• Title/Summary/Keyword: Chemical treatments

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Study of Chemical Parameters on Butchery wastes as a Bulking Agent in Composting of Swine Manure (돈분의 퇴비화에 있어 원보조재의 혼합비에 따른 최종산물의 화학적인 조성 연구)

  • 이상환;김인호;홍종욱;권오석;김정우
    • Korean Journal of Organic Agriculture
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    • v.9 no.3
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    • pp.93-101
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    • 2001
  • This study was conducted to evaluate chemical parameters on butchery wastes as a bulking agent in composting of swine manure. Treatments included T1 : Swine manure + Rice hull, T2 ; Swine manure + Rice hull + Vermiculite, T3 ; Swine manure + Rice hull + Perlite, T4, Swine manure + Vermiculite, T5 : Swine manure + Vermiculite + Perlite, T6 ; Swine manure + Perlite, T7 ; Swine manure + lice hull + Vermiculite + Perlite. During the composting period, changes of temperature and pH were showed traditionally composting trend. Moisture, organic matter, total nitrogen and C/N ratio were higher rice hull than vermiculite and perlite treatments. Ammonia-N and EC were not differences among the treatments. In heave metal, Cd and Cr were showed higher in vermiculite treatments than other treatments. Rice hull treatments were decreased volatile fatty acids compared to that of other treatments. In conclusion, rite hull containing high organic content was greater composting effects than vermiculite and perlite containing low organic content.

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Effects of Lime Applications on Chemical Properties of Soil and Rice Yields in Long-term Fertilization Experiment

  • Kim, Myung-Sook;Park, Seong-Jin;Lee, Chang-Hoon;Yun, Sun-Gang;Ko, Byong-Gu;Kim, Yoo-Hak
    • Korean Journal of Soil Science and Fertilizer
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    • v.48 no.4
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    • pp.233-239
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    • 2015
  • Monitoring of soil fertility and crop productivity in long-term application of fertilizers is necessary to use fertilizers efficiently. This study was conducted to investigate effects of continuous application of lime for rice cultivation from 1969 to 2014. The treatments were no lime treatments (N, NPK, NPKC, and NPKS) and lime treatments (N+L, NPK+L, NPKC+L, and NPKS+L). The application of lime in addition to N, NPK, and NPKC tended to increase pH, exchangeable Ca, and available $SiO_2$. The input of mean annual $1,170Mg\;ha^{-1}yr^{-1}$ of lime increased pH $0.0042yr^{-1}$, $0.0062yr^{-1}$, $0.0127yr^{-1}$, and $0.0041yr^{-1}$ in lime treatments (N+L, NPK+L, NPKS+L, and NPKC+L) compared with no treatments (N, NPK, NPKS, and NPKC), respectively. The mean annual Ca field balance varied from 169 to $561kg\;ha^{-1}yr^{-1}$in no treatments, from 871 to $1,263kg\;ha^{-1}yr^{-1}$ in lime treatments, indicating that Ca was accumulated in the soils. The mean annual Ca field balance in silicate fertilizer treatments (NPKS, NPKS+L) were higher than that of other treatments because silicate fertilizer included Ca component. Grain yield of rice had no significant differences between no lime treatments and lime treatments. Thus the application of lime led to changes in soil chemical properties but had no impact on the production of rice.

The Influence of Cyclic Treatments with H₂O₂ and HF Solutions on the Roughness of Silicon Surface

  • 이혜영;이충훈;전형탁;정동운
    • Bulletin of the Korean Chemical Society
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    • v.18 no.7
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    • pp.737-740
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    • 1997
  • The influence of cyclic treatments with H2O2/DIW (1 : 10) and HF/DIW (1 : 100) on the roughness of silicon surface in the wet chemical processing was investigated by atomic force microscopy (AFM). During the step of the SC-1 cleaning, there is a large increase in roughness on the silicon surface which will result in the poor gate oxide breakdown properties. The roughness of the silicon wafer after the SC-1 cleaning step was reduced by cyclic treatments of hydrogen peroxide solution and hydrofluoric acid solution instead of HF-only cleaning. AFM images after each step clearly illustrated that the average roughness of silicon surface after three times treatments with H2O2 and HF solutions was reduced by 10 times compared with that after the SC-1 cleaning step.

