made Glare Tester. Second, luminance of the Borderline between Comfort and Discomfort (BCD) was measured on the glare Tester. Circular sources of brightness were located at various angular distances from the line of vision along five meridians, $0^{\circ}$, $45{\circ}$, $90{\circ}$, $-45{\circ}$, $-90{\circ}$. The size of the glare source is 0.0011sr. The luminance of the surrounding field, which extended over the entire visual field, was maintained $34ccd/m^2$. Ten subjects aged from 25 to 29 were participated in the experiment. The results show that the luminance of BCD on the line of vision is $4337cd/m^2$ and the glare sensation of the lower visual field is more sensitive than the upper visual field.

Color stability of bulk-fill and incremental-fill resin-based composites polished with aluminum-oxide impregnated disks

  • Koc-Vural, Uzay;Baltacioglu, Ismail;Altinci, Pinar
    • Restorative Dentistry and Endodontics
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    • v.42 no.2
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    • pp.118-124
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    • 2017
  • Objectives: This study aimed to evaluate the color stability of bulk-fill and nanohybrid resin-based composites polished with 3 different, multistep, aluminum-oxide impregnated finishing and polishing disks. Materials and Methods: Disk-shaped specimens (8 mm in diameter and 4 mm in thickness) were light-cured between two glass slabs using one nanohybid bulk-fill (Tetric EvoCeram, Ivoclar Vivadent), one micro-hybrid bulk-fill (Quixfil, Dentsply), and two nanohybrid incremental-fill (Filtek Ultimate, 3M ESPE; Herculite XRV Ultra, Kerr) resin-based composites, and aged by thermocycling (between $5-55^{\circ}C$, 3,000 cycles). Then, they were divided into subgroups according to the polishing procedure as SwissFlex ($Colt\grave{e}ne/Whaledent$), Optidisc (Kerr), and Praxis TDV (TDV Dental) (n = 12 per subgroup). One surface of each specimen was left unpolished. All specimens were immersed in coffee solution at $37^{\circ}C$. The color differences (${\Delta}E$) were measured after 1 and 7 days of storage using a colorimeter based on CIE Lab system. The data were analyzed by univariate ANOVA, Mann-Whitney U test, and Friedmann tests (${\alpha}=0.05$). Results: Univariate ANOVA detected significant interactions between polishing procedure and composite resin and polishing procedure and storage time (p < 0.05). Significant color changes were detected after 1 day storage in coffee solution (p < 0.05), except Quixfil/Optidisc which was color-stable after 7 days (p > 0.05). Polishing reduced the discoloration resistance of Tetric EvoCeram/SwissFlex, Tetric EvoCeram/Praxis TDV, Quixfil-SwissFlex, and all Herculite XRV Ultra groups after 7 days storage (p < 0.05). Conclusions: Discoloration resistance of bulk-fill resin-based composites can be significantly affected by the polishing procedures.

A Study for Color and Illuminance Control Algorithm of Broadcast LED Lighting (방송용 LED 조명의 광색과 조도 제어 알고리즘에 대한 연구)

  • Shin, Dong-Seok;Park, Chul-Hyung;Park, Chong-Yeun
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.29 no.11
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    • pp.6-17
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    • 2015
  • In this paper, colors of broadcast lightings composed of Red, Green, and Blue LED(Light Emitted Diode) can be linearly and quantitatively controlled in low illuminance. Because LED cannot emit uniform illuminance in low illuminance, the colors of RGB LED are unmixable. Furthermore, the illuminances are nonlinear with the dimming values of the RGB LED due to the nonlinearity of the output illuminance with the current through the LED. This nonlinearity generated errors of the target colors and illuminances. The proposed algorithm set up the target colors, which is expressed by the color coordinates in CIE 1931 color space, and the target illuminances. Then the illuminances of RGB LED were calculated using color mixing theory. The calculated illuminances determined the dimming values of the RGB LED for transmission via DMX512 communication. After the broadcasting lighting received the dimming values of the RGB LED via DMX512 communication,.RGB LED can emit target color and illuminance, and be controlled by calculating the PWM(Pulse Width Modulation) duty ratio of the hybrid LED driver which be considered the nonlinearity for the illuminances of the LED. As a result, the proposed algorithm can linearly and quantitatively control the colors and illuminances in full range of illuminance. Then we verify experimentally that the errors of the emitted color coordination x, y and illuminance are 2.27%, 3.6% and 1.5%, respectively.

