• Title/Summary/Keyword: Chloride Ion

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Optimum Mix Proportion and Mechanical Properties of Rain Garden Structure Concrete using Recycled Coarse Aggregate, Hwang-Toh, Blast Furnace Slag and Jute Fiber (순환굵은골재, 황토, 고로슬래그 미분말 및 마섬유를 사용한 레인가든 구조물 콘크리트의 최적배합설계 및 역학적 특성)

  • Kim, Dong-Hyun;Park, Chan Gi
    • Journal of The Korean Society of Agricultural Engineers
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    • v.55 no.3
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    • pp.25-33
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    • 2013
  • In this study, the optimum mix proportions of rain garden structure concrete were decided and the mechanical properties were evaluated. Experimental parameters were blast furnace slag, hwang-toh, recycled aggregates and natural jute fibers. The target compressive strength and chloride ion penetration were more than 24 MPa and less than 1000 coulombs, respectively. The response surface method was used for statistical optimization of experimental results. The optimal mixing ratios of the blast furnace slag, hwang-toh, recycled coarse aggregate and jute fiber volume fraction were determined 59.98 %, 8.74 %, 12.12 % and 0.2 %, respectively. The compressive strength, flexural strength and chloride ion penetration test results of optimum mix ratio showed that the 24.56 MPa, 3.88 MPa and 999.08 columbs, respectively.

Development and Application of Unit Table Form using Euro Form for High-rise Building Construction (슬래그 혼입 콘크리트의 염소이온 차단성능)

  • Park, Dong-Cheon
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2018.05a
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    • pp.136-137
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    • 2018
  • The properties of concrete produced by ready mixed concrete company in Busan were measured. Because the concrete was mixed with blast furnace slag and fly ash etc., the compressive, tensile strength and chloride ion diffusion coefficient were lower than OPC concrete even though the specified concrete strength was same. If the durability about salt attack were satisfied, the concrete of lower specified concrete strength would be adopted to concrete mixing design. FEM analysis was carried out to predict the life time expectancy.

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Hydrodynamic and Chloride Ion Effects on Corrosion of Cobalt in Bicarbonate Buffer Solution (Bicarbonate 완충용액에서 코발트의 부식에 대한 대류와 염화이온의 영향)

  • Kim, Youn-Kyoo;Chon, Jung-Kyoon
    • Journal of the Korean Chemical Society
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    • v.51 no.6
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    • pp.479-486
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    • 2007
  • Bicarbonate 완충용액에서 Co-RDE를 이용하여 RDE 회전속도와 완충용액 속의 염화이온이 Co의 부식과 부동화에 미치는 영향을 연구하였다. Co-RDE의 회전속도가 부식에 미치는 영향은 Levich 식과 일치하였으며 부동화 막을 파괴하는데 염화이온의 효과가 큼을 알 수 있었다. 혼합 전위 이론을 사용하여 대류확산 조건에서 회전속도의 증가에 따라 부식전위가 양의 방향으로 증가하는 모형을 발견하였다. Tafel 영역에서 Co의 용해반응과 수소가 발생하는 환원반응은 전하이동과 물질이동을 이용하여 설명할 수 있었다.

Chloride Ion Diffusion for Ready Mixed Concrete (설계기준 압축강도별 레미콘의 염소이온 확산 특성평가)

  • Park, Dong-Cheon;Kim, Yong-Ro
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2018.11a
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    • pp.149-150
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    • 2018
  • The RC buildings which are constructed on the seaside are followed by KBC(2016) to achieve the minimization of durability damage. To control the corrosion of the reinforced steel bar by salt attack, W/C should be under 0.4 and specified concrete strength is more than 35MPa in the concrete/building construction standard specification. Ready mixed concretes which have usually include the admixtures in Busan were tested to certify the salt attack durability. In the same specified concrete strength, remarkable salt attack durability was evaluated in comparison to OPC.

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Evaluation on the Properties of Modified-sulfur Concrete as a Basic Study for Development of Anti-corrosive Concrete (내부식성 콘크리트 개발을 위한 기초연구로서 개질유황 혼합 콘크리트의 물성 평가)

  • Park, Sang-Soon;Na, Ok-Jung
    • Corrosion Science and Technology
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    • v.15 no.1
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    • pp.28-37
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    • 2016
  • Due to the increased construction of offshore concrete structures and the use of de-icing salts for the purpose of snow removal, the needs for the development of anti-corrosive concrete are increasing. To solve these problems, an evaluation of the mechanical and durability properties for concrete were conducted by mixing modified-sulfur as 0 %, 5 %, 10 %, 15 % cement weight ratio. Both strengths and the properties affecting durability such as water absorption coefficient, chloride ion permeability, accelerated carbonation resistance, rapid freezing and thawing, and chemical resistance were evaluated. All evaluations performed were according to the test specifications associated KS. The results indicate that mixing of modified-sulfur lowed chloride ion permeability and improved chemical resistance.

