• 한국연소학회:학술대회논문집
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• 2014.11a
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• pp.1-4
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• 2014

The present work focuses on the analysis of the pulverized coal combustion aerodynamics of the dual swirl burner by the control of the swirl-modes such as the outer swirl intensity (OSI). The detailed structure of pulverized coal swirling flames with swirl-mode was studied experimentally by particle image velocimetry and local flame colors based on $OH^*$, $CH^*$, and ${C_2}^*$ radicals. For all co-swirling conditions, the internal recirculation zone (IRZ) was observed near the inner shear layer with respect to the processing vortex core structure. Furthermore, a co-rotating vortex in the outer shear layer and the exhaust tube vortex (ETV) along the central axis were observed. The intensity of $CH^*$ signal was higher with small coal particle size, conversely, the size of the distribution of the $CH^*$ signal becomes larger. Therefore, the control of the aerodynamics with changing swirl intensities may play an important role in improving both environmental and combustion performances.

• Proceedings of the KSME Conference
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• 2004.11a
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• pp.1116-1121
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• 2004

In this study, the effect of central fuel injection on a coaxial laminar $CH_{4}/air$ flame was experimented at the defined premixing condition(${\Phi}=1.90$, ${\sigma}=50/75/100%$, x/D=10). The partial premixing parameter are the equivalence ratio that total fuel is fixed at 200cc/min, the fuel split degree which means the percentage of fuel entering the outer tube to the total amount, and the mixing distance indicating the nonreactant mixture's homogeneity between inner tube top and burner exit. The object is to investigate the flame structure and chemiluminescence characteristics of laminar partial premixed flame as changing mixing parameters. The radical signal was acquired from ICCD camera and PMT. Each intensity was compared with Abel inverted value for measuring the effect of background light on the peak signal location and the intensity at central preheat zone. The results show that the peak location of each radical was broaden as the fuel split degree increasing because the mixing quality was enhanced. and $OH^{\ast}$ is a good indicator for flame front between reaction and preheat zone. At last $CH_{2}^{\ast}$ has the same tendency with $CH^{\ast}$ but a thinner reaction zone than $CH^{\ast}$ due to a rapid decay on the burned gas side.

• Journal of the Korean Society of Propulsion Engineers
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• v.22 no.1
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• pp.28-35
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• 2018

In order to analyze the flammability limit and structure of the gaseous methane-gaseous oxygen diffusion flame formed through a shear coaxial injector, combustion experiments were carried out according to the condition of injector recess and propellant mass-flow rate. As a result, it was confirmed that stable anchored flame was observed even at the high oxygen Reynolds number as the propellant momentum flux ratio increased, and that the recess had no significant influence on the flame shape and flammability limit. The anchored flame visualized through a chemiluminescence showed the maximum OH radical emission intensity at a specific position, irrespective of the propellant injection condition, and the radical intensity was greatly reduced by the injector recess.

• Transactions of the Korean hydrogen and new energy society
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• v.18 no.1
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• pp.75-84
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• 2007

The effects of hydrogen enrichment to methane on NOx formation have been investigated with swirl stabilized pre-mixed hydrogen enriched methane flame in a laboratory-scale pre-mixed combustor(nominally of 5,000 kcal/hr). The hydrogen enriched methane fuel and air were mixed in a pre-mixer and introduced to the combustor through different degrees of swirl vanes. The flame stability was examined for different amount of hydrogen addition to the methane fuel, different combustion air flow rates and swirl strengths by comparing equivalence ratio at the lean flame limit. The hydrogen addition effects and swirl intensity on the combustion characteristics of pre-mixed methane flames were examined using gas analyzers, and OH chemiluminescence techniques to provide information about species concentration of emission gases and flowfield. The results of NOx and CO emissions were compared with a diffusion flame type combustor. The results show that the lean stability limit depends on the amount of hydrogen addition and the swirl intensity. The lean stability limit is extended by hydrogen addition, and is reduced for higher swirl intensity at lower equivalence ratio. The addition of hydrogen increases the NOx emission, however, this effect can be reduced by increasing either the excess air or swirl intensity. The NOx emission of hydrogen enriched methane premixed flame was lower than the corresponding diffusion flame under the fuel lean condition.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.34 no.12
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• pp.1035-1042
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• 2010

The thermal stratification effect has been thought as one of the way to avoid dramatically generating the heat from HCCI combustion. We investigate the effect of thermal stratification on HCCI combustion fueled by DME and n-Butane. The thermal stratification occurs in a combustion chamber of a rapid compression machine with premixture by buoyancy effect that is made of fuel and air. The premixture is then adiabatically compressed, and during the process, the in-cylinder gas pressure is measured and two-dimensional chemiluminescence images are prepared and analyzed. Under the thermal stratification, the LTR starting time and the HTR starting time are advanced than that of homogeneous case. Further, the LTR period and the luminosity duration under homogeneous conditions are shorter than the corresponding quantities under stratified conditions. Additionally, under stratified conditions, the brightest luminosity intensity is delayed longer than that of homogeneous condition.

