• Title/Summary/Keyword: Chemical properties

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Effect of Mechanical Impact Treatment on Fiber Morphology and Handsheet Properties

  • Yung B. Seo;Kim, Dukki;Lee, Jong-Hoon;Yang Jeon
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2001.11a
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    • pp.183-199
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    • 2001
  • Alternative way of shaping fibers suitable for papermaking was introduced. Impact refining, which was done simply by hitting wet fibers with a metal weight vertically, was intended to keep the fibers from shortening and to cause mostly internal fibrillation. Virgin chemical pulp, its recycled one and OCC were used in the experiment. It was noticed from the experiment that impact refining on virgin chemical pulp kept the fiber length and Increased bonding properties greatly, However, in the recycled fibers from the chemical pulp, fiber length and bonding properties were decreased. In OCC, which seems to contain fractions of semi-chemical pulp and mechanical pulp (GP), and which is recycled pulp from corrugated boxes, fiber length and bonding properties were decreased disastrously. We believe recycled cellulosic fibers (recycled chemical pulp and OCC in this case), which went through hornification, were less resistant to the mechanical impact than virgin chemical pulp. For virgin chemical pulp, impact refining allowed no significant fiber length shortening, high WRV, and high mechanical strength.

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Effect of Ionizing Radiation on Mechanical and Electric Properties of Polymer Composites Based on Polyvinyl ether of Ethyleneglycol

  • Mun G. A.;Nurkeeva Z. S.;Kovtunets V. A.;Kupchishin A. I.;Akhmetkalieva G. T.;Khutoryanskiy V. V.;Al-Sayed A. A.;Soh Dea-Wha
    • Transactions on Electrical and Electronic Materials
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    • v.4 no.3
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    • pp.25-28
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    • 2003
  • Radiation technology is an effective way for regulating polymeric materials to physicochemical and mechanical properties. New polymeric hydrogels based on vinyl ethers have been synthesized by the $\gamma$-initiated polymerization method. In this paper, we have studied the effect of radiation on mechanical and electrochemical properties of new rubber-like polymeric composite materials based on polyvinylether of ethyleneglycol (PVEEG).

Studies on Mechanical Interfacial Properties of Kevlar-29 Fibers Reinforced Composites (Kevlar-29 섬유강화 복합재료의 기계적 계면 특성 연구)

  • Park, Soo-Jin;Seo, Min-Kang;Ma, Tae-Jun;Lee, Jae-Rock
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2001.10a
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    • pp.158-162
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    • 2001
  • The effects of chemical treatment on Kevlar-29 fibers have been studied in a composite system. The surface characteristics of the Kevlar-29 fibers were characterized by pH, acid-base value and X-ray photoelectron spectroscopy (XPS). The mechanical interfacial properties of final composites were studied by interlaminar shear strength (ILSS) and critical stress intensity factor ($K_{IC}$). Also, the impact properties of the composites were investigated in the differentiating studies between initiation and propagation energies, and ductile index (DI) along with maximum farce and total energy. It was found that the chemical treatment with phosphoric acid ($H_3PO_4$) solution significantly affected the degree of adhesion at interfaces between fibers and resin matrix, resulting in improving the mechanical interfacial strength of the composites. This was probably due to the presence of chemical polar groups on Kevlar surfaces, leading to an increment of interfacial binding force in a composite system.

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Study on Pad Properties as Polishing Result Affecting Factors in Chemical Mechanical Polishing (CMP공정에서 연마결과에 영향을 미치는 패드 물성치에 관한 연구)

  • 김형재;김호윤;정해도
    • Journal of the Korean Society for Precision Engineering
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    • v.17 no.3
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    • pp.184-191
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    • 2000
  • Properties of pad are investigated to find the relationship between the chemical mechanical polishing(CMP) results, such as material removal rate and within wafer non-uniformity(WIWNU), and its properties. Polishing pressure is considered as important factors to affect the results, so behavior of ordinary polymer is studied to define the polishing result affecting properties of pad. Experimental setup is devised to identify the behavior of pad and several different pads are used in chemical mechanical polishing experiments to verify the correlations between pad properties and polishing results. The results indicate that the viscoelastic properties of pad had relationships with the polishing results, and shows correlation between suggested properties of pad and polishing result.

