• Korean Journal of Agricultural Science
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• v.49 no.2
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• pp.357-366
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• 2022

Biochar can be obtained by using various types of biomass under an oxygen-limited condition. Biochar can be utilized for various applications such as soil improvement, waste management, growth promotion, and adsorption. Wood vinegar is produced by the process of pyrolysis wood biomass and is used as a growth promoter, for soil improvement, and as a feed additive. When wood vinegar is treated on soil, it acts to control soil pH, improve nutrient availability, and alleviate N₂O and NH₃ volatilization. The objective of this study was to evaluate the effect of biochar and wood vinegar on the growth of perilla and soil quality. The experiment was conducted by using a Wagner pot (1·5,000 a^-1) in a glass greenhouse. The biochar was produced by pyrolysis at 450℃ for 30 minutes using rice husk and rice straw. Wood vinegar was diluted to 1 : 500 (v·v^-1) and used in this experiement. In the results of a cultivation experiment, co-application of biochar and wood vinegar enhanced the growth of perilla. In particular, rice husk biochar affected the leaves of the perilla, and rice straw biochar influenced the stems of the perilla. In addition, soil quality after treatment with biochar and wood vinegar applied together was highest compared to other units. Therefore, it is anticipated that co-application of biochar and wood vinegar will be more productive and improve soil quality compared to individual utilization of biochar and wood vinegar.

• Bulletin of the Korean Chemical Society
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• v.28 no.12
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• pp.2271-2278
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• 2007

Electron transfer of a redox protein at a bare gold electrode is too slow to observe the redox peaks. A novel Nafion-riboflavin functional membrane was constructed during this study and electron transfer of cytochrome c, superoxide dismutase, and hemoglobin were carried out on the functional membrane-modified gold electrode with good stability and repeatability. The immobilized protein-modified electrodes showed quasireversible electrochemical redox behaviors with formal potentials of 0.150, 0.175, and 0.202 V versus Ag/AgCl for the cytochrome c, superoxide dismutase and hemoglobin, respectively. Whole experiment was carried out in the 50 mM MOPS buffer solution with pH 6.0 at 25 oC. For the immobilized protein, the cathodic transfer coefficients were 0.67, 0.68 and 0.67 and electron transfer-rate constants were evaluated to be 2.25, 2.23 and 2.5 s?1, respectively. Hydrogen peroxide concentration was measured by the peroxidase activity of hemoglobin and our experiment revealed that the enzyme was fully functional while immobilized on the Nafion-riboflavin membrane.

• Journal of the Speleological Society of Korea
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• no.71
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• pp.1-4
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• 2006

Chloromethylnaphthalene is a valuable compound for obtaining of the plant growing stimulator - -napthylacetic acid. Chloromethylation of naphthalene by paraformaldehyde in the presence of glacial acetic acid, phosphoric and hydrochloric acids at temperature 80 - 85C and duration - 6 hours the -chloromethylnaphthalene yield was 55-57%. Using Box-Wilson method for mathematical planning of experiment carried out optimization of its synthesis for purpose increasing -chloromethylnaphthalene yield. Preliminary, one - factor experiments were carried out for selecting independence main parameters influencing on the synthesis. A full factor experiment of 23 with extended matrix of planning was used for optimization. Aiming to increase the -chloromethylnaphthalene yield, the obtained mathematical model was used for program of sharp raising on the reply surface. The received optimal conditions for the -chloromethylnaphthalene synthesis were selected as following: molar ratio of naphthalene parapfsormaldehyde of 1 : 2 temperature - 105C duration of the reaction - 3 hours. The yield of -chloromethylnaphthalene under these optimal conditions was 75%.

