• Journal of the Korea institute for structural maintenance and inspection
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• v.20 no.2
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• pp.102-109
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• 2016

This paper presents mechanical properties and chloride diffusivity of the recycled aggregate concretes(RAC) in which natural coarse aggregate was replaced by recycled coarse aggregate(RCA) by compressive strength levels(20, 35, 50 MPa). A total of 9 RAC were produced and classified into three series, each of which included three mixes designed with three compressive strength levels of 20 MPa, 35 MPa and 50 MPa and three RCA replacement ratios of 0, 50 and 100%. Engineering properties of RAC were tested for slump test, air content, compressive strength, chloride penetration depth and chloride diffusion coefficient. The test results indicated that the workability of RAC could be improved or same by RCA replacement ratios, when compared with that containing no RCA. This is probably because of the RCA shape improving the workability of RAC. Also, the test results showed that the compressive strength was decreased by 9~10% as the RCA replacement ratios increase. Furthermore, the result indicated that the measured chloride diffusion coefficient increases by 144% with the increase of the RCA replacement. In the case of the concrete having low level compressive strength, the increase of chloride diffusion coefficient tends to be higher when using the RCA. However, the trend of chloride diffusion coefficient in high level compressive strength concrete is similar to that obtained in general concrete. This is because that the effect of the RCA replacement could be a decrease with increase of compressive strength. Therefore, an advance on the admixture application and mix ratio control are required to improve the chloride resistivity when using the recycled aggregate in large scale.

• Journal of the Korean Society of Safety
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• v.22 no.3 s.81
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• pp.57-64
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• 2007

Recently, the corrosion of concrete structures has received great attention related with the deterioration of sea-side structures, such as new airport, bridges, and nuclear power plants. In this regards, many studies have been done on the chloride attack in concrete structures. However, those studies were confined mostly to the single deterioration due to chloride only, although actual environment is rather of combined type. The purpose of the present study is, therefore, to explore the influences of carbonation and freezing-thawing action to chloride attack in concrete structures. The test results indicate that the chloride penetration is more pronounced than the case of single chloride attack when the carbonation process is combined with the chloride attack. It is supposed that the chloride ion concentration of carbonation region is higher than the sound region because of the separation of fixed salts. Though the use of fly ash pronounces the chloride ion concentration in surface, amounts of chloride ion penetration into deep region decreases with the use of fly ash. The small reduction of relative dynamic elastic modulus induced from freezing-thawing increases the chloride ion penetration depths much. The present study allows more realistic assessment of durability for such concrete structures which are subjected to combined attacks of both chlorides and carbonation or freezing-thawing but the future studies for combined environment will assure the precise assessment.

• Computers and Concrete
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• v.8 no.5
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• pp.511-524
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• 2011

Although concrete is believed to be a durable material, concrete structures have been degraded by severe environmental conditions such as the effects of chloride and chemical, abrasion, and other deterioration processes. Therefore, durability evaluation has been required to ensure the long term serviceability of structures located in chloride exposed environments. Recently, probability-based durability analysis and design have proven to be reliable for the service-life predictions of concrete structures. This approach has been successfully applied to durability estimation and design of concrete structures. However, currently it is difficult to find an appropriate method engineers can use to solve these probability-based diffusion problems. In this paper, computer software has been developed to facilitate probability-based durability analysis and design. This software predict the chloride diffusion using the Monte Carlo simulation method based on Fick's second law, and provides durability analysis and design solutions. A graphic user interface (GUI) is adapted for intuitive and easy use. The developed software is very useful not only for prediction of the service life but for the durability design of the concrete structures exposed to chloride environments.

• Journal of the Korea Concrete Institute
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• v.15 no.2
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• pp.345-351
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• 2003

The transport characteristics of deleterious ions such as chlorides depend on the pore structures of concrete and are the major factors in the durability of concrete structures in subjected to chloride attack such as in marine environments. In this paper, the effect of the pore structure on compressive strength and chloride diffusivity of concrete was investigated. Six types of concretes were tested. The pore volume of concrete containing mineral admixtures increased in the range of 3∼30nm due to micro filling effect of hydrates of the mineral admixtures. There was a good correlation between the median pore diameter, the pore volume above 50nm and compressive strength of concrete, but there was not a significant correlation between the total pore volume and compressive strength. The relationship between compressive strength and chloride diffusivity were not well correlated, however, pore volume above 50nm were closely related to the chloride diffusion coefficient.

• Journal of the Korea Concrete Institute
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• v.17 no.4 s.88
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• pp.663-670
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• 2005

The present study concerns the influence of binder type on the chloride-induced corrosion being accompanied by the chloride threshold level (CTL), chloride transport and as their results the corrosion-free lift. Two levels of cement content, $30\%$ PFA and $65\%$ GGBS concrete were employed. It was found that the most dominant factor to the CTL is the entrapped air void content at the steel-concrete interface, irrespective of the chloride binding capacity, binder type and acid neutralisation capacity of cement matrix. The CTL for lower interfacial air void contents was significantly increased up to $1.52\%$ by weight of cement, whereas a same mix produced $0.35\%$ for a higher level of voids. Because of a remarkable reduction in the diffusion fur GGBS concrete, its time to corrosion ranges from 255 to 1,250 days, while the corrosion-free life for control varies from 20 to 199 days sand for $30\%$ PFA concrete from 200 to 331 days.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.11a
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• pp.413-416
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• 2008