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Study on the of the Correlation between Soil Chemical Properties and Bioactive Compounds of Acer tegmentosum Maxim.

  • Lee, Dong Hwan;Park, Youngki;Hong, Seong Su;Park, Gwang Hun;Kim, Hyun-Jun
    • Korean Journal of Plant Resources
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    • v.34 no.6
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    • pp.566-574
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    • 2021
  • This research was carried out to investigate the correlation between soil chemical properties and bioactive compounds of Acer tegmentosum Maxim. The methods of determining bioactive compounds were determined by high performance liquid chromatography, that contained (-)-gallocatechin (0.04±0.01 ~ 0.43±0.28%), salidroside (0.90±0.06 ~ 3.86±0.59%), tyrosol (0.03±0.00 ~ 0.43±0.00%), (-)-catechin (0.05±0.01 ~ 0.37±0.14%), 6'-O-galloylsalidroside (0.02± 0.01 ~ 0.31±0.06%), (-)-epicatechin-gallate (0.01±0.00 ~ 0.04±0.01%). The soil chemical properties analysis such as soil pH, electric conductivity (EC), organic matter (OM), total nitrogen (TN), available phosphate (Avail. P2O5), exchangeable cation and cation exchange capacity (CEC) were performed following the standard manual. The correlation analysis between soil chemical properties and bioactive compounds of A. tegmentosum, soil pH, available phosphate and exchangeable cation (Ca2+ and Mg2+) were negatively correlated with content of salidroside. On the other hand, soil exchangeable cation (Na+) showed positive correlation with content of salidroside. The results of this study was able to investigate the correlation between soil chemical properties and bioactive compounds of A. tegmentosum.

Rheological, Morphological and Electrical Properties of Polycarbonate/Multi-walled Carbon Nanotube Composites

  • Han, Mi-Sun;Sung, Yu-Taek;Chung, Ji-Woong;Kim, Woo-Nyon;Lee, Heon-Sang;Kum, Chong-Ku
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.220-220
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    • 2006
  • Rheological and electrical properties of the polycarbonate (PC) / multi-walled carbon nanotube (MWNT) were studied. The MWNT was funtoinalized by treating with the hydrogen peroxide ($H_{2}O_{2}$). The electrical conductivity showed higher value for the PC/MWNT ($H_{2}O_{2}$ treated, freeze drying) composites compared that of the PC/MWNT ($H_{2}O_{2}$ treated, thermal drying) composites. From the results of the morphological, rheological, and electrical properties of the PC/MWNT composites, it is suggested that the electrical and rheological properties of the PC/MWNT composites are affected by the MWNT-MWNT network structure which is related with the MWNT morphologies such as the degree of aggregation and aspect ratio of the MWNT.

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Synthesis of a Novel Phosphorus-containing Flame Retardant for Epoxy Resins

  • Xu, Hong-Jun;Jin, Fan-Long;Park, Soo-Jin
    • Bulletin of the Korean Chemical Society
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    • v.30 no.11
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    • pp.2643-2646
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    • 2009
  • In this study, a novel phosphorus-containing flame retardant copolymer of spirocyclic pentaerythritol di(phosphate monochloride) and bisphenol S (SPD-BS) was successfully synthesized and used as a flame retardant in diglycidyl ether of bisphenol A (DGEBA) epoxy resins. The chemical structure of the SPD-BS was characterized using FT-IR and $^1H$ NMR spectra. The thermal properties were investigated by differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). The effects of SPD-BS and nano-$CaCO_3$ on the flame-retardant properties of DGEBA/SPD-BS systems were evaluated by measurement of the burning rate. As a result, the thermal stabilities of the DGEBA/SPD-BS systems were decreased with increasing SPD-BS content. The flame-retardant properties and char yields of the systems were significantly increased when SPD-BS content increased. The synergism of nano-$CaCO_3$ incorporation on flame retardancy was found for the DGEBA/SPD-BS systems.