Effects of Ammonia, Urea Plus Calcium Hydroxide and Animal Urine Treatments on Chemical Composition and In sacco Degradability of Rice Straw

  • Fadel Elseed, A.M.A.;Sekine, J.;Hishinuma, M.;Hamana, K.
    • Asian-Australasian Journal of Animal Sciences
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    • v.16 no.3
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    • pp.368-373
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    • 2003
  • This experiment was conducted to examine the effects on the composition and rumen degradation in sacco of rice straw treated with animal urine (1 l of 2.9 g N/kg DM straw) and urea plus calcium hydroxide (2% urea plus 0.5% $Ca(OH)_2$/kg DM straw) as a cheap and relatively safe alternative for ammonia (3% ammonia solution/kg DM straw). Mold occurred in urine treated straw, but other treatments were apparently mold-free. All treatments significantly (p<0.05) increased CP content in the straw compared with untreated one. Ammonia-treated straw contained CP at about twice that in urine or urea-calcium hydroxide treated straw. NDF and hemicellulose contents decreased significantly (p<0.05) in all treatments, while ADF and cellulose showed no differences compared with untreated straw. The degradable fraction of DM, CP, NDF, hemicellulose and cellulose was significantly (p<0.05) increased for ammonia and urea-calcium hydroxide treatments than for urine treated or untreated straw except for CP of urine treated straw. Chemical treatment of rice straw increased the readily degradable fraction of CP, while it decreased the slowly degradable fraction for urine or urea-calcium hydroxide treated rice straw. The degradation rate of hemicellulose was significantly (p<0.05) increased for ammonia and urea-calcium hydroxide treatments compared to urine treated or untreated straw. However, no effect on cellulose degradation rate was found by any of the treatments. There was no improvement in the degradation kinetics caused by the urine treatment despite the improvement of the chemical composition. Although the improvement in rumen degradability was less in the urea-calcium hydroxide treatment than in the ammonia treatment, its use may be more desirable because it is less expensive to obtain, less hazardous nature, and readily available. For further improvement it is necessary to investigate the supplementation of slowly degradable nitrogen to ureacalcium hydroxide treated rice straw diet.

Electrochemical Performance of Activated Carbon Electrode Materials with Various Post Treatments for EDLC (활성탄의 후 처리에 의한 EDLC 전극재의 전기화학 성능 개선)

  • Lee, Eunji;Kwon, Soon Hyung;Choi, Pooreum;Jung, Ji Chul;Kim, Myung-Soo
    • Korean Journal of Materials Research
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    • v.24 no.6
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    • pp.285-292
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    • 2014
  • Commercial activated-carbon used as the electrode material of an electric double-layer capacitor (EDLC) was posttreated with various acids and alkalis to increase its capacitance. The carbon samples prepared were then heat-treated in order to control the amount of acidic functional groups formed by the acid treatments. Coin-type EDLC cells with two symmetric carbon electrodes were assembled using the prepared carbon materials and an organic electrolyte. The electrochemical performance of the EDLC was measured by galvanostatic charge-discharge, cyclic voltammetry, and electrochemical impedance spectroscopy. Among the various activated carbons, the carbon electrodes (CSsb800) prepared by the treatments of coconutshell-based carbon activated with NaOH and $H_3BO_5$, and then heat treated at $800^{\circ}C$ under a flow of nitrogen gas, showed relatively good electrochemical performance. Although the specific-surface-area of the carbon-electrode material ($1,096m^2/g$) was less than that of pristine activated-carbon ($1,122m^2/g$), the meso-pore volume increased after the combined chemical and heat treatments. The specific capacitance of the EDLC increased from 59.6 to 74.8 F/g (26%) after those post treatments. The equivalent series resistance of EDLC using CSsb800 as electrode was much lower than that of EDLC using pristine activated carbon. Therefore, CSsb800 exhibited superior electrochemical performance at high scan rates due to its low internal resistance.

