• Title/Summary/Keyword: Chrome(Cr)

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SENSITIVITY TO NICKEL, COBALT, CHROME, & COFFER IN DENIAL ALLOYS (치과 보철물 합금 성분중 니켈, 코발트, 크롬 및 구리에 대한 감작률에 관한 조사 연구)

  • Park Young-Mi;Choi Dae-Gyun;Choi Boo-Byung
    • The Journal of Korean Academy of Prosthodontics
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    • v.30 no.2
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    • pp.155-166
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    • 1992
  • In dentistry, precious metal alloys are, mainly due to economic factors, increasingly displaced by alternatives containing Ni-Cr-Co. There are some reports where hypersensitive reactions to Ni-Cr-Co alloys are presented and discussed. The reactions reported vary from mucosa contact stomatitis to generalized dermatitis without any oral mucosal reaction. The purpose of this study was to investigate the incidence of nickel, chrome, cobalt and copper, and to know whether subjects with positive skin reaction to nickel would also demonstrate adverse intraoral reaction to a non-precious metal nickel. The patch tests were performed in 81 subjects(male 39, female 42) and nickel sulfate 5% aq., potassium bichromate 0.5% at., cobalt chloride 2% aq., & copper sulfate 1% aq., were used for test allergens. And then the intraoral tests were performed in 16 subjects, 8 subjects with positive allergic skin reaction to nickel and 8 subjects with negative allergic skin reaction. A pure metallic nickel plate was attached to the buccal side of the upper second premolar. The results are as follows : 1. The frequency of nickel sensitivity was 9.9% (2 men, 6 women), cobalt was 4.9% (1 man, 3 women), and chrome was 2.5% (2 men) respectively and there was no positive reaction to copper 2. The positive reactions were 8 of 23 (34.8%) with a history of jewelry allergic reactions and 3 of 58 (5.1%) without a history of jewelry allergic reactions. 3. Three of 8 subjects with positive skin reaction. gave reactions to the metal plates.

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Analysis of Dancheong pigments at the Nahanjeon Songkwangsa Temple, Wanju (완주 송광사 나한전 단청안료 분석)

  • Hong, Jong-Ouk;Lee, Jang-jon
    • 보존과학연구
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    • s.34
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    • pp.102-108
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    • 2013
  • The purpose of this investigation is to Dancheong documentary project of Tangible cultural in Jeollabukdo. The colored pigments of Nahanjeon Hall in Songkwangsa Temple analyzed and composition and repair period for each pigments were compared. The result are that blue color is Ultramarine blue($Na_6Al_6Si_6O_{24}S_4$), green color is Yangrok($Cu(C_2H_3O_2)_2{\cdot}3Cu(AsO_2)_3$), orange color is Jangdan($Pb_3O_4$), yellow color is Chrome yellow($PbCrO_4$). It is difficult to distinguishable from coloring period by analysis of pigments of Nahanjeon Hall.

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A Study on the Content of Manganese and Chrome in the Ground Water in Seoul Area (Based on non-water supply area) (서울 일부지역 정호수의 망간, 크롬함량 조사연구 상수시설 미설치지역을 중심으로)

  • 구성회;우세홍;이성호;이부웅
    • Journal of Environmental Health Sciences
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    • v.1 no.1
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    • pp.41-45
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    • 1974
  • A study was carried out to determine the content of Mn and Cr in the ground water in Seoul area, where municipal water supply system was not installed, from Nov. 1 to Nov. 30, 1973. In this study, authors examined the hardness, pH, water temperature and Cl ion to investigate the general conditions of the ground water. For this study, samples were collected from 46 wells which were located in outpart of Seoul city, and Mn and Cr were determined with the Spectronic-20. The following results were obtained: 1) Average value of the ground water conditions of the wells were 13.3$\circ$C in temperature, pH 6.3, hardness 159 ppm and Cl ion 41 ppm. 2) In the manganese concentration, the highest area was Yeongdeungpo-Ku(0.318 ppm), while the lowest area was Sungbuk-Ku(0.065 ppm) and the mean concentration of the whole district was 0.196 ppm. 3) In the chrome concentration, the highest area was Yeongdeungpo-Ku(0.031 ppm), while the lowest area was Dobong-Ku (trace) and the mean concentration of the whole district was 0.012 ppm.

