• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.21 no.8
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• pp.433-438
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• 2009

Experimental results for performance characteristics of small $NH_3$ absorption chiller/ heater are presented. The apparatus consists of 7RT water-cooled absorption system, solution pump, boiler, cooling tower and peripheral devices. The effect of experimental parameters, such as refrigerant mass flow rate, solution mass flow rate and cooling water temperature have been investigated in view of the system performance. The capacity of each heat exchanger increased as refrigerant mass flow rate increased in cooling mode. Also, a cooling capacity increased as a strong solution mass flow rate increased. The cooling and heating COP show 0.5, 1.5 regardless of refrigerant mass flow rate, respectively. The results focus on the evaluation for performance characteristics of system with respect to variation of refrigerant mass flow rate under standard design conditions.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.23 no.4
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• pp.243-250
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• 2011

In order to investigate the effects of PAG oil concentration on heat transfer performance and pressure drop during gas cooling process of $CO_2$, the experiments on fin-tube heat exchanger of $CO_2$ heat pump were performed. The experimental apparatus consists of a gas cooler, a heater, a chiller, a mass flow meter, a pump and measurement system. Experiments were conducted in various experimental conditions, which were inlet temperature($110^{\circ}C$), mass flow rates (50, 55, 60, 65, 70 g/s) and PAG oil concentration(0 to 2.6 wt%). Heat transfer rate decreased with the increase of the oil concentration and the decrease of inlet pressure. And pressure drop increased with the increase of the oil concentration and mass flow rate of refrigerant. The COP reduction by deterioration of gas cooler performance with oil concentration was analyzed. When inlet pressure of gas cooler is 100 bar, the COP reduction was estimated by 6% under 1 wt% of oil concentration.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.23 no.3
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• pp.208-215
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• 2011

In this work, pool boiling heat transfer coefficients(HTCs) of R22, R123, R134a, and R245fa are measured on both horizontal plain and 26 fpi low fin tubes. The pool boiling temperature is maintained at $7^{\circ}C$ and heat flux is varied from 80 $kW/m^2$ to 10 $kW/m^2$ with an interval of 10 $kW/m^2$. Wall temperatures are measured directly by thermocouples inserted through holes of 0.5 mm diameter. Test results show that HTCs of high vapor pressure refrigerants are usually higher than those of low pressure fluids in both plain and low fin tubes. On a plain tube, HTCs of R245fa are 23.3% higher than those of R123 while on a 26 fpi low fin tube, HTCs of R245fa are 46.3% higher than those of R123. The fin effect is more prominent with low vapor pressure refrigerants than with high vapor pressure ones due to a sweeping effect.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.29 no.5
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• pp.239-248
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• 2017

At the $21^{st}$ Conference of the Parties (COP) of the United Nations Climate change Conference, representatives of the 195 member countries reached an agreement requiring all participating countries, including Korea, to establish proactive measures to fight climate change. Under this vision, energy network technologies are deemed as a key site of research towards meeting this goal. Herein, the headquarters of the Korea Institute of Energy Research (KIER) is a worthy site for carrying out energy network technology research insofar as it contains various heat sources. To prepare for this research, a study was conducted analyzing the heat sources at KIER based on measured data. The study also consisted of developeding simulation models to predict the amount of energy savings that could be derived by replacing an absorption chiller/heater with an absorption heat pump during winter seasons. In our simulation results, we observed a primary energy saving ratio of 65~72% based on the water temperature from the heat source of a coal power plant.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.21 no.1
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• pp.16-22
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• 2009

In order to investigate $CO_2$ heat transfer coefficient and pressure drop by PAG oil concentration during $CO_2$ evaporation, the experiment on evaporation heat transfer characteristics in a mini-channels were performed. The experimental apparatus consisted of a test section, a DC power supply, a heater, a chiller, a mass flow meter, a pump and a measurement system. Experiment was conducted for various mass fluxes($300{\sim}800kg/m^{2}s$), heat fluxes($10{\sim}40kW/m^2$) saturation temperatures($-5{\sim}5^{\circ}C$), and PAG oil concentration(0, 3, 5wt%). The variation of the heat transfer coefficient was different according to the oil concentration. With the increase of the oil concentration, the evaporation heat transfer coefficient decreased and the delay of dryout by oil addition was found. Pressure drop increased with the increase of the oil concentration and heat flux, and the decrease of saturation temperature.

• Economic and Environmental Geology
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• v.34 no.6
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• pp.507-522
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• 2001

