High quality MCM-41 is prepared from a gel of molar composition SiO2:0.20 CTACl:0.18 TMAOH:25 H2O aged at 20 ℃ for 24 hours before crystallization lasting for 48 hours. The (110) and (200) peaks of XRD pattern of high quality MCM-41 are unusually well resolved and the FWHM (full-width-at-half-maximum) of the (100) peak is 0.13° for as-prepared MCM-41 and 0.21° for calcined one, which indicate well-developed crystals. The properties of the crystal depend on the source and concentration of the reactants and the gel aging time. There is no induction period in the course of the synthesis, which is conveniently monitored by pH measurement. Gel aging, during which a spatial distribution of silicate polyanions and micellar cations is established, is essential for preparing high quality MCM-41. Surfactants with the same cationic organic group but different counteranions change the crystallization behavior. Highly basic gel (pH=12.6) favours the lamellar product; the quality of MCM-41 is lower as insufficient TMAOH is available to dissolve the silica.
The integrative ecological approaches of chemical assessments, physical habitat modelling, and multi-metric biological health modelling were applied to Gwanpyeong Stream within Gap-Stream watersheds to evaluate environmental impacts on the constructions of residential and commercial complex. For the analysis, the surveys conducted from 45 sites of reference streams within the Gap-Stream watershed and 3 regular sites during 2009 - 2010. Physical habitat health, based on the habitat model of Qualitative Habitat Evaluation Index(QHEI) declined from the headwaters(good - fair condition) to the downstream(poor condition). Chemical water quality, based turbidity and electric conductivity(EC), was degraded toward to the downstream, and especially showed abrupt increases, compared to the values of control streams(CS). Also, concentrations of chlorophyll-a in the downstreams were greater compared to the control stream(CS), indicating an eutrophication. Biological health conditions, based on the Index of Biological Integrity(IBI) using fish assemblages, averaged 19.3 which is judged as a fair condition by the biological criteria of the Ministry of Environment, Korea. The comparisons of model metric values in sensitive species and riffle-benthic species on the Maximum Species Richness Line(MSRL) of 45 reference streams indicated a massive disturbances in all sampling locations. Also, tolerance guild and trophic guild analyses suggest that dominances of tolerant species and omnivores were evident, indicating a biological degradation by habitat disturbances and organic matter pollutions. There was no distinct longitudinal variations of IBI model values from the headwater to the downstream in spite of slight chemical and habitat health gradients among the sampling sites. Overall, integrative ecological health(IEH) scores, based on the chemical, physical, and biological parameters, were low compared to the 45 reference streams due to physical and chemical disturbances of massive constructions of the residential and commercial complex. This stream, thus showed a tendency of typical urban streams which are disturbed in the chemical water quality, habitat structures, and biological integrity. Effective stream management plans and restoration strategies are required in this urban stream for improving integrative stream health.
This study was performed to investigate the quality of pre-processed vegetables used in school and institutional food-services. Pre-processed food materials (carrot, potato, and cabbage) frequently used in food-service were collected from 14 various processing company sources. The sensory and physico-chemical qualities of the pre-processed food materials were determined using sensory and instrumental analysis. For the physico-chemical analysis of the food materials, pH, total acidity, hardness, Hunter colorimeter value, reducing sugar and vitamin C content were determined. For the sensory quality evaluation, 15 panelist were trained and consensus was reached on the quality standards of the preprocessed materials (carrot, potato, and cabbage). Finally, appearance, color, texture, off-odor/taste, and overall quality were determined. In the physico-chemical analysis, there were no significant differences among samples collected from various processing companies. In sensory quality evaluations, the color quality of pre-processed potato was lower than that of other materials. From the coefficient correlations and partial least squares regression analysis between sensory and instrumental data, pH, total acidity, colorimeter values, and hardness were considered important components in assessing the quality of pre-processed vegetables.