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Preparation and Characterization of the Hydrolyzed Protein from Shaving Scraps of Leather Waste Containing Chromium (피혁폐기물(皮革廢棄物)인 Shaving scraps으로 부터 가수분해(加水分解) 단백질(蛋白質)의 제조(製造) 및 특성(特性))

  • Kim, Won-Ju;Cho, Ju-Sik;Lee, Hong-Jae;Heo, Jong-Soo
    • Journal of the Korea Organic Resources Recycling Association
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    • v.5 no.2
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    • pp.47-56
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    • 1997
  • To examine of possibility protein recycling of shaving scraps contained chrome generated from manufacturing process of leather, the characteristics of hydrolyzed protein that differently treated with MgO as alkaline agent were investigated. In alkaline hydrolysis of saving scraps treated with MgO, MgO had to be treated over 5.0% to maintain over pH 8.0 that is insoluble of chrome. Under the condition of alkaline treated with MgO, the solubility of chrome is low with about 60%. The average molecular weight of hydrolyzed proteins from shaving scraps treated with MgO was about 80~100 KD. The amino acid contents of that were largely collagen proteins such as glycine, alanine and proline, and acidic amino acids such as aspartic acid and glutatamic acid. The contents of Mg, Ca and Na in hydrolyzed protein were too much as liquid fertilizer, and chrome contents was 30~40 ppm that largely decreased in comparing with raw materials (40,000~42,000 ppm).

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A comparative study on wear property of WC-CoCr and WC-CrC-Ni coatingssprayed by HVOF

  • Cho, J.Y.;Joo, Y.K.;Zhang, S.H.;Song, K.O.;Cho, T.Y.;Yoon, J.H.
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2008.11a
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    • pp.153-154
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    • 2008
  • High velocity oxy-fuel (HVOF) thermal spraying coating has been used widely throughout the last 60 years mainly in defense, aerospace, and power plants. Recently this coating technique is considered as a promising candidate for the replacement of the traditional electrolytic hard chrome plating (EHC) which pollutes the environment and causes lung cancer by toxic hexa-valent $Cr^{6+}$. In this study, two kinds of cermet coatings, WC-CoCr and WC-CrC-Ni, are formed by HVOF spraying. The wear properties of coatings are evaluated comparatively by reciprocating sliding wear tests at $25^{\circ}C$, $250^{\circ}C$ and $450^{\circ}C$ respectively. Wear rates show that WC-CoCr coatings have better sliding wear resistance than WC-CrC-Ni coatings regardless of temperature due to more, compact and homogeneously distributed WC particles, less metal content, Co, Cr rich metallic bindermatrix with higher fracture strength and better adhesive strength with WC particles.

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Effect of Primarily Solidified Structure on the Microstructure and the Mechanical Properties of High Cr White Iron (고크롬 백주철의 미세조직과 기계적 특성에 미치는 초기응고 조직의 영향)

  • Jo, Hyun-Wook;Do, Jeong-Hyeon;Jo, Won-Je;Chung, Hyun-Deuk;Lee, Je-Hyun;Jo, Chang-Yong
    • Journal of Korea Foundry Society
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    • v.35 no.6
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    • pp.178-184
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    • 2015
  • Due to excellent abrasion resistance the high-chrome white irons are widely used in mining and mineral industries. Minor variation of carbon content in 28% chrome white iron resulted in difference in primarily solidified microstructure. Sub-eutectic (hypoeutectic) composition led to formation of primarily solidified dendrites. Formation of primarily solidified dendrites which were supersaturated with carbon and chrome also caused precipitation of fine secondary carbides that are different from relatively large plate type $M_7C_3$ carbides in the eutectic structure. Small portion of primarily solidified dendrite expected to contribute significantly to the improvement of abrasion resistance of the white iron because the dendrites provided mechanical support to carbides. The relative fraction of primary dendrite increased with reduction of carbon content from the eutectic composition. The increased fraction of primary dendrite increased hardness value of the white irons.

The Inhibitory Effects of Intestine-oriented Lactobacillus sp. KP-3 on the Accumulation of Heavy Metals in Sprague Dawley rats (Sprague Dawley 쥐에서 장내 유래 Lactobacillus sp. KP-3의 중금속 축적 저해 효과)

