• 한국진공학회:학술대회논문집
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• 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
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• pp.263-263
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• 2013

This work examines the dynamic properties of ice surfaces in vacuum for the temperature range of 140~180 K, which extends over the onset temperatures for ice sublimation and the phase transition from amorphous to crystallization ice. In particular, the study focuses on the transport processes of excess protons and chloride ions in ice and their segregative behavior to the ice surface. These phenomena were studied by conducting experiments with a relatively thick (~100 BL) ice film constructed with a bottom $H_2O$ layer and an upper $D_2O$ layer, with excess hydronium and chloride ions trapped at the $H_2O$/$D_2O$ interface as they were generated by the ionization of hydrogen chloride. The migration of protons, chloride ions, and water molecules to the ice film surface and their H/D exchange reactions were measured as a function of temperature using the methods of low energy sputtering (LES) and Cs+ reactive ion scattering (RIS). Temperature programmed desorption (TPD) experiments monitored the desorption of water and hydrogen chloride from the surface. Our observations indicated that both hydronium and chloride ions migrated from the interfacial layer to segregate to the surface at high temperature. Hydrogen chloride gas desorbs via recombination reaction of hydronium and chloride ions floating on the surface. Surface segregation of these species is driven by thermodynamic potential gradient present near the ice surface, whereas in the bulk, their transport is facilitated by thermal diffusion process. The finding suggests that chlorine activation reactions of hydrogen chloride for polar stratospheric ice particles occur at the surface of ice within a depth of at most a few molecular layers, rather than in the bulk phase.

• Bulletin of the Korean Chemical Society
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• 제21권6호
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• pp.571-576
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• 2000

Electrocatalytic effects for the reduction of thionyl chloride in $LiAICI_4/SOCl_2$ electrolyte solution containing Schiff base M(II) (M; Co and Fe) complexes are evaluated by determining kinetic parameters with cyclic voltammetry and chronoamperometry at a glassy carbon electrode. The charge transfer process during the reduction of thionyl chloride is affected by the concentration of the catalyst. The catalytic effects are demonstrated from both a shift of the reduction potential for the thionyl chloride toward a more positive direction and an increase in peak currents. Catalytic effects are larger in thionyl chloride solutions containing the binuclear [M(II) $_2$ (TSBP)] complex rather than mononuclear [M(II)(BSDT)] complexes. Significant improvements in the cell performance have been noted in terms of both thermodynamics and activation energy for the thionyl chloride reduction. The activation energy calculated from the Arrhenius plots is 4.5-5.9 kcal/mole at bare glassy carbon electrodes. The activation energy calculated for the catalyst containing solution is 3.3-4.9 kcalmole, depending on whether the temperature is lowered or rasied.

• Corrosion Science and Technology
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• 제21권6호
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• pp.454-465
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• 2022

The objective of this study was to determine effects of temperatures and pH of sodium chloride solution with MgCl₂ ions on corrosion resistance of duplex stainless-steel X2CrNiMoN22-5-3 (DSS) and Ti 6Al 2Nb1Ta1Mo (Ti). Effects of sodium chloride concentration on corrosion resistance were also studied. Corrosion behavior and pitting morphology of duplex stainless steel (DSS) and Ti alloys were evaluated through potentiodynamic polarization, electrochemical impedance spectroscopy (EIS), and scanning electron microscopy (SEM). It was found that a decrease in pH significantly reduced the corrosion resistance of both alloys. Changes in chloride concentration and temperature had more substantial impact on corrosion behavior of DSS than on Ti alloys. Pitting corrosion was formed on DSS samples under all conditions, whereas crevice corrosion was developed on Ti samples with the presence of magnesium chloride at 90 ℃. In conclusion, magnesium chloride ions in an exceedingly strong acidity solution appear to interact with re-passivation process at the surface of these alloys and influence the resulting surface topography.

• 한국재료학회지
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• 제12권10호
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• pp.803-808
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• 2002

Nickel powders were prepared from nickel chloride solution by wet reduction process, and the size control of the particles was investigated with reactant concentration, dispersant agent, and the addition of ethanol as an organic solvent in NiCl$_2$ aqueous solution. The size of the particle decreased with the increase of nickel chloride concentration. Their average particle size were 1.9$\mu\textrm{m}$, 1.6$\mu\textrm{m}$ and $1.5\mu\textrm{m}$ with 0.5M, 0.8M and 1.0M of nickel chloride concentration respectively. The spherical particle was easily controlled by the addition of ethanol as an organic solvent. Especially, in 30 vol% of ethanol, the average particle size and specific surface area were about 0.2$\mu\textrm{m}$ and 8.98m$^2$/g, respectively.

• International Journal of Concrete Structures and Materials
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• 제6권2호
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• pp.87-100
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• 2012

The process of selecting a repair material is a typical one of multi-criteria decision-making (MCDM) problems. In this study Analytical Hierarch Process was applied to solve this MCDM problem. Many factors affecting a process to select an optimal repair material can be classified into quantitative and qualitative requirements and this study handled only quantitative items. Quantitative requirements in the optimal selection model for repair material were divided into two parts, namely, the required chemical performance and the required physical performance. The former is composed of alkali-resistance, chloride permeability and electrical resistivity. The latter is composed of compressive strength, tensile strength, adhesive strength, drying shrinkage, elasticity and thermal expansion. The result of the study shows that this method is the useful and rational engineering approach in the problem concerning the selection of one out of many candidate repair materials even if this study was limited to repair material only for chloride-deteriorated concrete.