Journal of The Korean Society of Grassland and Forage Science
/
v.19
no.3
/
pp.251-258
/
1999
A field experiment was carried out to determine the effects of chemical /mechanical treatments at mowing on the field drying rate and hay quality of rye (Secale cereale L.). The chemical drying agent/mower conditioner ($K_2CO_3$ 2%, conditioning, $K_2CO_3$ 2% + conditioning and control) were treated at different harvest stage (late boot, heading and bloom stage) for hastening hay-making in the spring of 1996. After field dry, square bales were made by hay baler, and the dry matter(DM) loss, visual estimation and nutritive value of rye hay were evaluated after storing two months. The field drying rate of rye was higher with delayed stage of harvest, and mechanical and chemical + mechanical treatment, but the effectiveness of chemical alone was very low. With mower conditioning, the duration of field dry was shortened by 1.5 to 2 days compared with control. The DM loss of rye hay was reduced by late harvest and mechanical, and chemical + mechanical combined treatment, but the efficiency by chemical alone was very low. The visual score (Ieafiness, green color, odor and softness) of hay after storing was high in mechanical and chemical + mechanical, but the score by chemical alone was very low. The nutritive value (ADF, NDF, digestibility, and relative feed value) of hay was also high with treatment of mechanical and chemical + mechanical, but the quality by chemical alone was similar compared with control. The quality of hay was very low when harvested at bloom stage. In conclusion, mower conditioning can enhance the field drying rate of rye, but the drying effectiveness of chemical drying agent was very low. The effect of chemical/mechanical combined treatment was very similar when compared with mechanical alone. Harvest at early heading to heading stage was recommended for high quality rye hay.
Korean oil and honey Yukwa has been paid attention as formal cake for traditional national seasons' holiday and religious service. Quality of Yukwa, however, has been maintained arbitrarily by each Yukwa manufacturer. Since even same Yukwa had severe differences in size, weight, and pattern, it has given the negative effect to the consumer. Yukwa industries need to setup the quantitative quality specifications instead of qualitative ones to maintain the uniformity of Yukwa quality. Efficient and economical inspection and process control system should be developed. In developing quality standards of Yukwa, features which can measure quality quantitatively in real time should be properly chosen. Existing quality features such as acidity, oxidization, hardness, viscosity, and texture were measured by the chemical or physical base destructive methods. Many research and developments have been performed in investigating and analyzing chemical transition states of those quality features as environment or storage condition changes. Most methods, however, require either off-line or complex treatment or time consuming process of analysis in evaluating quality features. Consumer, however, selects products mostly based on the external features such as shape, size, and color. Therefore, critical visual quality features should be chosen and the efficient real time measurement system must be developed. In this paper, computer image acquisition and processing system were developed and software modules were developed to extract the quantitative data of those features in real-time. Computer image processing system will promote in maintaining uniform quality of Yukwa and establishing quality standards of Yukwa.
Luna, Marco Andres Guevara;Luna, Fredy Alejandro Guevara;Espinosa, Juan Felipe Mendez;Ceron, Luis Carlos Belalcazar
Asian Journal of Atmospheric Environment
/
v.12
no.2
/
pp.165-177
/
2018
Particulate matter (PM) measurements are important in air quality, public health, epidemiological studies and decision making for short and long-term policies implementation. However, only few cities in the word have advance air quality-monitoring networks able to provide reliable information of PM leaves in the ambient air, trends and extent of the pollution. In Colombia, only major cities measure PM concentrations. Available measurements from Bogota, Medellin and Bucaramanga show that PM concentration are well above World Health Organization guidelines, but up to now levels and trends of PM in other cities and regions of the country are not well known. Satellite measurements serve as an alternative approach to study air quality in regions were surface measurements are not available. The aim of this study is to perform a spatial and temporal assessment of PM in the ambient air of Colombia. We used Aerosol optical depth (AOD) retrieved by the Moderate Resolution Imaging Spectroradiometer (MODIS) satellite of NASA and surface measurements from the air quality networks of Bogota, Medellin and Bucaramanga. In a first step, we estimated the correlation between MODIS-AOD and monthly average surface measurements (2000 to 2015) from these three cities, obtaining correlation coefficient R values over 0.4 for the cities under study. After, we used AOD and $PM_{10}$ measurements to study the temporal evolution of PM in different cities and regions. Finally, we used AOD measurements to identify cities and regions with the highest AOD levels in Colombia. All the methods presented in this paper may serve as an example for other countries or regions to identify and prioritize locations that require the implementation of more accurate air quality measurements.