Effects of Gamma-ray and Chemical Mutagens on the Germination and Seedling Growth in Stevia rebaudiana Bert. (감마선 및 화학적 돌연변이원 처리가 스테비아 (Stevia rebaudiana Bert.)의 종자 발아 및 초기 생장에 미치는 영향)

  • Yoon, Tai-Young;Kim, Ee-Youb;Kim, Young-Ho;Choi, Gin-Su;Hyun, Kyung-Sup;Seong, Yoon-Hee;Jo, Han-Jig;Kim, Dong Sub;Kang, Si-Yong;Ko, Jeong-Ae
    • Journal of Radiation Industry
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    • v.6 no.2
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    • pp.189-197
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    • 2012
  • This study was carried out to develop the improved useful mutants for yield or composition of stevia plants using the gamma ray or chemical mutagens treatments. The seeds of stevia 'Suwon No. 11' were irradiated up to 400 Gy of gamma ray. Chemical mutagens were treated on the seeds of the 'Suwon No. 11' using 0.07% colchicine, 10 mM sodium azide, or 10 mM NMU for various durations. The germination rate, and shoot and root growth of seedling were estimated at 30 days after gamma ray irradiation or chemical mutagen treatment, and the plant height, the number of branches, and leaf length and width were examined at 3 months after mutagenesis treatments. In the case of gamma ray treatments, the germination rate and early-stage growth were decreased as the increase of radiation dose, and the 50% lethal dose was found to be 200 Gy. the plant height was decreased as the increase of radiation dose, while the number of branches per plant and leaf length were increased. Leaf shape was modified to the relatively longer one compared to the control, which was identified more apparently at the treatments of higher than 150 Gy. In the treatment of chemical mutagens, the rate of germination and survival were decreased as the increase of incubation time. The 50% lethal dose for germination rate were identified as the conditions of the 15 hours incubation in 0.07% colchicine, the 4 hrs in 10 mM sodium azide, and the 2 hrs in 10 mM NMU, in the three chemical mutagens treatments. Chemical mutagens had no influence on shoot growth, while root growth was increased, especially as the incubation time was extended. The highest root growth occurred in the NMU treatment at 6 hrs incubation time. The plant height was decreased as the increase of incubation time in the chemical mutagens treatments. Among the chemical mutagens, NMU was the most effective to induce the mutants with long-shaped or the least lobed leaves.

Chemical Modification of Wood with Alkylene Oxides, Vinylpirrolidinone and Furans:Effects on Dimensional Stabilization

  • Guevara, R.;Moslemi, A.A.
    • Journal of the Korean Wood Science and Technology
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    • v.10 no.4
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    • pp.38-52
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    • 1982
  • The effect of propylene oxide, butylene oxide, furan resin, and vinylpyrrolidinone in controlling wood dimensional stability have been examined. Wood in the green or ovendry condition was treated with various chemical treatments using a vacuum-pressure procedure, and treated specimens were tested for tangential sweelling, moisture gain, and changes in sorption hysteresis. Results' indicate that propylene oxide, and butylene oxide enhanced with the crosslin king agent trimethylol propane trimethacrylate and applied to ovendry wood were the most efficient chemical treatments in controlling tangential sweeling caused by liquid water or water vapor, and in reducing water vapor adsorption. The sorption behavior of treated wood as depicted by the ratios of sorption was "very favorable" in most instances. In the particular case of furan resin treatments, ratios of sorption were improved from 25 to 100 percent as compared to those of untreated wood.

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Effect of Pig Slurry Application on the Mineral Content of Leaf, Fruit Quality and Soil Chemical Properties in Pear Orchard (돈분 액비 시용이 배나무 잎의 무기성분 함량, 과실특성과 토양화학성에 미치는 영향)

  • Park, Jin-Myeon;Lim, Tae-Jun;Lee, Seong-Eun
    • Korean Journal of Soil Science and Fertilizer
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    • v.45 no.2
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    • pp.209-214
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    • 2012
  • This experiment was carried out to investigate the replaceability of chemical fertilizer by SCB liquid fertilizer (SCB) in pear orchard for 5 years. The effects on the mineral content of leaf, fruit quality, yield and soil chemical properties are as follows: The mineral content of leaf showed no difference between the treatments; two SCB liquid fertilizer treatments based on the N (SCB-N) and K (SCB-K) content, and control (chemical fertilizer application). There were no significant differences in yield, titratable acidity and weight of the fruit although the figure of fruit weight was high in SCB-N treatment. Soluble solids content was higher in the SCB treatments than the control. Soil chemical properties such as the content of soil organic matter, available soil phosphate and exchangeable cation were not different, although soil pH was higher in SCB treatments. In conclusion, it is suggest that the use of chemical fertilizer in pear orchard could be replaced by the application of SCB liquid fertilizer because of the same effect on the growth of pear tree and soil chemical properties.

