• Title/Summary/Keyword: Chemical-structural properties

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Design of Natural Fiber Composites Chemical Container Using Resin Flow Simulation of VARTML Process

  • Lee, Haseung;Park, Gwanglim;Kong, Changduk;Park, Hyunbum
    • International Journal of Aerospace System Engineering
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    • v.1 no.1
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    • pp.21-28
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    • 2014
  • In this study, an investigation on mechanical properties of flax natural fiber composite is performed as a precedent study on the design of eco-friendly structure using flax natural fiber composite. The Vacuum Assisted Resin Transfer Molding-Light (VARTML) manufacturing method is adopted for manufacturing the flax fiber composite panel. The VARTML is a manufacturing process that the resin is injected into the dry layered -up fibers enclosed by a rigid mold tool under vacuum. In this work, the resin flow analysis of VARTM manufacturing method is performed. A series of flax composite panels are manufactured, and several kinds of specimens cut out from the panels are tested to obtain mechanical performance data. Based on this, structural design of chemical storage tank for agricultural vehicle was performed using flax/vinyl ester. After structural design and analysis, the resin flow analysis of VARTM manufacturing method was performed.

Molecular Dynamics Simulation on thermodynamic and Structural Properties of Liquid Hydrocarbons : Normal Alkanes

  • Im, Won-Pil;Won, Young-Do
    • Bulletin of the Korean Chemical Society
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    • v.15 no.10
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    • pp.852-856
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    • 1994
  • A series of aliphatic hydrocarbons, methane to hexane in the liquid state, are modeled with the molecular mechanical potential parameters treating all hydrogen degrees of freedom explicitly. Thermodynamic properties (heat capacities and heats of vaporization) are calculated from relatively short (20ps) molecular dynamics trajectories. The liquid state structures are also examined through various radial distribution functions. Molecular dynamics simulations reproduce experimentally measured properties within a few percent errors, thus indicate that the present set of all-hydrogen parameters is suitable for simulating macromolecular systems in bulk.

Periplasmic glucans isolated from Proteobacteria

  • Lee, Sang-Hoo;Cho, Eun-Ae;Jung, Seun-Ho
    • BMB Reports
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    • v.42 no.12
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    • pp.769-775
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    • 2009
  • Periplasmic glucans (PGs) are general constituents in the periplasmic space of Proteobacteria. PGs from bacterial strains are found in larger amounts during growth on medium with low osmolarity and thus are often been specified as osmoregulated periplasmic glucans (OPGs). Furthermore, they appear to play crucial roles in pathogenesis and symbiosis. PGs have been classified into four families based on the structural features of their backbones, and they can be modified by a variety of non-sugar substituents. It has also recently been confirmed that novel PGs with various degrees of polymerization (DPs) and/or different substituents are produced under different growth conditions among Proteobacteria. In addition to their biological functions as regulators of low osmolarity, PGs have a variety of physico-chemical properties due to their inherent three-dimensional structures, hydrogen-bonding and complex-forming abilities. Thus, much attention has recently been focused on their physico-chemical applications. In this review, we provide an updated classification of PGs, as well as a description of the occurrences of novel PGs with substituents under various bacterial growth environments, the genes involved in PG biosynthesis and the various physico-chemical properties of PGs.

Properties of Ge,Ga and Ga-doped ZnO thin films prepared by RF magnetron sputtering (RF magnetron sputtering으로 생성한 Ga,Ge와 Ga이 도핑된 ZnO 박막의 특성)

  • Jung, Il-Hyun;Kim, Yu-Jin;Park, Jung-Yoon;Lee, Ru-Da
    • Journal of the Semiconductor & Display Technology
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    • v.9 no.3
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    • pp.41-45
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    • 2010
  • The ZnO thin films doped with Ga(GZO) and both Ga and Ge(GZO:Ge) were deposited on glass substrate by using RF sputtering system respectively. Structural, morphological and optical properties of the films deposited in the same condition were investigated. Structural properties of the films were investigated by Field Emission Scanning Electron Microscopy, FE-SEM images and X-ray diffraction, XRD analysis. These studies showed shape of films' surface and direction of film growth respectively. It's showed that all films were deposited by vertical orientation strongly. It can be confirmed that all dopants of targets were included in deposited films by results of EDX analysis. UV-Vis spectrometer results showed that all samples had highly transparent characteristics in visible region and have similar 3.28~3.31 eV band gap. It was found that existence of all dopants by EDX analysis. Morphology and roughness of surface of each film were clearly shown by Atomic Force Microscopy, AFM images. It was found in this research that film doped with Ge more dense and stable with hardly any difference in gap energy compared to ZnO films.