• Applied Chemistry
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• v.15 no.2
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• pp.113-116
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• 2011

A sensitive and selective determination method of Fe(II) ion by luminol-H₂O₂ system using a chelating reagent has been presented. A metal ion-chelating ligand complex such as Fe(II)-diethylenetriamine pentaacetic acid (DTPA) produced higher chemiluminescence (CL) intensity as well as longer lifetime in luminol-H₂O₂ system than metal exist as free ions. Furthermore, the catalytic activity of Cu(II) and Pb (II) complexes with chelating reagents in luminol-H₂O₂ system was lost since chelating reagents act as a masking agent although free Cu(II) and Pb(II) ions have high catalytic activity. On the optimized conditions, the calibration curve of Fe(II) ion was linear over the range from 1.0×10^-7 to 2.0×10^-5 M with correlation coefficient of 0.996. The detection limit was calculated to be 4.0×10^-8 M.

• 한국연소학회:학술대회논문집
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• 2006.10a
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• pp.73-78
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• 2006

The lifted oscillating flame has been studied using experiments of inverse diffusion flames that the air jet injected into a methane background. To find out the characteristics of inverse diffusion flames, fundamentally flame stabilized diagram is investigated with various air and fuel jet velocities. It has five regions - flame extinction, stable attached flame, anchored flame, liftoff flame and blow off region. In inverse diffusion flame, lifted flames were observed near the blow off region. As long as flames lift off, flames oscillate by periods. In this oscillating lifted flame region, the frequency of 1 and under were observed in various air and methane jet velocities. Characteristics of lifted flames are also examined by using the ICCD direct image. And intensity of flame chemiluminescence is very different in rising and falling period from photographs. For the present, it is predicted that the changes of flame structure are related with flame oscillation, but more experiments will be needed to make clear the phenomenon.

• Journal of the Korean Society of Combustion
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• v.7 no.3
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• pp.37-46
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• 2002

Characteristics of lifted flames in axisymmetric laminar coflow jets have been investigated experimentally. Approximate solutions for velocity and concentration accounting virtual origins have been proposed for coflow jets to analyze the behavior of liftoff height. From the measurement of Rayleigh intensity for probing the concentration field of propane, the validity of the approximate solutions was substantiated. From the images of OH PLIF and CH chemiluminescence and the Rayleigh concentration measurement, it has been shown that the positions of maximum luminosity in direct photography coincide with the tribrachial points, which were located along the stoichiometric contour. The liftoff height in coflow jets was found to increase highly nonlinearly with jet velocity and was sensitive to coflow velocity.

• Journal of the Korean Society of Combustion
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• v.15 no.2
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• pp.19-26
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• 2010

Combustion behavior of pulverized coal particles in a post-combustion gas reactor was investigated. Radiation emission from coal particles were analyzed by direct photograph and $CH^*$ radical chemiluminescence intensity. Coal particles were sampled during the combustion and were observed by scanning electron microscopy (SEM) and cross section micrograpy technique. Two coal types(one bituminous and one subbituminous coals typically used in the Korean power plants) were tested at typical combustion environment. Gas flow conditions were controlled to represent temperature and oxygen concentration. Experimental data were discussed along with conceptual descriptions of pulverized coal combustion, where particle heat-up, release and combustion of volatiles, and char combustion were sequentially progressed.

• Bulletin of the Korean Chemical Society
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• v.21 no.7
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• pp.701-704
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• 2000

Fluorene and carbazole-containing distyrylarylene model and polymeric fluorophores were prepared by reacting 2,7-dibromo-9-butylfluorene and 3,6-dibromo-9-butylcarbazole with styrene and divinylbenzene using the Heck reaction for the chemiluminesc ence. The UV-vis absorbance, photoluminescence (PL) as well as the chemiluminescence (CL) characteristics of the model and polymeric fluorophores were measured. Sodium salicylate-catalyzed reaction of bis(2,4,6-trichlorophenyl)oxalate (TCPO) with hydrogen peroxide produced a strong chemiluminescent blue light emission with 439-489 nm in the presence of the fluorophore. The wave-length of CL light was similar to that of photoluminescence. The chemiluminescent intensity was decayed according to the exponential equation.The glow of CL maintained more than 12 hr and was visible with naked eye.