  • Kim, Shin Yeon;Kim, Hyun Pyo
    • Journal of Life Science
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    • v.25 no.2
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    • pp.164-173
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    • 2015
  • To investigate the effect of lactic acid bacteria on the heavy metal adsorption from internal organs and blood, lactic acid bacteria were isolated from human feces. Some strains resistant to heavy metals were selected by incubation in agar media containing each of chrome and cadmium salts. Among them, a strain named KP-3 was ultimately chosen due to its higher growth rate in selective broth medium containing the heavy metals at the concentration of 0.01%. The strain was identified as Lactobacillus sp. based on its morphological, cultural and physiological characteristics. For evaluating the ability to prevent accumulation of heavy metals by selected Lactobacillus sp. strain in vivo, Sprague Dawley rats were fed with heavy metal salts (cadmium, chrome and lead) with or without cultured whole cells for 7 days. The amounts of heavy metals accumulated in liver, kidney and blood were analyzed. As a result, chrome was accumulated to kidney mostly, and lead was frequently found in liver and kidney. Experimental group (rats fed with lactic acid bacteria) showed less accumulation of heavy metal than control group (rats fed with saline solution). The inhibition rates of heavy metal accumulation were calculated to 41.8% (Cd), 33.4% (Cr) and 44.2% (Pb). Especially, feeding lactic acid bacteria strongly reduced accumulation of cadmium in blood. The results showed that feeding Lactobacillus sp. KP-3 could prevent the bioaccumulation of heavy metals in the living body.

Machining Characteristics of Nickel-Chrome Alloy according to Changing with Ultra High-Speed RPM (초고속 RPM변화에 따른 니켈-크롬 합금의 밀링가공 특성 평가)

  • Lee, Seung-Jun;Choi, Soo-Chang;Kim, Jin-Geun;Shin, In-Dong;Lee, Deug-Woo;Lee, Jong-Ryul
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.9 no.2
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    • pp.1-5
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    • 2010
  • According to the high demand of hybrid components, the hybrid materials development and processing technology were increased in the industry field. Although hybrid materials have various machining technologies, the research about them has rarely been proceed. This study is to carry out results about design technology of miniaturized high-speed air spindle and machining characteristics of hybrid materials using that. We studied machining characteristics in Nickel-Chrome alloy(Ni-Cr) according to change rotating speed using miniaturized high-speed air spindle. As the following results, the change of surface shape and roughness was investigated as the processing conditions such as rotating speed of miniaturized high-speed air spindle.

a-Si:H Photosensor Using Cr silicide Schottky Contact

  • Hur, Chang-Wu
    • Journal of information and communication convergence engineering
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    • v.4 no.3
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    • pp.105-107
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    • 2006
  • Amorphous silicon is a kind of optical to electric conversion material with current or voltage type after generating a numerous free electron and hole when it is injected by light. It is very effective technology to make schottky diode by bonding thin film to use optical diode. In this paper, we have fabricated optical diode device by forming chrome silicide film through thermal processing with thin film($100{\AA}$) having optimal amorphous silicon. The optimal condition is that we make a thin film by using PECVD(Plasma Enhanced Chemical Vapor Deposition) to improve reliability and characteristics of optical diode. We have obtained high quality diode by using chrome silicide optical diode from dark current and optical current measurement compared to previous method. It makes a simple process and improves a good reliability.

Comparison of the bond strength of ceramics to Co-Cr alloys made by casting and selective laser melting

  • Lawaf, Shirin;Nasermostofi, Shahbaz;Afradeh, Mahtasadat;Azizi, Arash
    • The Journal of Advanced Prosthodontics
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    • v.9 no.1
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    • pp.52-56
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    • 2017
  • PURPOSE. Considering the importance of metal-ceramic bond, the present study aimed to compare the bond strength of ceramics to cobalt-chrome (Co-Cr) alloys made by casting and selective laser melting (SLM). MATERIALS AND METHODS. In this in-vitro experimental study, two sample groups were prepared, with one group comprising of 10 Co-Cr metal frameworks fabricated by SLM method and the other of 10 Co-Cr metal frameworks fabricated by lost wax cast method with the dimensions of $0.5{\times}3{\times}25\;mm$ (following ISO standard 9693). Porcelain with the thickness of 1.1 mm was applied on a $3{\times}8-mm$ central rectangular area of each sample. Afterwards, bond strengths of the samples were assessed with a Universal Testing Machine. Statistical analysis was performed with Kolmogorov-Smirnov test and T-test. RESULTS. Bond strength in the conventionally cast group equaled $74.94{\times}16.06\;MPa$, while in SLM group, it equaled $69.02{\times}5.77\;MPa$. The difference was not statistically significant ($P{\leq}.05$). CONCLUSION. The results indicated that the bond strengths between ceramic and Co-Cr alloys made by casting and SLM methods were not statistically different.