At the Tongyeong mine, quartz, rhodochrosite (kutnahorite), muscovite, illite, pyrite, galena, chalcopyrite. sphalerite, acanthite, and hessite are the principal vein minerals. They were deposited under epithermal conditions in two stages. Ore mineral assemblages and associated gangue phases in stage can be clearly divided into two general associations: an early cycle (band) that appeared with introduction of most of the sulfides and electrum, and a later cycle in which base metal and carbonate-bearing assemblages (mostly rhodochrosite) became dominant. Tellurides and some electrum occur as small rounded grains within subhedral-to euhedral pyrite or anhedral galena in stageII. Sulfide mineralization is zoned from pyrite to galena and sphalerite. We have used computer modeling to simulate formation of four stages of vein genesis. The reaction of a single fluid with andesite host rock at 28$0^{\circ}C$, isobaric cooling of a single fluid from 26$0^{\circ}C$ to 12$0^{\circ}C$, and boiling and mixing of a fluid with both decreasing pressure and temperature were studied using the CHILLER program. Calculations show that the precipitation of alteration minerals is due to fluid-andesite interaction as temperature drops. Speciation calculations confirm that the hydrothermal fluids with moderately high salinities and pH 5.7 (acid), were capable of transporting significant quantities of base metals. The abundance of gold in fluid depends critically on the ratio of total base metals and iron to sulfide in the aqueous phase because gold is transported as an Au(HS)$_2$- complex, which is sensitive to sulfide activity. Modeling results for Tongyeong mineralization show strong influence of shallow hydrogenic processes such as boiling and fluid mixing. The variable handing in stageII mineralization is best explained by maltiple boilings of hydrothermal fluid followed by lateral mixing of the fluid with overlying diluted, steam-heated ground water. The degree of similarity of calculated mineral assemblages and observed electrum composition and field relationships shows the utility of the numerical simulation method in identifying chemical processes that accompany boiling and mixing in Te-bearing Au-Ag system. This has been applied in models to narrow the search area for epithermal ores.

• Korean Chemical Engineering Research
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• v.48 no.4
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• pp.499-505
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• 2010

In this study, hydrodynamics and reaction characteristic of K-based solid sorbents for $CO_2$ capture were investigated using a continuous system composed of two bubbling fluidized-bed reactors(1.2 m tall bed with 0.11 m i.d.). Potassium-based dry sorbents manufactured by the Korea Electric Power Research Institute were used, which were composed of $K_2CO_3$ of 35% for $CO_2$ absorption and supporters of 65% for mechanical strength. The continuous system consists of two bubbling fluidized-bed reactors, solid injection nozzle, riser, chiller, analyzer and heater for regeneration reaction. The minimum fluidizing velocity of the continuous system was 0.0088 m/s and the solid circulation rate measured was $10.3kg/m^2{\cdot}s$ at 1.05 m/s velocity of the solid injection nozzle. The $CO_2$ concentration of the simulated gas was about 10 vol% in dry basis. Reaction temperature in carbonator and regenerator were maintained about $70^{\circ}C$ and $200^{\circ}C$, respectively. Differential pressures, which were maintained in carbonator and regenerator, were about $415mmH_2O$ and $350mmH_2O$, respectively. In order to find out reaction characteristics of dry sorbents, several experiments were performed according to various experimental conditions such as $H_2O$ content(7.28~19.66%) in feed gas, velocity (0.053~0.103 m/s) of simulated gas, temperature($60{\sim}80^{\circ}C$) of a carbonator, temperature($150{\sim}200^{\circ}C$) of a regenerator and solid circulation rate($7.0{\sim}10.3kg/m^2{\cdot}s$). The respective data of operating variables were saved and analyzed after maintaining one hour in a stable manner. As a result of continuous operation, $CO_2$ removal tended to increase by increasing $H_2O$ content in feed gas, temperature of a regenerator and solid circulation rate and to decrease by increasing temperature of a carbonator and gas velocity in a carbonator.

• Journal of the Korean Society of Groundwater Environment
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• v.5 no.4
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• pp.192-202
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• 1998

We investigated the geochemistry and environmental isotopes of granite-bedrock groundwater in the Yeongcheon diversion tunnel which is located about 300 m below the land surface. The hydrochemistry of groundwaters belongs to the Ca-HCO$_3$type, and is controlled by flow systems and water-rock interaction in the flow conduits (fractures). The deuterium and oxygen-18 data are clustered along the meteoric water line, indicating that the groundwater are commonly of meteoric water origin and are not affected by secondary isotope effects such as evaporation and isotope exchange. Tritium data show that the groundwaters were mostly recharged before pre-thermonuclear period and have been mixed with younger surface water flowing down rapidly into the tunnel along fractured zones. Based on the mass balance and reaction simulation approaches, using both the hydrochemistry of groundwater and the secondary mineralogy of fracture-filling materials, we have modeled the low-temperature hydrogeochemical evolution of groundwater in the area. The results of geochemical simulation show that the concentrations of Ca$\^$2＋/, Na$\^$＋/ and HCO$_3$and pH of waters increase progressively owing to the dissolution of reactive minerals in flow paths. The concentrations of Mg$\^$2＋/ and K$\^$＋/ frist increase with the dissolution, but later decrease when montmorillonite and illitic material are precipitated respectively. The continuous adding of reactive minerals, namely the progressively larger degrees of water/rock interaction, causes the formation of secondary minerals with the following sequence: first hematite, then gibbsite, then kaolinite, then montmorillonite, then illtic material, and finally microcline. During the simulation all the gibbsite is consumed, kaolinite precipitates and then the continuous reaction converts the kaolinite to montmorillonite and illitic material. The reaction simulation results agree well with the observed, water chemistry and secondary mineralogy, indicating the successful applicability of this simulation technique to delineate the complex hydrogeochemistry of bedrock groundwaters.