A Study on the Quality Properties of the Expansive For Dry-Shrinkage Compensation of the Floor Mortar (온돌바닥 모르터의 건조수축보상을 위한 팽창제의 품질특성 연구)

  • 이웅종;이종열;정연식;이순기;정성철
    • Proceedings of the Korea Concrete Institute Conference
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    • 2000.10a
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    • pp.155-160
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    • 2000
  • In this paper, we investigated quality properties for the expansive of the CaO-$CaSO_4$ family which used to compensate dry-shrinkage in the floor mortar of On-Dol heating System. This experimental study established the mix condition with quantity of the expansive and is to investigate the relativity between the compress strength and the length change and the relativity between the chemical properties and the length change with the analysis of the physical and chemical properties. As a result of the study, the expansive is controlled by more the CaO than the $CaSO_4$. The relativity between the compress strength and the length change is expressed by exponential function, showing that if the expansive performance is increased, the compress strength is decreased. And the relativity between the chemical properties and the length change is only relative the quantity of the F-CaO among the chemical properties, is expressed by the second order function, showing that if the F-CaO is increased, the expansive performance is increased.

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Rice Yield Prediction Based on the Soil Chemical Properties Using Neural Network Model (인공신경망 모형을 이용하여 토양 화학성으로 벼 수확량 예측)

  • Sung J. H.;Lee D. H.
    • Journal of Biosystems Engineering
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    • v.30 no.6 s.113
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    • pp.360-365
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    • 2005
  • Precision agriculture attempts to improve cropping efficiency by variable application of crop treatments such as fertilizers and pesticides, within field on a point-by-point basis. Therefore, a more complete understanding of the relationships between yield and soil properties is of critical importance in precision agriculture. In this study, the functional relationships between measured soil properties and rice yield were investigated. A supervised back-propagation neural network model was employed to relate soil chemical properties and rice yields on a point-by point basis, within individual site-years. As a results, a positive correlation was found between practical yields and predicted yields in 1999, 2000, 2001, and 2002 are 0.916, 0.879, 0.800 and 0.789, respectively. The results showed that significant overfitting for yields with only the soil chemical properties occurred so that more of environmental factors, such as climatological data, variety, cultivation method etc., would be required to predict the yield more accurately.

The Soil Improvement and Plant Growth on the Newly-Reclaimed Sloped land VI. Relationship between annual change of soil phsico-chemical properties and yield of silage corn (신개간경사지 토양개량과 작물생육에 관한 연구 VI. 토양의 물리화학성 년차간 변화가 옥수수 청예수량에 미치는 영향)

  • 허봉구;김무성
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.11 no.1
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    • pp.22-29
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    • 1991
  • This study was experimented to obtain the basic information on the changeable aspect and improvement of soil fertility in newly-reclaimed sloped land. Silage corn was cultivated under the six different treatments for 4 years. The relation between the amount or ratio of annual changes of soil physico-chemical properties and yield of silage corn were analyzed. Soil bulk density was decreased in 3rd year at topsoil, but that decreased in 4th year at subsoil. Soil organic matter also decreased in 2nd year at topsoil, and decreased continuously at subsoil. Bulk density and hardness of soil depths showed significant negative simple correlation with dry matter yield and cation exchange capacity showed positive. Correlation coefficient of chemical properties with dry matter yield were low. The range of annual changes of moisture percent, hardness and organic matter were wider than the other properties. The significantly different of physical properties were higher than the chemical properties, and those of topsoil were higher than subsoil. According to multiple regression between yield and physico-chemical properties of subsoil, bulk density and cation exchange capacity were in the greatest contribution at the variations, but bulk density was greatest at the ratios.

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