Assessment of the effect of sulfate attack on cement stabilized montmorillonite

  • Kalipcilar, Irem;Mardani-Aghabaglou, Ali;Sezer, Gozde Inan;Altun, Selim;Sezer, Alper
    • Geomechanics and Engineering
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    • v.10 no.6
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    • pp.807-826
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    • 2016
  • In this study, aiming to investigate the effects of sulfate attack on cement stabilized highly plastic clay; an experimental study was carried out considering the effects of cement type, sulfate type and its concentration, cement content and curing period. Unconfined compressive strength and chloride-ion penetration tests were performed to obtain strength and permeability characteristics of specimens cured under different conditions. Test results were evaluated along with microstructural investigations including SEM and EDS analyses. Results revealed that use of sulfate resistance cement instead of normal portland cement is more plausible for soils under the threat of sulfate attack. Besides, it was verified that sulfate concentration is responsible for strength loss and permeability increase in cement stabilized montmorillonite. Finally, empirical equations were proposed to estimate the unconfined compressive strength of cement stabilized montmorillonite, which was exposed to sulfate attack for 28 days.

Validation on Reliability of Data for Development of Forecasting System of Service Lifetime in Marine Structures (해양구조물 수명예측 시스템 구축을 위한 데이터 신뢰성 검증)

  • Leem, Young-Moon;Yang, Eun-Ik;Hwang, Young-Seob
    • Journal of the Korea Safety Management & Science
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    • v.9 no.2
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    • pp.85-95
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    • 2007
  • Because the damages of corrosion resulting from the chloride ion are very serious, many research studies have been performed to measure the penetration depth of the chloride ion. However, there is a problem with data selection obtained from collection during experiments. After careful study, it appears that the collected data are not conformed to a normal distribution. The result of this study will play a very important role, as a first step for the development and construction of a forecasting system to help determine a reliable service lifetime of marine structures.

Estimation on the Durability of High-Strength Concrete using Metakaolin (Metakaolin 혼합 고강도콘크리트의 내구특성 평가)

  • Moon Han Young;Yum Jun Hwan;Moon Su Dong;Lee Sang Ho
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.11a
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    • pp.217-220
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    • 2004
  • Metakaolin is a cementitious material for producing high-strength concrete. This material is now used as substitute for silica-fume. In this paper, we did the durability test such as chloride ion diffusion, chemical attack. repeated freezing and thawing, carbonation. In the chloride ion diffusion test, according to the increase of substitute of metakaolin & silica-fume for binder, the diffusion coefficient is more reduced. And in the chemical attack test, according to the increase of substitute, the resistance is more excellent. In the other durability test, the concrete using metakaolin is also compared with those of the portland cement concrete and silica fume concrete. According to these tests, we recognized that metakaolin is able to be used as a substitute for silica-fume.

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An Experimental Study on the Strength and Permeability Characteristics of Repair Mortar (보수용 모르타르의 강도 및 투과특성에 관한 연구)

  • Paik, Shin-Won
    • Journal of the Korean Society of Safety
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    • v.18 no.4
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    • pp.105-109
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    • 2003
  • Structure surfaces damaged due to many causes are repaired by several special mortars. But wide studies about the permeability of these mortars were rarely conducted. In this study compressive strength test, flexural strength test and bond strength test of these mortars were conducted. And chloride ion penetration test was also conducted to explore the permeability charcteristics of selected repair mortars. This test was carried out following the standard ASTM C1202-91. Colouriemtric penetration depth can be drawn from these test results using a relationship equation between colourimetric penetration depth and charge passed which C. Andrade suggested. Diffusion coefficient can be calculated by CTH rapid method. To the end, the present study can provide a firm base for the application of repair mortars to concrete structures.

Polymeric Membrane Cesium-Selective Electrodes Based on Quadruply-bridged Calix[6]arenes

  • Choe, Eun Mi;O, Hye Jin;Go, Seung Hwa;Choe, Yong Guk;Nam, Gye Chun;Jeon, Seung Won
    • Bulletin of the Korean Chemical Society
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    • v.22 no.12
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    • pp.1345-1349
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    • 2001
  • New quadruply-bridged calix[6]arenes (I-V) have been studied as cesium selective ionophores in poly(vinyl chloride) (PVC) membrane electrodes. PVC membranes were prepared with dioctyl sebacate (DOS) or 2-nitrophenyl octyl ether (o-NPOE) as the sol vent mediator and potassium tetrakis(p-chlorophenyl)borate as the lipophilic salt additive. These ionophores produced electrodes with near-Nernstian slope. The selectivity coefficients for cesium ion with respect to alkali, alkaline earth and ammonium ions have been determined. The lowest detection limit (logaCs+ = -6.3) and the higher selectivity coefficient (logkpotCs+,Rb+ = -2.1 by SSM, -2.3 by FIM for calix[6]arene I) for Cs+ have been obtained for membranes containing quadruply-bridged calix[6]arenes (I, Ⅱ, Ⅲ), which have no para t-butyl substituents on the bridging benzene ring.