Colour Interpolation of Tongue Image in Digital Tongue Image System Blocking Out External Light (디지털 설진 시스템의 색상 보정)

  • Kim, Ji-Hye;Nam, Dong-Hyun
    • The Journal of the Society of Korean Medicine Diagnostics
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    • v.16 no.1
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    • pp.9-18
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    • 2012
  • Objectives The aim of this study is to propose an optimized tongue colour interpolation method to achieve accurate tongue image rendering. Methods We selected 60 colour chips in the chips of DIC color guide selector, and then divided randomly the colour chips into two groups. The colour chips of a group (Gr I) were used for finding the optimized colour correction factor of error and those of the other group (Gr II) were used for verifying the correction factor. We measured colour value of the Gr I colour chips with spectrophotometer, and took the colour chips image with a digital tongue image system (DTIS). We adjusted colour correction factor of error to equal the chip colour from each method. Through that process, we obtained the optimized colour correction factor. To verify the correction factor, we measured colour value of the Gr II colour chips with a spectrophotometer, and took the colour chips image with the DTIS in the two types of colour interpolation mode (auto white balance mode and optimized colour correction factor mode). And then we calculated the CIE-$L^*ab$ colour difference (${\Delta}E$) between colour values measured with the spectrophotometer and those from images taken with the DTIS. Results In auto white balance mode, The mean ${\Delta}E$ between colour values measured with the spectrophotometer and those from images taken with the DTIS was 13.95. On the other hand, in optimized colour correction factor mode, The mean ${\Delta}E$ was 9.55. The correction rate was over 30%. Conclusions In case of interpolating colour of images taken with the DTIS, we suggest that procedure to search the optimized colour correction factor of error should be done first.

Effect of resin thickness on the microhardness and optical properties of bulk-fill resin composites

  • Kim, Eun-Ha;Jung, Kyoung-Hwa;Son, Sung-Ae;Hur, Bock;Kwon, Yong-Hoon;Park, Jeong-Kil
    • Restorative Dentistry and Endodontics
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    • v.40 no.2
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    • pp.128-135
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    • 2015
  • Objectives: This study evaluated the effects of the resin thickness on the microhardness and optical properties of bulk-fill resin composites. Materials and Methods: Four bulk-fill (Venus Bulk Fill, Heraeus Kulzer; SDR, Dentsply Caulk; Tetric N-Ceram Bulk Fill, Ivoclar vivadent; SonicFill, Kerr) and two regular resin composites (Charisma flow, Heraeus Kulzer; Tetric N-Ceram, Ivoclar vivadent) were used. Sixty acrylic cylindrical molds were prepared for each thickness (2, 3 and 4 mm). The molds were divided into six groups for resin composites. The microhardness was measured on the top and bottom surfaces, and the colors were measured using Commission Internationale d'Eclairage (CIE) $L^*a^*b^*$ system. Color differences according to the thickness and translucency parameters and the correlations between the microhardness and translucency parameter were analyzed. The microhardness and color differences were analyzed by ANOVA and Scheffe's post hoc test, and a student t-test, respectively. The level of significance was set to ${\alpha}=0.05$. Results: The microhardness decreased with increasing resin thickness. The bulk-fill resin composites showed a bottom/top hardness ratio of almost 80% or more in 4 mm thick specimens. The highest translucency parameter was observed in Venus Bulk Fill. All resin composites used in this study except for Venus Bulk Fill showed linear correlations between the microhardness and translucency parameter according to the thickness. Conclusions: Within the limitations of this study, the bulk-fill resin composites used in this study can be placed and cured properly in the 4 mm bulk.

