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New Hyperbranched Polyimides and Polyamides: Synthesis, Chain-End Functionalizations, Curing Studies, and Some Physical Properties (새로운 Hyperbranchedpolyimidesandpolyamides: 합성, 말단기 변형, 경화 연구, 그리고 물리적 성질)

  • Baek, Jong-Beom;Chris B. Lyon;Tan, Loon-Seng
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2003.10a
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    • pp.1-2
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    • 2003
  • While aromatic polyimides and polyamides have found widespread use as high performance polymers, the present work addressed the need for organosoluble materials through the use of a hyperbranching scheme. The $AB_2$ monomers were prepared. The $AB_2$ monomers were then polymerized via aromatic fluoride-displacement and Yamazaki reactions to afford the corresponding hydroxyl-terminated hyperbranched polyimides (HT-PAEKI) and amine-terminated hyperbranched polyamides, respectively. HT-FAEKI was then functionalized with allyl and propargyl bromides as well as epichlorohydrin to afford allyl-terminated AT-PAEKI, propargyl-terminated PT-PAEKI, and epoxy (glycidyl)-terminated ET-PAEKI, in that order. All hyperbranched poly(ether-ketone-imide)s were soluble in common organic solvents. AT-PAEKI was blended with a bisphenol-A-based bismaleimide (BFA-BMI) in various weight ratios. Thermal, rheological, and mechanical properties of these blend systems were evaluated. Two characteristic hyperbranched polyamides, which the one has para-electron donating groups to the surface amine groups and the other has para-electron withdrawing groups to the surface amine groups, were selected to compare BMI curing behaviors. The electron rich polymer displayed ordinary Michael addition type exothermic reaction, while electron deficient polymer did display unusual curing behaviors. Based on analytical data, the later system provided the strong evidences to support room temperature curing of BMI by reactive intermediates instead of reactive primary amine groups on the macromolecule surface.

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Environmental Mercury and Its Toxic Effects

  • Rice, Kevin M.;Walker, Ernest M. Jr.;Wu, Miaozong;Gillette, Chris;Blough, Eric R.
    • Journal of Preventive Medicine and Public Health
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    • v.47 no.2
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    • pp.74-83
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    • 2014
  • Mercury exists naturally and as a man-made contaminant. The release of processed mercury can lead to a progressive increase in the amount of atmospheric mercury, which enters the atmospheric-soil-water distribution cycles where it can remain in circulation for years. Mercury poisoning is the result of exposure to mercury or mercury compounds resulting in various toxic effects depend on its chemical form and route of exposure. The major route of human exposure to methylmercury (MeHg) is largely through eating contaminated fish, seafood, and wildlife which have been exposed to mercury through ingestion of contaminated lower organisms. MeHg toxicity is associated with nervous system damage in adults and impaired neurological development in infants and children. Ingested mercury may undergo bioaccumulation leading to progressive increases in body burdens. This review addresses the systemic pathophysiology of individual organ systems associated with mercury poisoning. Mercury has profound cellular, cardiovascular, hematological, pulmonary, renal, immunological, neurological, endocrine, reproductive, and embryonic toxicological effects.

Effects of Muscle and Finishing Diets Containing Distillers Grains with Low Moisture Levels on Fatty Acid Deposition in Two Novel Value-added Beef Cuts

  • Giotto, Francine M.;Fruet, Ana Paula B.;Nornberg, Jose L.;Calkins, Chris R.;de Mello, Amilton S.
    • Food Science of Animal Resources
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    • v.40 no.3
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    • pp.484-494
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    • 2020
  • This study evaluated the effects of muscle and dietary treatments including CORN, dry distillers grains (DDGS), and modified distillers grains (MDGS) on fatty acid (FA) deposition in two novel value-added beef cuts (Petite Tender - M. teres major - TM, and Flat Iron - M. infraspinatus - INF). Crossbred steers were randomly assigned to one of three dietary treatments (CORN, 40% of DDGS with 8%-12% of moisture, and 40% of MDGS with 45%-55% of moisture - DM basis) and fed for 190 days. The TM muscle had higher concentrations of ω6 FAs and polyunsaturated fatty acids (PUFA) when compared to INF. Beef fed CORN showed greater C16:0 and lower C18:0 values when compared to beef fed distillers grains (DGS). Beef fed DDGS had higher concentrations of ω6 FAs when compared to MDGS. Different moisture levels only affected FAs containing 14, 16, and 17 carbons. Different muscles, diets, and moisture levels of DGS affected the deposition of FAs in the lean.

