• Title/Summary/Keyword: Chloride Ion Penetration

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Mechanical Properties and Durability of Asphalt Emulsion-Modified Cement Mortars

  • Song Hun;Do Jeong-Yun;Soh Yang-Seob
    • Journal of the Korea Concrete Institute
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    • v.17 no.3 s.87
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    • pp.467-472
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    • 2005
  • Asphalt emulsion is manufactured by the emulsification of asphalt, and is considered as an energy-saving, ecologically safe material because it does not need any heating processes with gas emission and fire hazard in its use. This study is concerned with evaluating the feasibility of the use of an asphalt emulsion as a poly-meric admixture. Asphalt-modified mortars using an experimentally manufactured asphalt emulsion were prepared with various polymer-cement ratios, and tested far the mechanical properties such as strengths and adhesion and the properties related to durability such as water absorption, permeation, carbonation and chloride ion penetration. As a result, the waterproofness, carbonation resistance and chloride ion penetration resistance of the asphalt-modified mortars were markedly improved with an increase in the polymer-cement ratio, but their compressive strength and adhesion to mortar substrates were reduced with increasing polymer-cement ratio. Therefore, it is recommended to control their polymer-cement ratio to be $10\%$ or lower in their practical applications. Further study to improve their compressive strength and adhesion is needed.

Analysis of physical properties of high-performance concrete using domestic low-cost silica fume (국산 저가형 실리카퓸을 이용한 고성능 콘크리트의 물리적 특성 분석)

  • Kim, Sang Do;Yun, Kyung Ku;Ham, Seung Yeon;Lee, Kyeo Re
    • Journal of Industrial Technology
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    • v.37 no.1
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    • pp.32-36
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    • 2017
  • In this study, as part of a research on the development of economical high-performance concrete with high strength and high quality, the physical properties of high-performance concrete were analyzed by substituting a certain amount of low-cost domestic silica fume exempted from the re-importation type distribution structure of the domestic production and the existing high-priced silica fume distribution structure. Performing tests to identify the physical properties of the fresh and hardened concrete and durability analogy of the concrete which use low-cost domestic silica fume and imported silica fume, the chloride ion penetration resistance test result showed that the strength difference between the low-cost silica fume and the imported silica fume is not big but the strength of the low-cost silica fume was measured higher than the imported silica fume. The chloride ion penetration resistance of all variables was measured as "very low". Since the low-cost domestic silica fume can be used as a high-performance admixture of concrete, the results suggest that it is possible to produce a more economical high-performance concrete.

Mechanical and Durability Characteristics of Latex-Modified Concrete Using Ultra Rapid Hardening Cement (초속경 시멘트를 이용한 라텍스 개질 콘크리트의 역학성능과 내구성능)

  • Park, Sang-Hyun;Jung, Si-young;Kim, Hyun-yu;Choi, Kyoung-Kyu
    • Journal of the Architectural Institute of Korea Structure & Construction
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    • v.35 no.5
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    • pp.153-160
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    • 2019
  • The purpose of this study was to investigate the mechanical and durability characteristics of latex-modified concrete using ultra rapid hardening cement : four types of mechanical tests including compressive strength, modulus of elasticity, flexural strength and bond strength were performed; and seven types of durability tests including resistance of concrete to chloride ion penetration, freeze-thaw resistance, scaling resistance, coefficient of thermal expansion, cracking tendency, abrasion resistance and drying shrinkage were performed. Required material performance of each test was determined in accordance with the Korea specification for repair of concrete and pavement repairing materials. The test results satisfied the required material performances, and presented a good mechanical and durability characteristics. In particularly, the materials showed early development of compressive strength, flexural strength and bond strength at 3 and 4 hours after curing. SEM photos were also taken to investigate the micro structures of the materials after chloride ion penetration test.

A Study on Chloride Attack Resistibility of Quaternary Concrete (4성분계 콘크리트의 염해 저항성능에 관한 연구)

  • Lee, Dong-Un;Park, Hyun-Jung
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.2
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    • pp.1188-1194
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    • 2014
  • The purpose of this study is to estimate Chloride Attack Resistibility and mechanical properties of quaternary concrete adding fly ash, blast-furnace slag, and silica fume. Compressive strength, modulus of elasticity, chloride migration coefficient, charge passed from Rapid chloride penetration test(RCPT), and immersion testing in 3% NaCl are tested. Chloride migration coefficient and charge passed of quaternary concrete measured $0.032{\times}10^{-12}m^2/sec$ and 650 coulomb at 17 weeks, which are in a permitted limit. Also in immersion test, depth of chloride penetration and maximum chloride ion of quaternary concrete measured 3.7 mm and $10.211kg/m^3$ respectively. From the results, quaternary concrete adding fly ash, blast-furnace slag, and silica fume denotes improvement of mechanical properties and chloride attack resistibility.

Chloride Attack Resistibility of Marine Concrete under Pressure (압력을 받는 해양콘크리트의 염해저항성)

  • Kim, Gyeong-Tae;Kim, Gyu-Yong;Lee, Sang-Kyu;Hwang, Eui-Chul;Son, Min-Jae;Nam, Jeong-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2018.11a
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    • pp.52-53
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    • 2018
  • As a result of exposing the concrete at 1 and 6 atm in order to evaluate the salt resistance of the pressurized marine concrete, the pressure resulted in promoting the chloride ion penetration of the concrete. Particularly, the amount of water soluble chloride in the surface area tends to increase rapidly, and this cause is considered to be highly correlated with the size of the capillary pores of the concrete. On the other hand, the blending of blast furnace slag was effective to increse chloride attack resistibility even under the pressure.

