• Title/Summary/Keyword: Chloride removal

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The Effect of Porosity of Seiving Particles on the Romoval Efficiency of Organic Substances via Biofilter in the Fixed Bed

  • Park Young Gyu
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.7 no.1
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    • pp.31-37
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    • 2002
  • This paper was investigated to clarify the possibility of a biodegradation of materials adsorbed on different porous granular-activated carbons (GACs) such as coal-& coconut-based GAC. Total organic carbon, humic substance and ammonia were used to compare their removal efficiencies. The objective of this study is to determine the adsorption capacity of bioregenerated GAC. When raw water reacted with chloride, the yield of THMs increased as a function of the input amount of chloride. The formation of trihalomethanes (THMs) was investigated in water treated with chlorine when humic acid was used as THM precursor. As the input amount of chloride in raw water increased by two or five-fold to remove the $NH_3$, the chloroform of the THMs significantly increased also five or ten-fold. It was found that the chloroform was significantly removed by the treatment of biological activated carbon (BAG) in comparison with the ozone treatment, and the removal efficiency of THMs in coal-typed GAC was $10-30\%$ better than coconut-typed GAC due to the biological degradation on the surface of the activated carbons.

A Study on the Removal of $NO_3-N$ from Groundwater by $FeCl_3$-Coated Activated Carbon (염화철코팅 활성탄을 이용한 지하수 중의 질산성질소 제거를 위한 연구)

  • Cheong Kyung-Hoon;Jung Oh-Jin;Choi Hyung-Il;Park Sang-Il;Park Dae-Hoon
    • Journal of Environmental Health Sciences
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    • v.31 no.2 s.83
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    • pp.165-171
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    • 2005
  • A laboratory experiment was performed to investigate the nitrate removal from groundwater using Iron chloride(III) coated activated carbon (ICCAC). The breakthrough profiles of two ionic species, such as nitrate and sulfate showed that nitrate was selectively exchanged with chloride in ICCAC. The $FeCl_3$-coated activated carbon produced about 26 BV (Bed volume) of throughout when treating groundwater containing about $25\;mg/\iota\;of\;NO_3-N$. The regeneration of ICCAC with 1M KC1 was effective at a flow rate of 4 BV/hr. The ion exchange technology seems to be suitable technology for the treatment of small volumes of groundwater polluted by nitrate.

Effect of Humic Substances on the Simultaneous Removal of Nitrate and Phosphate in a Micellar-Enhanced Ultrafiltration (MEUF) (미셀 한외여과(MEUF)를 이용한 질산성 질소와 인산의 동시제거 시 휴믹산의 영향)

  • 김보경;백기태;김호정;양지원
    • Journal of Soil and Groundwater Environment
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    • v.8 no.3
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    • pp.30-36
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    • 2003
  • The effect of humic acid on the simultaneous removal of nitrate and phosphate was investigated in a micellar-enhanced ultrafiltration (MEUF). At the low molar ratio of cetylpyridinium chloride (CPC) to contaminants, the removal of nitrate was lower to 50% by 100 ppm of humic acid due to the competition for binding on micelles. At the molar ratio higher than 3, however, the removal of nitrate was over 80%. Phosphate was removed over 80% at the molar ratio higher than 1. The CPC and humic acid were rejected over 99 % by UF membrane. The flux did not decrease by 100 ppm of humic acid but rather slightly increased since the humic acid adsorbed on the membrane made the membrane more hydrophilic. As a result, humic acid did not diminish the performance of MEUF in the simultaneous removal of nitrate and phosphate.

Simultaneous removal of dissolved TCE and chromate using micellar-enhanced ultrafiltration

  • 이율리아;김호정;백기태;김보경;양지원
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2003.09a
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    • pp.413-416
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    • 2003
  • Micellar enhanced ultrafiltration(MEUF) is a surfactant-based separtaion technique which can remove dissolved organics or multivalent ions from water. In this study, trichloroethylene(TCE) and chromate were simultaneouly removed using MEUF and cetyltrimethylammoniun chloride (CPC) was used as a surfactant. The removal efficiency of chromate was 99% and that of TCE was more than 80%. The presence of TCE or chromate did not affect removal efficiency of each pollutants because the predominat mechanism of TCE and chromate are different.

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Iron Removal from Neodymium Chloride Solution with Alamine 336 (Alamine 336을 이용한 염화네오디뮴 수용액으로부터 Fe 제거)

  • Eom, Hyoung-Choon;Lee, Jin Young;Kim, Chul-Joo;Sohn, Jung-Soo;Yoon, Ho-Sung
    • Korean Chemical Engineering Research
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    • v.46 no.3
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    • pp.512-515
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    • 2008
  • The removal of iron from neodymium chloride solution was carried out by solvent extraction using Alamine 336 in kerosine. The effect of Alamine 336, hydrochloric acid and chloride ion concentrations on the extraction of Fe were studied. The results showed that Alamine 336 as an extractant for removal of iron was effective and the extraction percentage of iron was increased with increasing hydrochloric acid and chloride ion concentration in aqueous solution. The extraction of 99% of iron is attained at a ratio of A/O = 4 by distilled water. The stripping yield of iron from loaded Alamine 336 decreased with decreasing hydrochloric acid concentration in stripping solution.

