• Journal of the Korea Institute of Building Construction
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• v.19 no.1
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• pp.31-38
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• 2019

In this study, amine derivatives and ion exchange resins were selected to actively control penetration ions ($SO{_4}^{2-}$, $Cl^-$) as the element technology of repair materials for concrete structures in drainage environments. Ions ($SO{_4}^{2-}$, $Cl^-$) adsorption performance and corrosion resistance of calcium hydroxide solution with amine derivative and ion exchange resin were confirmed by ion chromatography and potentiostat analysis. As a result of the experiment, it was confirmed that the amine derivative is excellent in the adsorption of chlorine ion and the ion exchange resin is excellent in the adsorption of sulfate ion. It has been confirmed that corrosion resistance can be increased by proper combination of two materials in the calcium hydroxide solution containing sulfate ion and chloride ion simulating sewage environment.

• Journal of Adhesion and Interface
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• v.24 no.2
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• pp.69-75
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• 2023

Recently, the application of paint protection films (PPFs) for automobiles having a self-recovery coating layer has been grown up. In this study, we report the evaluation results on the basic physical properties of a poly(vinyl chloride)- based PPF containing poly(urea-urethane) hybrid self-recovery coating layer. Depending on the main chemical composition and the thickness of poly(urea-urethane)-based coating layer for PPF, the self-recovery performance by an optical microscope and the stain resistance through color difference value are measured. To improve the surface properties and show its easy-cleaning effect against the polluted things, silicone-modified polyacrylate is introduced to the self-recovery coating composition. The contact angle of water on the coated surface is confirmed to show its hydrophobic surface. Finally, accelerated weathering test of paint protection film with poly(urea-urethane) hybrid coating layer is performed to check the possibility of discoloration and deformation due to long-term exposure on harsh condition.

• Journal of the Korea Institute of Building Construction
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• v.19 no.5
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• pp.411-419
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• 2019

Underground concrete structures are constructed under a geographical environment called underground and exposed to various environments that promote deterioration. Among them, groundwater promotes deterioration of underground concrete structures due to contaminated water from the ground. In this study, the chemical resistance performance test evaluation of five different receptors for a total of 15-type leakage repair materials of five series was conducted to determine the chemical stability of the leakage repair material used in the crack area. The results show a general increase and decrease in most chemical receptors, but the biggest increase and decrease was shown in acrylic systems, which were found in sodium chloride and sodium hydroxide, and epoxy was found in hydrochloric acid. The cement system is showing a lot of increase and decrease in sodium chloride. It is expected that the results of these studies will be used as a basis for chemical stabilization in the development of new materials.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2005.05a
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• pp.113-117
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• 2005

The ceramic metal resin paints for waterproof and anti corrosion is not long history in development of materials even many actual result. So far, no standard have been given to construction and maintenance method, Quality and property, it is real state that cannot afford to proper quality control in job site or production. This study has been test for the ceramic metal resin paints for water and anti corrosion, as the result, it have proper performance of job site and mechanical performance of compare to other existing. In particular, tensile strength indicates more high about $14.1N/mm^2$ than epoxy resin paints, and in elongation per unit length is more high It is shows having better adhesive strength than epoxy resin paint for crack on the concrete structure. Moreover, The ceramic metal paint for water and corrosion proofing have to have main performance is watertightness and resistance for external impact, chloride ion permeation, drinkable water elution.

• Journal of the Korea Concrete Institute
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• v.14 no.3
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• pp.349-356
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• 2002

This research deals with the properties of fresh and hardened high-performance concrete(HPC) incorporating high-reactivity metakaolin(HRM). The properties of fresh and hardened state concrete were investigated included air content, slump flow, setting time, heat of hydration, compressive strength, resistance to chloride-ion penetration, abrasion and repeated freezing and thawing. The properties of the HRM concrete were also compared with those of the portland cement concrete and silica fume(SF) concrete. The laboratory test results indicate that HRM material can be used as a supplementary cementitious material to produce high-performance concrete.

• Nuclear Engineering and Technology
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• v.54 no.12
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• pp.4474-4480
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• 2022

Deep geological disposal using a multibarrier system is a promising solution for treating high-level radioactive (HLRW) waste. The HLRW canister represents the first barrier for the migration of radionuclides into the biosphere, therefore, the corrosion behavior of canister materials is of significance. In this study, the electrochemical behaviors of SS316L, Ti-Gr.2, Alloy 22, and Cu in naturally aerated KAERI underground research tunnel (KURT) groundwater solutions were examined. The corrosion potential, current, and impedance spectra of the test materials were recorded using electrochemical methods. According to polarization and impedance measurements, Cu exhibits relatively higher corrosion rates and a lower corrosion resistance ability than those exhibited by the other materials in the given groundwater condition. In the anodic dissolution tests, SS316L exposed to the groundwater solution exhibited the most uniform corrosion, as indicated by its surface roughness. This phenomenon could be attributed to the extremely low concentration of chloride ions in KURT groundwater.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.11a
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• pp.697-700
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• 2008