• 한국산업보건학회지
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• 제16권1호
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• pp.68-80
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• 2006

This study aimed to prepare the fundamental data and assess the status and trend of exposure level for 5 chemical substances such as sulfuric acid, hydrogen chloride, ammonia, formaldehyde and phenol in manufacturing industry by type of industry, working process, and size of factory, chronological change. Subjects related to this study consist of 146 factories, 12 industries and 17 working processes located in Busan area from Jan. 1997 to Dec. 2001. 1. All 5 kinds of chemical substances by type of industry, working process were generated in chemical manufacturing industry. There were founded in 8 types of industries and 13 types of working processes for ammonia, which is the highest number of in all 5 chemical substances. 2. In terms of the exposure level for 5 chemical substances by type of industry, working process, geometric mean concentration for sulfuric acid was $0.40mg/m^3$ in manufacture of chemicals and chemical products, $0.30mg/m^3$ in compounding process, for hydrogen chloride was 0.57 ppm in manufacture of basic metal, 0.48 ppm in dyeing process, for ammonia was 1.11 ppm in manufacture of rubber and plastic products, 0.94 ppm in buffing process, for formaldehyde was 0.49 ppm in manufacture of wood and of products of wood and cork, except furniture; manufacture of articles straw and plating materials, 0.53 ppm in mixing process, and for phenol were 0.53 ppm in manufacture of chemical and chemical products, 0.55 ppm in compounding process, respectively. Results for 5 chemical substances by type of industry and working process were significantly higher than those of the others(p<0.05). 3. The exposure level for hydrogen chloride, formaldehyde were significantly increased by size of industry (p<0.01). ammonia was significantly decreased by size of industry (p<0.01). 4. In trend of the concentration difference of five chemical substances by chronology, geometric mean concentration for sulfuric acid was significantly increased (p<0.01), hydrogen chloride and ammonia were significantly decreased by year (p<0.05) and for formaldehyde and phenol were decreased in chronological change. According to the above results 5 chemical substances were founded together in a way mixed in the same places one another and concentrations of chemical substances by industry, working process, size of industry and year appeared markedly. The authors recommend more systemic and effective work environmental management should be conducted in workplaces generating five chemical substances.

• 콘크리트학회논문집
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• 제15권6호
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• pp.902-912
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• 2003

전 세계적으로 콘크리트 구조물의 열화를 발생하는 가장 중요한 원인은 중성화와 염소이온이다. 대체적으로 많은 콘크리트 구조물에서 염소이온과 중성화로 인하여 철근이 부식되며 이에 대한 많은 연구가 이루어지고 있다. 그러나 실구조물의 상황은 염소이온과 중성화가 복합적으로 발생함에도 불구하고 많은 연구들이 각각의 단일열화에 대한 연구가 이루어지고 있으며 복합열화에 대한 연구는 매우 드문 상황이다. 본 연구는 2중 복합 매체에 대한 확산모델을 이용하여 중성화된 콘크리트의 염소이온 프로파일을 예측하고자 하였다. 실험결과에 의하여 중성화 깊이로부터 3∼5 mm영역에 염소이온의 농축현상이 발생하였으며 2중 복합 구조체에 적용할 수 있는 확산 방정식에 중성화된 콘크리트와 비중성화된 콘크리트의 시간의존적인 염소이온 확산 계수를 고려하여 내구수명예측에 반영하였다.

• 전기화학회지
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• 제11권3호
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• pp.159-164
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• 2008

변전위법, 순환전압전류법, 대시간전류법 및 대시간전기량법을 이용하여 구리의 산화 용해반응에 미치는 $Cl^-$의 영향을 조사하였다. 아르곤 분위기의 NaCl 수용액에서 Cu의 산화 용해반응은 전반응식 $Cu+2Cl^{-}{\rightleftharpoons}{CuCl_2}^{-}+e^-$ 에 따라 일어나며, Cu 표면에 $Cl^-$가 흡착하는 과정에 잘 맞는 등온식은 Temkin 흡착등온식 임을 알 수 있었다.

• 폴리머
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• 제39권1호
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• pp.1-5
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• 2015

The effects of zeolite on the thermal stability of poly(vinyl chloride) (PVC) were investigated by the static thermal stability test, pyrolysis experiment and ultraviolet spectrum. The results showed that the porous zeolite could absorb hydrogen chloride (HCl), which suppressed the catalysis of HCl on thermal degradation of PVC, thus improved the thermal stability of PVC. The oxidizing acid which was loaded on zeolite had oxidated on the double bond that formed during the dehydrochlorination of PVC. This process could prohibit the growth of the conjugated polyene and improved the color of PVC. Hence, zeolite might be possible to come up with a high performance thermal stabilizer.

• 한국지구물리탐사학회:학술대회논문집
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• 한국지구물리탐사학회 2003년도 Proceedings of the international symposium on the fusion technology
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• pp.598-602
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• 2003

The general red-mud minerals consist of hematite, sodalite, anatase, quartz, gibbsite and miner impurities. This gives serious environmental damage for the ocean disposal. It mixed with chloride compound and the content of chlorine is about 2,000-3,000ppm. This paper can be suggested the chloride reduction technology that is applied basically mineral processing by physical separation. Then it can be possible to produce the totally 24wt. $\%$ useful red-mud which chloride content is less then 400ppm.