Growth and Fruiting Characteristics, and Nut Qualities of Castanea crenata by Low-Concentrated Liquid Fertilizer (저농도 액비처리에 따른 밤나무 생장 및 결실특성과 과실품질)

  • Lee, Uk;Hwang, Suk-In;Kim, Mahn-Jo;Kim, Ji-Hye
    • Journal of Korean Society of Forest Science
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    • v.100 no.3
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    • pp.432-440
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    • 2011
  • The objective of this study was to investigate growth and fruiting characteristics (e.g., nut qualities) of chestnut (Castanea cerenata) after applying various fertilizer treatments at the cultivation site in Suncheon. Fertilizer treatments were designed as follow: liquid fertilizer, chemical fertilizer, organic fertilizer, and control. Both liquid and chemical fertilizer treatments provided the best growth in height and basal diameter. In addition, these two treatments were very effective for crown width of the trees between both east-west and north-south orientation. The liquid fertilizer treatment was effective on total length of the fruiting branch and length of the bearing to terminate part. Both liquid and chemical fertilizer treatments produced the longest length of basal to bearing part compared to the other two treatments. The liquid fertilizer treatment showed the most thickened basal diameter of the fruiting branch and the greatest diameter of above and below the bearing burr part. Elongation Index of the fruiting branch (EI) was the highest with liquid fertilizer treatment and the remaining four indices (Production Index of fruiting branch, PI; Ratio of Diameter between below and above bearing burr part, RD; Growth Index of fruiting branch diameter, GI; Thickness Index of fruiting branch or dormant branch, TI) were the highest with the chemical fertilizer treatment. Total number of produced branch per fruiting mother branch and number of small and weak branches per fruiting mother branch were highest on the control and liquid fertilizer treatment; however, all treatments produced similar numbers. The chemical and organic fertilizer treatments produced a high number of fruiting branches per fruiting mother branch, while organic and liquid fertilizer treatments produced a high number of burr per fruiting branch. The rate of commercializing on the basis of nut weight and quantity was higher on control (87.5%) than chemical fertilizer treatment (84.6%); however, the rate was even lower on liquid fertilizer treatment (84.3%) and organic fertilizer treatment (82.7%). The liquid fertilizer treatment showed the highest average of nut weight, while chemical fertilizer treatment showed the highest average number of fruiting burr. There was no significant difference in average number of normal nuts per burr among treatments. The yield per tree was high on chemical (8.2 kg) and liquid (8.0 kg) fertilizer treatments, but there was no significant difference among treatments. In the rate of nut grade on the basis of nut weight and quantity, the liquid fertilizer treatment, 43.5% and 34.3% more than large nut respectively, produced higher value chestnuts compared to other treatments.

Effect of Cover Crop Species and Liquid Manure Application Rate on Green Manure Production, Leaf Mineral Content, Fruit Quality and Soil Chemical Properties in Pear Orchard

  • Lee, Seong Eun;Park, Jin Myeon;Park, Young Eun;Choi, Dong Geun
    • Korean Journal of Soil Science and Fertilizer
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    • v.47 no.6
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    • pp.558-562
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    • 2014
  • Cover cropping and liquid manure application are considered as effective ways to replace the use of chemical fertilizer in orchard. This study was conducted to investigate the effect of cover crop species and liquid manure application rate on green manure production, leaf mineral content, fruit quality and soil chemical properties in pear orchard. The treatments include rye and hairy vetch as cover crops, two liquid manure application levels based on N and $K_2O$ requirement on each cover crop species, and chemical fertilizer as control. Green manure production was higher in hairy vetch than in rye. K content of pear leaves and soil exchangeable K content increased in N based liquid manure application treatments. The yield was higher in rye + liquid manure and fertilizer treatments, and fruit quality was not different between the treatments. Taking all of these into account, rye + $K_2O$ requirement-based liquid manure application is recommended in pear orchard for not only sufficient nutrient supply but also prevention of any problem related with soil $K_2O$ accumulation in pear orchard in long-term perspective.