White organic light-emitting diodes with various spacers inserted between blue and red emissive layers (Spacer에 따른 백색 유기 전기 발광 소자의 전기적 특성에 관한 연구)

  • Park, Jung-Hyun;Lee, Seok-Jae;Kim, Gu-Young;Seo, Ji-Hyun;Seo, Ji-Hoon;Yoon, Seung-Soo;Lee, Seung-Hee;Kim, Young-Kwan
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.402-403
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    • 2007
  • High-efficiency white organic light-emitting diodes (WOLEDs) were fabricated with two emissive layers and a spacer was sandwiched between two phosphorescent dyes which were, bis(3,5-Difluoro-2-(2-pyridyl)phenyl-(2-carboxypyridyl) iridium III (FIrpic) as the blue emission and bis(5-acetyl-2-phenylpyridinato-N,C2') acetylacetonate $((acppy)_2Ir(acac))$ as the red emission. This spacer effectively prevented a triple-triple energy transfer between the two phosphorescent emissive layers with blue and red emission that was showed a improved lifetime. The white device showed Commission Internationale De L'Eclairage $(CIE_{x,y})$ coordinates of (0.33, 0.42) at $22400\;cd/m^2$, a maximum luminance of $27300\;cd/m^2\;at\;0.388\;mA/cm^2$, and a maximum luminous efficiency of 26.9 cd/A.

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Encapsulation Method of OLED with Organic-Inorganic Protective Thin Films Sealed with Metal Sheet (금속판으로 봉인된 유-무기 보호 박막을 갖는 OLED 봉지 방법)

  • Lim, Su yong;Seo, Jung-Hyun;Ju, Sung-Hoo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.26 no.7
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    • pp.539-544
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    • 2013
  • To study the encapsulation method for heat dissipation of high brightness organic light emitting diode (OLED), red emitting OLED of ITO (150 nm) / 2-TNATA (50 nm) / NPB (30 nm) / $Alq_3$ : 1 vol.% Rubrene (30 nm) / $Alq_3$ (30 nm) / LiF (0.7 nm) / Al (200 nm) structure was fabricated, which on $Alq_3$ (150 nm) / LiF (150 nm) as buffer layer and Al as protective layer was deposited to protect the damage of OLED, and subsequently it was encapsulated using attaching film and metal sheet. The current density, luminance and power efficiency was improved according to thickness of Al protective layer. The emission spectrum and the Commission International de L'Eclairage (CIE) coordinate did not have any effects on encapsulation process using attaching film and metal sheet The lifetime of encapsulated OLED using attaching film and metal sheet was 307 hours in 1,200 nm Al thickness, which was increased according to thickness of Al protective layer, and was improved 7% compared with 287 hours, lifetime of encapsulated OLED using attaching film and flat glass. As a result, it showed the improved current density, luminance, power efficiency and the long lifetime, because the encapsulation method using attaching film and metal sheet could radiate the heat on OLED effectively.

Emission Characteristics of White Organic Light-Emitting Diodes Using Ultra Wide Band-gap Phosphorescent Material (Ultra Wide Band-gap 인광체를 이용한 백색 OLED의 발광 특성)

  • Chun, Hyun-Dong;Na, Hyunseok;Choo, Dong Chul;Kang, Eu-Seok;Yang, Jae-Woong;Ju, Sung-Hoo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.25 no.11
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    • pp.910-915
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    • 2012
  • We studied the emission characteristics of white phosphorescent organic light-emitting diodes (PHOLEDs), which were fabricated using a two-wavelength method. The best blue emitting OLED and red emitting OLED characteristics were obtained at a concentration of 12 vol.% FIrpic and 1 vol.% $Bt_2Ir$(acac) in UGH3, respectively. And the optimum thickness of the total emitting layer was 25 nm. To optimize emission characteristics of white PHOLEDs, white PHOLEDs with red/blue/red, blue/red, red/blue and co-doping emitting layer structures were fabricated using a host-dopant system. In case of white PHOLEDs with co-doping structure, the best efficiency was obtained at a structure UGH3: 12 vol. % FIrpic: 1 vol.% $Bt_2Ir$(acac) (25 nm). The maximum brightness, current efficiency, power efficiency, external quantum efficiency, and CIE (x, y) coordinate were 13,430 $cd/m^2$, 40.5 cd/A, 25.3 lm/W, 17 % and (0.49, 0.47) at 1,000 $cd/m^2$, respectively.