Recently, high strength, flowability, and durability of concrete were required according to increase of large scale and high rise structure. However, cracks occurred easily on the high performance concrete. In this reason, using expansion agent for reducing shrinkage cracks were increased, but it did not consider on durability of high performance concrete. Accordingly, this study1 investigated the resistance of shrinkage and damage form salt by mixing CSA expansion agent on the blast-furnace slag cement and mixed cement for the low heat of hydration by three components. The cases that 8% of expansion agent was mixed and the proportion was OPC were expanded till 43.7 times compared with control concrete. For the resistance to the damage of salt, it was improved when mixing ratio was incresed and the maximum size of coarse aggregate growed bigger. In this study, the resistance to the damage of salt of the cases that 8% of expansion agent was mixed was improved about 16% compared with control concrete.

• Applied Chemistry for Engineering
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• v.28 no.3
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• pp.360-368
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• 2017

In order to investigate the durability of high performance polymer concrete composites, polymer concrete specimens were prepared using the ortho-type unsaturated polyester resin (UPR) and iso-type UPR as a polymer binder and the calcium carbonate and silica fine powder as a filler. The durability of polymer concrete specimens was measured by hot water resistance, chemical resistance, pore analysis and SEM observation. The compressive strength of the specimen using the iso-type UPR was higher than that of using the ortho-type UPR, and the compressive strength of the specimen using the silica fine powder was higher than that of using the calcium carbonate filler. From hot water resistance results, it was found that the specimen using the iso-type UPR was superior to that of using the ortho-type UPR and the specimen using the calcium carbonate filler was superior to that of using the silica fine powder. The compressive strength reduction rate was measured after the chemical resistance test and the sodium hydroxide solution showed the highest reduction rate, followed by sulfuric acid, hydrochloric acid and calcium chloride solutions. When using the alkaline solution of sodium hydroxide, the weight reduction rate of the specimen using calcium carbonate was lower than that of using silica fine powder, while for the acidic solutions of sulfuric acid and hydrochloric acid, the weight reduction rate of the specimen using the silica fine powder was lower than that of using calcium carbonate.

• Advances in concrete construction
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• v.10 no.3
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• pp.237-245
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• 2020

Past research efforts already established geopolymer as an environment-friendly alternative binder system for ordinary Portland cement (OPC) and recycled aggregate is also one of the promising alternative for natural aggregates. In this study, an effort was made to produce eco-friendly mortar mixes using geopolymer as binder and recycled fine aggregate (RFA) partially and study the resistance ability of these mortar mixes against the aggressive environments. To form the geopolymer binder, 70% fly ash, 30% ground granulated blast furnace slag (GGBS) and alkaline solution comprising of sodium silicate solution and 14M sodium hydroxide solution with a ratio of 1.5 were used. The ratio of alkaline liquid to binder (AL/B) was also considered as 0.4 and 0.6. In order to determine the resistance ability against aggressive environmental conditions, acid attack test, sulphate attack test and rapid chloride permeability test were conducted. Change in mass, change in compressive strength of the specimens after the immersion in acid/sulphate solution for a period of 28, 56, 90 and 120 days has been presented and discussed in this study. Results indicated that the incorporation of RFA leads to the reduction in compressive strength. Even though strength reduction was observed, eco-friendly mortar mixes containing geopolymer as binder and RFA as fine aggregate performed better when it was produced with AL/B ratio of 0.6.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2022.04a
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• pp.93-94
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• 2022

The presence of chloride (Cl-) ions in environments causes localized corrosion resulting decrease the durability of the structures. In this study, 5% Mg containing Al alloys (Al-5Mg) wire used vis-à-vis compared its corrosion resistance with pure Al in 3.5wt.% NaCl solution with exposure periods. Initially both wires exhibited identical open circuit potential (OCP) attributed to the presence of native oxide film on the surface but with the exposure periods it shifted towards active direction owing to the dissolution of oxide film. The pure Al continuously shifted the OCP towards active direction while Al-5Mg shows stabilization of OCP after 8 days of exposure. The OCP of Al-5Mg is slightly higher compared to pure Al wire owing to the activeness of Mg. The total impedance of the Al-5Mg alloy is almost three times greater than pure Al with exposure periods in 3.5 wt.% NaCl solution. It might be formation of Al-Mg LDH (layered double hydroxide) thin film onto the surface.