This study developed the classification of National Soil Quality Monitoring Network (NSQM) and its site selection criteria to meet the recently established purposes of the NSQM. The NSQM were suggested by this study to classify into the six-purposes site groups from the current classification of land uses. The six purposes site groups were 1) intensive observation sites, 2) contaminant loading sites, 3) human activity sites, 4) background sites, 5) river soil sites, and 6) sites near the groundwater quality monitoring wells. Furthermore, this study developed the site selection criteria of NSQM utilizing the accumulated NSQM data, road traffic data, chemical emission data, census, soil information, and the literature related to soil quality variation due to contaminant loads. For selecting suitable sites for NSQM, this study used road traffic, chemical emission, the distance from the contaminant sources, and population information as specific criteria. The suggested site classification and criteria were appled for the current 100 NSQM sites for evaluation. Forty sites were met to the criteria suggested by this study, but sixty sites were not met to the criteria. However, some of the sixty sites also included the obscure sites that their addresses were not apparent to find them.
Kim, Jin-Ho;Lee, Kyung-Do;Lee, Jong-Sik;Ryu, Jong-Su;Kwun, Soon-Kuk
Proceedings of the Korean Society of Agricultural Engineers Conference
/
2003.10a
/
pp.303-306
/
2003
This survey was carried out to investigate the chemical characteristics of ground water for livestock purpose and to estimate the influence of ground water quality by livestock farming. Water samples were collected three times in 2000, and analyzed for theirs chemical compositions using Korean Standard Methods for Water Quality. The EC of ground water was from 0.214 to 0.474 dS/m. $NO_3-N$ contamination range was from 3.56 to 11.81. The $SO_4{^{2-}}$ was $4.31{\sim}69.37mg/L$ and CI was $12.75{\sim}41.46mg/L$. The data of ground water quality indicated suitable quality for livestock. Also, the concentration of heavy metals in the sample could not make damage to the animals. The $NO_3-N$ concentration of the water by times are as follows: October (8.19 mg/L) > July (7.65 mg/L) > April (4.04 mg/L) with no significant differences during the livestock farming period. The average quality of groundwater for livestock is good for its purpose, and it was showed there was few influence by livestock farming.
Chemical Mechanical Planarization (CMP) process that planarizes semiconductor wafer's surface by polishing is difficult to manage reliably since it is under various chemicals and physical machinery. In CMP process, Material Removal Rate (MRR) is often used for a quality indicator, and it is important to predict MRR in managing CMP process stably. In this study, we introduce prediction models using machine learning techniques of analyzing time-series sensor data collected in CMP process, and the classification models that are used to interpret process quality conditions. In addition, we find meaningful variables affecting process quality and explain process variables' conditions to keep process quality high by analyzing classification result.
Antioxidant films are one active packaging technology that can extend food shelf-life through preventing lipid oxidation, stabilizing color, maintaining sensory properties and delaying microbial growth in foods. Because raw, fresh and minimal processed foods are more perishable during storage or under display conditions than further processed foods, they rapidly lose their original quality. Foods are susceptible to physical, chemical, and biochemical hazards to which packaging films can be effective barriers. Although films incorporated natural (tocopherols, flavonoids and phenolic acids) or synthetic antioxidants (BHT, BHA, TBHQ, propyl gallate) have been extensively tested to improve quality and safety of various foods, food applications require addressing issues such as physical properties, chemical action, cost, and legal approval. Increased interest in natural antioxidants as substitutes for synthetic antioxidants has triggered research on use of the new natural antioxidants in films and coatings. Use of new components (phytochemicals) as film additives can improve food quality and human health. The biosynthesis of plant phenolics can potentially be optimized by active coatings on harvested fruits and vegetables. These coatings can trigger the plants natural proline-linked pentose phosphate pathway to increase the phenolic contents and maintain overall plant tissue quality. This alternate metabolic pathway has been proposed by Dr. K. Shetty and is supported by numerous studies. A new generation of active food films will not only preserve the food, but increase food's nutritional quality by optimizing raw food biochemical production of phytochemicals.
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