Reinforcement corrosion is generally prohibited under normal condition by the alkalinity of the pore water in the concrete. However, concrete structures in marine environment are subjected to chloride attack due to the high salinity of the sea water. Thus the probability of steel corrosion becomes higher when the chloride ions are introduced into the concrete. Steel corrosion is a decisive factor for the determination of service life of the marine concrete structure because chloride ions are abundant in the sea, and piers are the typical construction elements in concrete structures in marine environment. Hence, it is of great importance to evaluate the service life of the piers. In this paper, chloride penetration analysis for the rectangular pier in the marine environment is performed considering the diffusion and convection movement of chlorides. Result reveals that the service life of the reinforcement with drying-wetting cycles is much shorter than that of the reinforcement with saturated condition. This may be due to the fact that moisture movement is much faster that chloride diffusion.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.28 no.5A
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• pp.709-718
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• 2008

Developed is a chloride penetration analysis program in which changes of environmental conditions such as temperature, humidity and external chloride concentration, and the diffusion, convection and binding of chlorides are considered. In order to consider the changes of environmental conditions, analyses for temperature and moisture distribution are implemented simultaneously, and variation of diffusion coefficients due to temperature, humidity and age is also considered. By comparing the calculated total chloride contents with some experimental data, it has been confirmed that the proposed analysis program can trace measured chloride distribution well. Also, through some example analyses, the mechanism of accumulation of chlorides at near surface and acceleration of corrosion of steel reinforcement in case that the moisture distribution changes according to repeated drying and wetting cycles have been verified.

• Journal of the Korea institute for structural maintenance and inspection
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• v.21 no.6
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• pp.83-90
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• 2017

Concrete structure for nuclear power plant is mass concrete structure with large wall depth and easily permits cracking in early age due to hydration heat and drying shrinkage. It always needs cooling water so that usually located near to sea shore. The crack on concrete surface permits rapid chloride intrusion and also causes more rapid corrosion in the steel. In the study, the effect of age and crack width on chloride diffusion is evaluated for the concrete for nuclear power plant with 6000 psi strength. For the work, various crack widths with 0.0~1.4 mm are induced and accelerated diffusion test is performed for concrete with 56 days, 180days, and 365 days. With increasing crack width over 1.0mm, diffusion coefficient is enlarged to 2.7~3.1 times and significant reduction of diffusion is evaluated due to age effect. Furthermore, apparent diffusion coefficient and surface chloride content are evaluated for the concrete with various crack width exposed to atmospheric zone with salt spraying at the age of 180 days. The results are also analyzed with those from accelerated diffusion test.

• Journal of the Korean Recycled Construction Resources Institute
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• v.11 no.1
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• pp.62-69
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• 2023

For the nuclear power concrete plant structures in the UAE, it is necessary to consider the deterioration from high sulfate ions in the atmosphere and high chloride ions from the coast. In this study, two strength grade concrete mixture (40 MPa and 27 MPa) and two curing/diffusion temperatures (20 ℃ and 50 ℃) were considered for evaluating the temperature effects on diffusion and strength due to high average temperature above 38 ℃ a year in UAE. When the initial curing temperature was high, the compressive strength increased in high-temperature curing to 7 days, but the strength slightly increased in the 20 ℃ curing condition at 28 days. Regarding diffusion test, unlike the compressive test results, reduced chloride diffusion coefficients were evaluated both in 40 MPa and 27 MPa grade at 28 days. In the case of 91 days of curing, an increase in diffusivity due to high temperature and a decrease in diffusivity due to age effect occur simultaneously. Compared to the results of the curing and diffusion tests at 20 ℃ and 28 days, when the curing and diffusion tests were conducted at 50 ℃ in 91 days, the diffusion coefficients decreased to 76.2 % in 40 MPa grade and 85.4 % in 37 MPa grade with increasing curing period, respectively.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.30 no.5A
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• pp.433-442
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• 2010

A control of chloride diffusion coefficient is very essential for service life of reinforced concrete (RC) structures exposed to chloride attack so that much studies have been focused on this work. The purpose of this study is to derive the intended diffusion coefficient which satisfies intended service life and propose a technique for optimum concrete mixture through genetic algorithm(GA). For this study, 30 data with mixture proportions and related diffusion coefficients are analyzed. Utilizing 27 data, fitness function for diffusion coefficient is obtained with variables of water to binder ratio(W/B), weight of cement, mineral admixture(slag, flay ash, and silica fume), sand, and coarse aggregate. 3 data are used for verification of the results from GA. Average error from fitness function is observed to 18.7% for 27 data for diffusion coefficient with 16.0% of coefficient of variance. For the verification using 3 data, a range of error for mixture proportions through GA is evaluated to 0.3~9.3% in 3 given diffusion coefficients. Assuming the durability design parameters like intended service life, cover depth, surface chloride content, and replacement ratio of mineral admixture, target diffusion coefficient, where exterior conditions like relative humidity(R.H.) and temperature, is derived and optimum design mixtures for concrete are proposed. In this paper, applicability of GA is attempted for durability mixture design and the proposed technique would be improved with enhancement of comprehensive data set including wider range of diffusion coefficients.