• Elastomers and Composites
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• 제38권2호
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• pp.167-174
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• 2003

Thermoplastic vulcanizates (TPV) or dynamic vulcanizates are thermoplastic elastomers produced by simultaneous mixing and crosslinking of a rubber and a thermoplastic. The objective of the present work is to investigate the effects of different types of peroxides as curing agents on the properties of PP/EPDM TPVs. The mechanical properties change significantly with the chemical nature of the peroxides and the extent of crosslinking at a fixed PP/EPDM blend ratio. The tensile strength of the TPVs obtained with the various peroxides can be related to the solubility parameters of the polymers and of the peroxides. The Young's modulus of the peroxide-cured TPVs can be correlated with the delta torque values of equivalent thermoset EPDM vulcanizates, corresponding to the crosslinking efficiencies of the peroxides.

• 한국기계가공학회지
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• 제19권6호
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• pp.88-95
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• 2020

Currently, Fiber-Reinforced Plastic (FRP) composite materials are used in many industrial fields, owing to their superior stiffness and specific strength compared to metals. However, there are issues with FRP inefficiency, due to low productivity of such materials, environmental problems they pose and long curing times needed. Trying to address these issues, research was conducted towards the development of a FRP composite material with excellent properties and short production time, introducing a curing method using a UV lamp. Four types of composite materials were prepared, cured with catalyst or UV (CZ: Catalyst + ZNT 6345, CR: Catalyst + RF 1001 MV, UVZ: Photoinitiator + ZNT 6345, and UVR: Photoinitiator + RF 1001 MV). Examination of the chemical and mechanical properties of these composites showed that UV-cured materials performed better than the catalyst-cured ones. These results indicate that the production process of FRP composite materials can be simplified by using a UV lamp for curing, resulting in composite materials with the same quality, but reduced production time by about 70% compared to currently used practices. This advancement will contribute greatly to the composite material industry.

• Elastomers and Composites
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• 제29권5호
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• pp.436-443
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• 1994

Melamine resin was mixed with polybutadiene rubber or wood flour in the ranges of $5{\sim}75%(wt.%)$. For mixtures, physical and thermal properties were tested experimentally. Physical properties were mainly influenced on the dispersed states of rubber or wood flour. The highest flexural and impact strength were obtained at wood flour content $65{\times}67%$. Rubber was homopolymerized by hardner, or partially copolymerized with melamine resin. At rubber content $3{\sim}6%$, cured products represented lower modulus without decreasing mechanical strength.

• Elastomers and Composites
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• 제22권4호
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• pp.305-313
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• 1987

In this study, as one of the developing ways of the functional elastomer, improvement of the functionality of 1-Chlorobutadiene-Butadiene Copolymer(CB-BR) was attempt through curing reaction by moisture. The curing reaction of CB-BR was determined an use of $\gamma$-Aminopropyltriethoxysilane(APS) and $\gamma$-Aminopropylmethyldiethoxysilane(ADS) as a crosslinking agent with filler at so the uncrosslinked elastomer was exposured in the air and curing reaction by moisture in the air was studied. The results obtained are as follows. 1. APS was more efficient than ADS as a crosslinking agent for CB-BR 2. Optimum amount of APS for moisture cured elastomer was r=1.5(at the ratio of $[APS]/[Cl^*]$) also in case(r=1.5), elastomer formed after soaking $T_{72}$ had similar physical properties with elastomer crosslinked by sulfur and it was very good. 3. Uncrosslinked elastomer(CB-BR+APS+Silica) was easily crosslinked by exposure to the air, and the physical properties was also satisfactory.

• Korean Chemical Engineering Research
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• 제50권4호
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• pp.621-626
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• 2012

본 연구에서는 마이크로 기공의 중공구를 유기 고분자 수지와 복합화한 유/무기 하이브리드 물질을 제조하여 우수한 단열 성능을 갖는 코팅유리를 개발하고자 하였다. 유기 고분자 물질로는 투명성과 접착성이 우수한 6관능기의 우레탄 아크릴레이트(UP118), 3관능기의 trimethylolpropane triacrylate (TMPTA), 2관능기의 1,6-hexanediol diacrylate (HDDA), 광 개시제(Irgacure184) 등으로 구성된 자외선 경화형 수지를 사용하였다. 유리 및 실리카 중공구를 고분자 수지에 각각 10~40 vol%까지 첨가하여 얻어진 코팅 졸을 투명유리에 바(bar)코팅 방식으로 박막을 형성시킨 후 자외선 경화를 통해 최종 코팅유리를 제조하였다. 마이크로 중공구의 종류 및 함량이 제조된 코팅유리의 광 투과율, 열전도도, 접착성 및 표면 경도에 미치는 영향을 조사하였다. 복합물 코팅유리는 중공구가 과량 첨가되어도 우수한 접착성(5B)을 유지하였으며, 단열 성능은 각 중공구가 20 vol%만 함유되어도 뚜렷하게 향상된 결과를 나타냈다. 또한 실리카 중공구(SP)를 단열 재료로 사용하였을 경우 광 투과율 80 %의 투명 코팅유리를 얻을 수 있었다.