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Diffusion study for chloride ions and water molecules in C-S-H gel in nano-scale using molecular dynamics: Case study of tobermorite

  • Zehtab, Behnam;Tarighat, Amir
    • Advances in concrete construction
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    • v.4 no.4
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    • pp.305-317
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    • 2016
  • Porous materials such as concrete could be subjected to aggressive ions transport. Durability of cement paste is extremely depended on water and ions penetration into its interior sections. These ions transport could lead different damages depending on reactivity of ions, their concentrations and diffusion coefficients. In this paper, chloride diffusion process in cement hydrates is simulated at atomistic scale using molecular dynamics. Most important phase of cement hydrates is calcium silicate hydrate (C-S-H). Tobermorite, one of the most famous crystal analogues of C-S-H, is used as substrate in the simulation model. To conduct simulation, a nanopore is considered in the middle of simulation cell to place water molecules and aggressive ions. Different chloride salts are considered in models to find out which one is better for calculation of the transport properties. Diffusion coefficients of water molecules and chloride ions are calculated and validated with existing analytical and experimental works. There are relatively good agreements among simulation outputs and experimental results.

The Effect of Corrosion Protection of Reinforcing Steel in Concrete Applied Surface Painting Materials (내염성도장 콘크리트 주에 묻은 철근의 방청효과)

  • 문한영;김성수;김홍삼;김홍삼
    • Proceedings of the Korea Concrete Institute Conference
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    • 1996.10a
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    • pp.196-200
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    • 1996
  • In the case of construction under the marine environment the durability of concrete structures is everely deteriorated by the penetration of salts which results in the corrosion of reinforcing steel. To verify the effect of corrosion protection of reinforcing steel by isolating the penetration of chlorideion this study investigated the bond strength between painting material and concrete, the degree of the penetration-diffusion of chloride ion and the accelerated corrosion test using different potential. Results show that the painted concrete has little the penetration-diffusion of cholride and the reinforcing steel in painted concrete is little corroding.

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Durability Properties of Low Carbon Green Concrete (저탄소 그린콘크리트의 내구 특성)

  • Cho, Il Ho;Sung, Chan Yong
    • Journal of The Korean Society of Agricultural Engineers
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    • v.55 no.6
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    • pp.11-17
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    • 2013
  • This study was performed to evaluate the chlorine ion penetration resistance, chemical resistance and freezing and thawing resistance used ordinary portland cement, crushed coarse aggregate, crushed sand, river sand, fly ash, limestone powder, blast furance slag powder and superplasticizer to find optimum mix design of low carbon green concrete for structures. The performance of low carbon green concrete used fly ash, limestone powder and blast furnace slag powder were remarkably improved. This fact is expected to have economical effects in the manufacture of low carbon green concrete for offshore structures. Accordingly, the fly ash, limestone powder and blast furnace slag powder can be used for offshore structure materials.

Influence of Reinforcements on the Chloride Diffusion Analysis of Concrete Structures (철근의 영향을 고려한 콘크리트 구조물의 염소이온 확산해석)

  • 오병환;장봉석;이명규
    • Journal of the Korea Concrete Institute
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    • v.14 no.6
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    • pp.883-891
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    • 2002
  • The chloride penetration in concrete structures is influenced by many factors such as types of cement and admixture proportion. Therefore, the effects of these factors on chloride diffusion must be correctly considered. The conventional diffusion analysis also neglected the existence of reinforcing bar in concrete structures. The purpose of the present paper is therefore to investigate the effect of reinforcing bar on the chloride diffusion in concrete structures. For this purpose, a comprehensive finite element analyses have been conducted to obtain chloride penetration profile. The results indicate that the chlorides are accumulated in front of a reinforcing bar and that the accumulation is much larger for the case of large diameter bars. The higher accumulation of chloride at bar location causes much faster corrosion of reinforcing steel. It can be concluded from the present study that the effects of reinforcing bars must be considered in chloride diffusion analysis for more realistic prediction of durable life of concrete structures.

Corrosion-Inhibition and Durability of Polymer-Modified Mortars Using Bisphenol A and F Type Epoxy Resin with Calumite (비스페놀 A 및 F형 에폭시수지와 칼루마이트를 병용한 폴리머 시멘트 모르타르의 방청성 및 내구성)

  • Kim, Joo-Young;Kim, Wan-Ki
    • Journal of the Korea Concrete Institute
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    • v.26 no.4
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    • pp.517-524
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    • 2014
  • Nitrite-Type hydrocalumite (calumite) is a material that can adsorb chloride ions ($Cl^-$) that cause corrosion of reinforce bars and liberate the nitrite ions ($NO_2{^-}$) that inhibit corrosion in reinforced concrete. In this study, polymer-modified mortars using two types of epoxy resin with calumite are prepared with various polymer binder-ratios of 0, 5, 10, 15, 20% and calumite contents of 0, 5%. The specimens are tested for chloride ion penetration, carbonation, drying shrinkage and corrosion inhibition. As a result, the chloride ion penetration and carbonation depth of PMM using epoxy resin somewhat increases with increasing calumite contents, but those remarkably decreases depending on the polymer-binder ratios. The 28-d drying shrinkage shows a tendency to decrease with increasing polymer-binder ratio and calumite content. Unmodified mortars with calumite content of 5% did not satisfy quality requirement by KS. However, it was satisfied with KS requirement by the modification of epoxy resin in cement mortar. On the whole, the carbonation and chloride ion penetration depth of epoxy-modified mortars with calumite is considerably improved with an increase in the polymer-binder ratio regardless of the calumite content, and is remarkably improved over unmodified mortar. And, the replacement of the portland cement with the calumite has a marked effect in the corrosion-inhibiting property of the epoxy-modified mortars.