Design of a Feature-based Multi-viewpoint Design Automation System

  • Lee, Kwang-Hoon;McMahon, Chris A.;Lee, Kwan-H.
    • International Journal of CAD/CAM
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    • v.3 no.1_2
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    • pp.67-75
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    • 2003
  • Viewpoint-dependent feature-based modelling in computer-aided design is developed for the purposes of supporting engineering design representation and automation. The approach of this paper uses a combination of a multi-level modelling approach. This has two stages of mapping between models, and the multi-level model approach is implemented in three-level architecture. Top of this level is a feature-based description for each viewpoint, comprising a combination of form features and other features such as loads and constraints for analysis. The middle level is an executable representation of the feature model. The bottom of this multi-level modelling is a evaluation of a feature-based CAD model obtained by executable feature representations defined in the middle level. The mappings involved in the system comprise firstly, mapping between the top level feature representations associated with different viewpoints, for example for the geometric simplification and addition of boundary conditions associated with moving from a design model to an analysis model, and secondly mapping between the top level and the middle level representations in which the feature model is transformed into the executable representation. Because an executable representation is used as the intermediate layer, the low level evaluation can be active. The example will be implemented with an analysis model which is evaluated and for which results are output. This multi-level modelling approach will be investigated within the framework aimed for the design automation with a feature-based model.

Limit states of RC structures with first floor irregularities

  • Favvata, Maria J.;Naoum, Maria C.;Karayannis, Chris G.
    • Structural Engineering and Mechanics
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    • v.47 no.6
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    • pp.791-818
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    • 2013
  • The seismic performance of reinforced concrete (RC) frame structures with irregularities leading to soft first floor is studied using capacity assessment procedures. The soft first story effect is investigated for the cases: (i) slab-column connections without beams at the first floor, (ii) tall first story height and (iii) pilotis type building (open ground story). The effects of the first floor irregularity on the RC frame structure performance stages at global and local level (limit states) are investigated. Assessment based on the Capacity Spectrum Method (ATC-40) and on the Coefficient Method (FEMA 356) is also examined. Results in terms of failure modes, capacity curves, interstory drifts, ductility requirements and infills behaviour are presented. From the results it can be deduced that the global capacity of the structures is decreased due to the considered first floor morphology irregularities in comparison to the capacities of the regular structure. An increase of the demands for interstory drift is observed at the first floor level due to the considered irregularities while the open ground floor structure (pilotis type) led to even higher values of interstory drift demands at the first story. In the cases of tall first story and slab-column connections without beams soft-story mechanisms have also been observed at the first floor. Rotational criteria (EC8-part3) showed that the structure with slab-column connections without beams exhibited the most critical response.

Development of a Unified Research Platform for Plug-In Hybrid Electrical Vehicle Integration Analysis Utilizing the Power Hardware-in-the-Loop Concept

  • Edrington, Chris S.;Vodyakho, Oleg;Hacker, Brian A.
    • Journal of Power Electronics
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    • v.11 no.4
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    • pp.471-478
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    • 2011
  • This paper addresses the establishment of a kVA-range plug-in hybrid electrical vehicle (PHEV) integration test platform and associated issues. Advancements in battery and power electronic technology, hybrid vehicles are becoming increasingly dependent on the electrical energy provided by the batteries. Minimal or no support by the internal combustion engine may result in the vehicle being occasionally unable to recharge the batteries during highly dynamic driving that occurs in urban areas. The inability to sustain its own energy source creates a situation where the vehicle must connect to the electrical grid in order to recharge its batteries. The effects of a large penetration of electric vehicles connected into the grid are still relatively unknown. This paper presents a novel methodology that will be utilized to study the effects of PHEV charging at the sub-transmission level. The proposed test platform utilizes the power hardware-in-the-loop (PHIL) concept in conjunction with high-fidelity PHEV energy system simulation models. The battery, in particular, is simulated utilizing a real-time digital simulator ($RTDS^{TM}$) which generates appropriate control commands to a power electronics-based voltage amplifier that interfaces via a LC-LC-type filter to a power grid. In addition, the PHEV impact is evaluated via another power electronic converter controlled through $dSPACE^{TM}$, a rapid control systems prototyping software.