• Elastomers and Composites
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• 제33권4호
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• pp.267-273
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• 1998

MDI와 에스테르타입의 폴리올인 EBA, NBA, HA를 각각 반응시켜 이소시아네이트 말단기를 갖는 다양한 우레탄 프리폴리머를 합성하였다. 합성된 프리폴리머는 상온에서는 100% 고형분이었으며, 약 $80^{\circ}C$로 가열하면 용융되어 도포에 적당한 흐름성을 나타내었고, 냉각하면 고화되고 습기와 반응하면서 서서히 경화되었다. 대기중의 습기와 반응하여 경화된 우레탄수지의 인장물성은 폴리올의 구조에 따라 특징적인 거동을 나타내었다. 접착력은 EBA, NBA, HA순의 큰 값을 나타내었으며, 이는 동일한 조건에서 가교된 우레탄수지의 파단에너지와 같은 경향을 나타내었다. 또한, 접착조인트의 파괴는 모두 접착제 자체에서 일어났으며, 시험속도가 증가함에 따라 증가하였다. 이로 미루어, 우레탄 핫멜트 접착제 자체의 강인성이 접착력을 결정하는 주요 요인임을 알 수 있었다.

• Composites Research
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• 제35권6호
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• pp.412-418
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• 2022

메타크릴산과의 에스터화 반응을 통해 브롬화 에폭시 수지와 일반 에폭시 수지의 혼합물로부터 난연성 비닐에스터 핫멜트 필름을 제조하였고 이를 이용하여 탄소섬유와 비닐에스터 복합 프리프레그를 제조하였다. 저점도 비스페놀-A와 고점도 브롬화 비스페놀-A 에폭시 전구체를 혼합하여 필름 생산에 적합한 VE 수지의 점도를 최적화하였다. 경화된 VE 수지의 브롬 함량 증가는 비 브롬화 VE에 비해 제한 산소 지수(LOI)(39%), 25℃에서의 저장 탄성률(2.4 GPa) 및 잔류 탄화물(16.1%) 값을 더 증가시켰다. 합성한 VE 프리프레그의 수동 레이업과 후속 경화로 인장 및 굴곡 강도가 우수한 CF 강화 복합재를 성공적으로 제작하였다. 본 연구 결과는 스티렌이 없는 친환경적인 VE 복합 재료 공정의 향후 산업화에 대한 높은 가능성을 보여준다.

• Restorative Dentistry and Endodontics
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• 제28권5호
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• pp.369-377
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• 2003

The aim of this study was to evaluate the effect of two polishing methods and chemical conditioning on the surface of hybrid composites. Ninety cylindrical specimens (diameter：8mm, depth：2mm) were made with three hybrid composites-Filtek Z250, Tetric Ceram. DenFil. Specimens for each composite were randomly divided into three treatment subgroups $^{\circled1}$ Mylar strip (no treatment). $^{\circled2}$ Sof-Lex XT system, $^{\circled3}$ PoGo system. Average surface roughness(Ra) was taken using a surface profilometer at the time of setting and after immersion into 0.02N lactic acid for 1 week and 1 month. Representative specimens were examined by scanning electron microscopy. The data were analyzed using ANOVA and Scheffe's tests at 0.05% significance level. The results were as follows：1. Mylar strip resulted in smoother surface than PoGo and Sof-Lex system (p<0.001). Sof-Lex system gave the worst results. 2. Tetric Ceram was smoother than DenFil and Z250 when cured under only mylar strip. However, it was significantly rougher than other materials when polished with PoGo system. 3. All materials showed rough surface after storage in 0.02N lactic acid, except groups polished with a PoGo system. The PoGo system gave a superior polish than Sof-Lex system for the three composites. However. the correlation to clinical practice may be limited, since there are several processes. such as abrasive, fatigue, and corrosive mechanisms. Thus. further studies are needed for polishing technique under in vivo conditions.

• Bulletin of the Korean Chemical Society
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• 제33권11호
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• pp.3706-3710
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• 2012

A novel silicon-containing arylacetylene resin (MSAR) modified by dipropargyl ether of bisphenol A (DPBPA) and dipropargyl ether of perfluorobisphenol A (DPPFBPA) was prepared separately. The curing behaviors of modified resins, DPBPA/MSAR and DPPFBPA/MSAR, were characterized with differential scanning calorimeter (DSC). The kinetic parameters of modified resins were obtained by the Kissinger and Ozawa methods. The results of dynamic mechanical analysis (DMA) revealed that the glass transition temperature ($T_g$) of the cured DPBPA/MSAR reached $486^{\circ}C$. According to the thermogravimetric analysis (TGA), the decomposition temperature ($T_{d5}$) of the cured resins and char yield ($Y_c$, $800^{\circ}C$) decreased as the dipropargyl ether loadings increased, especially in air. With the same weight loading, thermal stability of DPBPA/MSAR was better than that of DPPFBPA/MSAR. The carbon fiber (T300) reinforced composites exhibited excellent flexural properties at room temperature with a high property retention at $300^{\circ}C$.

• Elastomers and Composites
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• 제44권1호
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• pp.41-46
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• 2009

천연고무의 일정하중 영구압축률에 온도와 가교시스템이 미치는 영향을 고찰하였다. 다양한 가교시스템과 가교밀도의 고무시편을 만들기 위해 여러 가지 함량의 황과 dicumyl peroxide(DCP)를 사용하여 배합하였으며, 가교된 천연고무의 일정변위 조건에서 측정된 영구압축률과 일정하중에서 측정된 영구압축률의 차이를 비교하였다. 일정하중 영구압축률은 일정변위 영구압축률에 비해 가교밀도의 변화에 따라 상대적으로 큰 차이를 보였으며, 이는 영구압축률 측정 시 공급된 변형에너지가 다르기 때문이다. 또한 일정하중 영구압축률 측정에서 황으로 가교시킨 시편의 경우 하중과 온도증가에 따라 영구압축률이 크게 증가하였고, 이에 반해 DCP로 가교시킨 시편의 경우 하중과 온도증가에 큰 영향을 받지 않았다.