A Study on the Elimination of Microcystis sp. using Microbubble (미세기포를 이용한 Microcystis sp. 제거에 관한 연구)

  • Hyung, Sung-Hee;Lee, Kap-Du;Park, Sang-Won
    • Journal of Environmental Science International
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    • v.25 no.3
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    • pp.425-438
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    • 2016
  • This study carried out zeta potential measurements of the Microcystis sp. under various solutions condition and investigated the characteristics of Microcystis sp. through the size control of microbubbles to eliminate algae that causes problems in aquatic ecosystems and human activities. DAF process was adopted and several coagulants were used to remove the Microcystis sp. CCD Camera was used to measure and analyze the size of microbubble, and fluorescent microscope was used to observe the particle, algae species and community. Zeta potential behavior of the algae was analyzed by using ELS-Z. Lab-scale and pilot-scale experiments were conducted to test flotation process. Polyaluminium chloride(PAC) coagulant was used, and the removal efficiency of the algae was assessed through Chlorophyll-a analysis. In the Lab-scale experiment, 2.2 ppm, 11 ppm, 22 ppm, and 44 ppm of polyaluminium chloride was injected to coagulate the algae. The coagulated algae was floated by the microbubble. The microbubbles in the experiments were generated at a air pressure of 450 ~ 550 kPa. The microbubble size was controlled in $36{\mu}m$, $100{\mu}m$, and $200{\mu}m$, respectively by using different diffuser. The results of lab-scale experiments on flotation plant indicated that the average removal rate was about 90% or above for 11 ppm, 22 ppm, and 44 ppm of polyaluminium chloride. On the other hand, in the pilot-scale experiment, the removal efficiency was in the range of 85% to 95% in all dose ranges of polyalumium chloride and aluminium sulfate coagulants.

Treatment of Dye-Processing Wastewater by Chemical Precipitation (화학적 침전공정에 의한 염색가공폐수의 처리)

  • Han, Myung-Ho;Huh, Man-Woo;Kim, Jeong-Mog;Lee, Jin-Sik;Lim, Hak-Sang
    • Textile Coloration and Finishing
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    • v.9 no.6
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    • pp.26-32
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    • 1997
  • In order to remove the pollutants effectively in the dye-processing wastewater by chemical precipitation, coagulation and flocculation test was carried out using several coagulants on various reaction conditions. It was found that the Ferric sulfate was best coagulant for the treatment of mixed dye-processing wastewater. When the Ferric sulfate dosage was 1,100mg/$\ell$, the COD removal rate was very high(50%), and the color was removed very effectively. The COD was decreased relatively well up to 40%, when Alum was dosed as coagulant. But it was difficult to remove the color effectively. Test results about COD removal for the Ferrous sulfate and the Ferric chloride used were mostly same as those of the Alum used. However, the color removal by the Ferrous sulfate was much better than the case of the Alum or the Ferric chloride. It was found that the COD removal was increased and the sludge yield was decreased by pH control before polymer flocculant addition, during the jar test for the Ferrous sulfate and the Ferric sulfate as a coagulant.

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Bisphenol-A Removal in Conventional Water Treatment Systems (정수처리공정에서 bisphenol-A의 제거에 관한 연구)

  • 김혜리;이윤진;박선구;남상호
    • Journal of Environmental Health Sciences
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    • v.30 no.1
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    • pp.59-64
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    • 2004
  • This study was carried out to investigate influencing factors of bisphenol A(BPA) removal characteristic in conventional water treatment systems to be connected with coagulation, sedimentation, filtration and disinfection. The result are summarized as follows; In BPA removal, optimal doses of PAC, alum, ferric chloride were 7.5 mg Al/L, 10.0 mg AI/L, 15.0 mg Fek. PAC was most effective coagulant to remove BPA. In coagulation process, BPA removal efficiency were increased about 2% by adjusting pH of raw water as 6. At temperature rise 1$0^{\circ}C$, BPA removal efficiency were increased 0.94%. but BPA removal efficiency in sand filtration process were under 1 %ie, so that BPA was almost not removed. At free chlorine dose 1, 2 mg/L, the reaction rate constant k in the BPA removal have been calculated to be 0.397, 0.953 min$^{-1}$ . At free chlorine dose 1, 2 mg/1-, degradation reaction of BPA was completed during 10 min and BFA removal efficiencies were 97.66, 99.99% at this time.

Structural behaviour of concrete beam under electrochemical chloride extraction against a chloride-bearing environment

  • Ki Yong Ann;Jiseok Kim;Woongik Hwang
    • Computers and Concrete
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    • v.34 no.1
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    • pp.49-61
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    • 2024
  • The present study concerns a removal of chloride ions and structural behaviour of concrete beam at electrochemical chloride extraction (ECE). The electrochemical properties included 1000 mA/m2 current density for 2, 4 and 8 weeks. It was found that an increase in the duration of ECE resulted in an increase in the extraction rate of chlorides, in the range of 35-85%, irrespective of chloride contamination. In structural behaviour, the strength and maximum bending moment of specimen was always lowered by ECE. Moreover, the flexural rigidity and bending stiffness were reduced by the loss of effective cross-section area in the linear elastic range. Simultaneously, the inertia moment was substantially subjected to 70% loss of the cross-section by the tensile strain at the condition of the failure. However, a lower rate of the inertia moment reduction was achieved by ECE, implying the higher resistance to the cracking, but the higher risk of deformation.