PHealth Service Deployment Methodology: A Case Study

  • Paggetti, Cristiano;Rugnone, Alberto;Tamburini, Elena;Nugent, Chris
    • Journal of Computing Science and Engineering
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    • v.6 no.1
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    • pp.60-66
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    • 2012
  • It has been proved that information and communication technology (ICT) solutions for personalized health (PHealth) and ambient assisted living (AAL) can support people in their daily life activities. Several solutions have been demonstrated to empower different levels of services through seamless data acquisition and specific users' interaction modalities. Usually services usability and accessibility are handled in the design process and are validated with small users' groups. Moreover, while service design and systems development have been extensively described in literature, service deployment methodologies are not properly addressed and documented. Proper reference guidelines are also missing. The most common methodologies like unified process (UP) or ICONX can cover only the design and the development of PHealth services without a clear description on the following phases such as deployment, service provision and maintenance. These phases present several risks to be taken into account right from the beginning of the implementation of PHealth or AAL services. This paper focuses on the description of a structured methodology to deploy PHealth services and how this process can be supported by integrated software routines and adapting the UP framework in particular the "Transition phase."

Differentially Expressed Genes in Marine Medaka Fish (Oryzias javanicus) Exposed to Cadmium

  • Woo, Seon-Ock;Son, Sung-Hee;Park, Hong-Seog;Vulpe, Chris D.;Ryu, Jae-Chun;Yum, Seung-Shic
    • Molecular & Cellular Toxicology
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    • v.4 no.4
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    • pp.293-299
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    • 2008
  • To screen the differentially expressed genes in cadmuim-exposed marine medaka fish (Oryzias javanicus), a candidate marine test fish for ecological toxicity, the differential display polymerase chain reaction (DD-PCR) was carried out, since the genome-wide gene expression data are not available in this fish species yet. A total of 35 clones were isolated from cadmium-exposed fish and their nucleotide sequences were analyzed. The differentially expressed gene candidates were categorized to response to stimulus (3); ion binding (3); DNA binding (1); protein binding (6); carbohydrate binding (1); metabolic process (4); biological regulation (3); cellular process (2); protein synthesis (2); catalytic activity (2); sense of sight (1); immune (1); neurohormone (1); signaling activity (1); electron carrier activity (1) and others (3). For real-time quantitative RT-PCR, we selected catalase, glucose-6-phosphate dehydrogenase, heat shock protein 70, and metallothionein and confirmed that cadmium exposure enhanced induction of these four genes.

Global Increases in Dissolved Organic Carbon in Rivers and Their Implications

  • Kang, Ho-Jeong;Jang, In-Young;Freeman, Chris
    • Korean Journal of Ecology and Environment
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    • v.43 no.4
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    • pp.453-458
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    • 2010
  • DOC (Dissolved Organic Carbon) is an operational terminology for organic carbon molecules dissolved in natural waters. DOC has been studied by ecologists extensively, because it plays a key role in various ecological functions such as substrates for secondary production and the carbon cycle. DOC also represents a substrate for microbial growth within potable water distribution systems, and can react with disinfectants (e.g., chloride) to form harmful disinfection by-products. In addition, residual DOC may carry with it organically bound toxic heavy metals. DOC in aquatic ecosystems may ultimately be transported to the oceans, or released back to the atmosphere by heterotrophic respiration, which can accelerate global climate change. There is evidence that DOC concentrations in aquatic ecosystems are increasing in many regions of the world including Europe, North America, and even in Korea. Land use changes, elevated temperature, elevated $CO_2$, recovery from acidification, and nitrogen deposition have been proposed as mechanisms for the trend. However, the key driving mechanism is yet to be conclusively determined. We propose that more extensive and longer-term observations, research of chemical properties of DOC, impacts of elevated DOC on environmental issues and interdisciplinary approaches are warranted as future studies to fill the gaps in our knowledge about DOC dynamics.

ASTAS: Architecture for Scalable and Transparent Anycast Services

  • Stevens, Tim;De Leenheer, Marc;Develder, Chris;De Turck, Filip;Dhoedt, Bart;Demeester, Piet
    • Journal of Communications and Networks
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    • v.9 no.4
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    • pp.457-465
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    • 2007
  • Native information provider(IP) anycast suffers from routing scalability issues and the lack of stateful communication support. For this reason, we propose architecture for scalable and transparent anycast services(ASTAS), a proxy-based architecture that provides support for stateful anycast communications, while retaining the transparency offered by native anycast. Dynamic resource assignment for each initiated session guarantees that a connection is established with the most suitable target server, based on network and server conditions. Traffic engineering in the overlay can be realized in an effective way due to the dissemination of aggregated state information in the anycast overlay. To minimize the total deployment cost for ASTAS architectures, we propose optimized proxy placement and path finding heuristics based on look-ahead information gathered in network nodes. Contrary to a regular integer linear program(ILP) formulation, these heuristics allow to optimize proxy placement in large networks. A use case on a European reference network illustrates that lower proxy costs enable proxy deployment closer to the end-users, resulting in a reduced network load.