Cation Ordering and Microwave Dielectric Properties of $Ba(Mg_{1/3}Nb_{2/3})O_3$ Ceramics: II. Local Order-Disorder Phase Transition and Second Phase formation ($Ba(Mg_{1/3}Nb_{2/3})O_3$세라믹스의 양이온 규칙구조와 유전특성: II. 국부적 규칙-불규칙 상전이와 이차상 생성 거동)

  • 김영웅;박재환;김긍호;김윤호;박재관
    • Korean Journal of Crystallography
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    • v.12 no.2
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    • pp.81-87
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    • 2001
  • We have studied the effect of sintering temperature and time on the cation ordering and second phase formation in Ba(Mg/sub 1/3/Nb/sub 2/3/)O₃(BMN) microwave ceramics by using transmission electron microscopy. The relationship between the structural-chemical behavior arid microwave dielectric properties has also been investigated. It is revealed that according to the sintering conditions the BMN ceramics show very diverse local ordering behavior, such as the development of domain twinning and "core-shell"-structured grains and the formation of local disordered domains, though having 1 : 2 cation ordering structure basically. The disordered structure is found in Mg-excess region. Such local chemical variation seems to be caused by the formation of BaNb₂O/sub 6/-like second phase in its neigh-boring grain boundary. The microwave dielectric quality factor of the ceramics decreases greatly with the increase of the structural-chemical inhomogeneity and diversity.

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STRUCTURAL MORPHOLOGY AND DIELECTRIC PROPERTIES OF POLYANILINE-EMERALDINE BASE AND POLY METHYL METHACRYLATE THIN FILMS PREPARED BY SPIN COATING METHOD

  • Shekar, B. Chandar;Yeon, Ji;Rhee, Shi-Woo
    • 한국정보디스플레이학회:학술대회논문집
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    • 2003.07a
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    • pp.1081-1084
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    • 2003
  • Structural morphology, annealing behavior and dielectric properties of polyaniline-emeraldine base (Pani-EB) and poly methyl methacrylate (PMMA) thin films prepared by spin coating technique have been studied. MIM and MISM structures were used to investigate annealing and dielectric behavior. The XRD and AFM spectrum of as grown and annealed thin films indicates the amorphous nature. The observed amorphous phase, low loss, dielectric behavior and thermal stability even at high temperatures implies the feasibility of utilizing PMMA and Pani-EB thin films as gate dielectric insulator layer in organic thin film transistors which can find application in flat panel display.

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Technical Status of Carbon Nanotubes Composites (탄소나노튜브 복합체의 기술동향)

  • Lee, Jong-Il;Jung, Hee-Tae
    • Korean Chemical Engineering Research
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    • v.46 no.1
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    • pp.7-14
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    • 2008
  • Carbon nanotubes are considered as the most ideal nano filler in the field of composites with their excellent electrical, mechanical, and thermal properties. Therefore carbon nanotubes composites are increasingly utilized in conductive materials, structural material with high strength and low weight and multifunctional material. This review article describes recent research trend of carbon nanotubes synthesis, modification, various properties of the carbon nanotubes composites and their application. Furthermore the future development direction for the commercialization of carbon nanotubes composites is proposed.

Critical evaluation of a Nigerian sub-bituminous coal potential for energy derivation

  • Odeh, Andrew O.
    • Advances in Energy Research
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    • v.4 no.3
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    • pp.203-211
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    • 2016
  • A good understanding of the chemical composition and structural characteristics of a carbonaceous material is essential in conversion processes. Understanding how the composition and structural changes influence the burning behaviour of coal is important when assessing a coal's potential for utilization. To explore the potentials of a typical Nigerian coal, both conventional and advanced analytical techniques such as proximate analysis, ultimate analysis, calorific value, surface area analyser, SEM, FTIR, XRD and SAXS were employed. The results obtained from these characterizations agree favourable well with a typical South African coal that is of enormous contribution to the gross domestic product (GDP) of the nation economy.

Characterization of Insulation Materials for Low Voltage Cables in a Nuclear Power Plant with ${\gamma}$-Ray Irradiation (방사선조사에 따른 원전 저압케이블용 절연재료의 특성분석)

  • 박정기;이우선;한재홍
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.14 no.5
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    • pp.397-404
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    • 2001
  • This study describes the effect of γ-ray irradiation on the properties of insulation materials for low voltage cables in a nuclear power plant. The radiation effects were characterized by measuring OIT, FTIR, electrical properties of the irradiated specimens. As a result, they showed the decrease of OIT and the increase of chemical structural defects with the increase of γ-ray amount. Also, the electrical properties such as dielectrical constant, tan $\delta$ and current were changed by aging. These changes may come from the increase of chemical structural defects by $\delta$-ray irradiation.

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