• Proceedings of the Korean Environmental Sciences Society Conference
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• 2005.05a
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• pp.267-271
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• 2005

This experiment was carried out at 450"C, which is relatively lower than the temperature for supercritical water oxidation (600-650$^{\circ}C$). In this experiment, the decomposition rates of various incombustible organic substances were very high. In addition, it was confirmed that hetero atoms existed in organic compounds and chlorine was neutralized by sodium(salt formation).However, to raise the decomposition rate, relatively large amount of sodium nitrate(3-4 times the equivalent weight) was required. When complete oxidation is intended as in the case with PCB, the amount of oxidizer and decomposition cost is important. But when vaporization reduction is required as in the case with nuclear wastes, the amount of radioactive wastes increases instead. But as can be seen in the result of XRD measurement, unreacted sodium nitrate remained unchanged. If oxidation reaction of organic substance simply depends on collision frequency, unreacted sodium nitrate can be recovered and reused, then oxidation equivalent weight would be sufficient. In the gas generated, toxic gas was not found. As the supercritical water medium has high reactivity, it is difficult to generate relatively low energy level SO$_{X}$, and NO$_{X}$.

• Nuclear Engineering and Technology
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• v.53 no.4
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• pp.1088-1099
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• 2021

Time-frequency analysis technique is an effective analysis tool for non-stationary processes. In the field of reactor neutron noise, the time-frequency analysis method has not been thoroughly researched and widely used. This work has studied the time-frequency analysis of the reactor neutron noise experimental signals under bubble disturbance and control rod vibration. First, an experimental platform was established, and it could be employed to reactor neutron noise experiment and data acquisition. Secondly, two types of reactor neutron noise experiments were performed, and valid experimental data was obtained. Finally, time-frequency analysis was conducted on the experimental data, and effective analysis results were obtained in the low-frequency part. Through this work, it can be concluded that the time-frequency analysis technique can effectively investigate the core dynamics behavior and deepen the identification of the unstable core process.

• Journal of the Korean Chemical Society
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• v.15 no.5
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• pp.265-274
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• 1971

A significant structure theory of monolayer physical adsorption is developed. The theory is tested with the adsorptions on graphite of gases Ar, $N_2$, $CHCl_3$, and $CCl_4$. A restricted rotation model is used for the polyatomic molecules $N_2$, $CHCl_3$, and $CCl_4$. The computed isotherms and heats of adsorption are in good agreement with experiment in all cases studied.

• Journal of the Korean Chemical Society
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• v.49 no.6
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• pp.584-590
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• 2005

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2000.07a
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• pp.707-710
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• 2000

Optimization of the biphenyl chloromethylation process with para-formaldehyde has been investigated in the presence of ZnCl$_2$with HCI gas by the Box-Wilson method of mathematical planning of experiment. The 4,4'- (dichloromethyl)-biphenyl yield dependence on the biphenyl para-formaldehyde ratio, temperature and reaction duration has been studied. A mathematical model of the process has been developed and optimal conditions for the biphenyl chloromethylation procedure has been determined.

• Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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• 2004.05a
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• pp.77-79
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• 2004

Optimization of the biphenile chloromethylation process with paraphormaldegide has been done in the presence of ZnCl$_2$ with HCI gas by the Box-Wilson method of mathematical planning of experiment. The 4, 4'-( dichloromethyl)-biphenile yield dependence on the biphenile - paraphormaldegide ratio, temperature and reaction duration has been studied. A mathematical model of the process has been developed and optimal conditions for the biphenile chloromethylation procedure has been determined

• Bulletin of the Korean Chemical Society
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• v.7 no.6
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• pp.442-444
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• 1986

Starting with the readily available p-tert-butyl-calix[4]arene 2, tert-butyl groups are removed by $AlCl_3$-catalyzed de-alkylation reaction, and the calix[4]arene 3 formed is converted to the tetraacetate 4. This compound undergoes Fries rearrangement to yield p-acetylcalix[4]arene 6, which seems to be an attractive starting material for the introduction of functional groups. As a preliminary experiment p-(1-hydroxyethyl)calix[4]arene 7 is prepared by LiAlH$_4$ reduction of 6.