• 대한화학회지
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• 제16권2호
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• pp.93-99
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• 1972

To obtain the various kinds of inositol stereomers, we have selected the process of electrolytic reduction of DL-epi-inosose-2 using Ni, Ta, Cu, Mo, Pb, Sn, W, Cd and Hg etc., as cathode. We think that this process gives greater variety than chemical processes. DL-epi-inosose-2 was synthesized by chemical oxidation of myo-inositol, dissolved in aqueous solution of potassium hydroxide, and used as electrolytic solution. To prevent anodic oxidation of cathode products the H-type diaphragm cell was used. As the results of paper chromatography of cathodic products, we obtained the $R_f$ values of myo-inositol and epi-inositol were in good agreement with literature values.

• 한국결정성장학회지
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• 제10권6호
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• pp.378-380
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• 2000

The epitaxial $BaTiO_{3}$ thin film was prepared on the MgO substrate by the coating-pyrolysis process using a mixed solution of Ba-naphthenate and Ti-naphthenate. The crystal structure of the epitaxial $BaTiO_{3}$ thin film was characterized by XRD ${\theta}/2{\theta}$ scan and asymmetric {303} rocking curve scan. The epitaxial $BaTiO_{3}$ thin film had the cubic phase with the lattice parameter of a = c = 0.4018 nm.

• 펄프종이기술
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• 제37권3호
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• pp.59-65
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• 2005

There are accumulations of remained chemical additives and contaminants in the process water of semi-closed linerboard mill. High temperature of the process water aggravates the anaerobic digestion of contaminated process water and causes the generation of hazardous gases, which are from the biological reaction of varied additives and contaminants. The hydrogen sulfide in the gases easily combine with moisture in the air, and become sulfuric acid, which causes corrosion of paper machinery. This hydrogen sulfide is from the reduction of sulfate ions in the process water, and the sulfate ions are mostly from the alum. We changed the alum to PAC (Poly Aluminum Chloride). The results were preventing generation of hydrogen sulfide, and equivalent sizing effect by the use of PAC.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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• pp.234.2-234.2
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• 2014

Organic light emitting diode (OLED) is considered as the next generation flat panel displays due to its advantages of low power consumption, fast response time, broad viewing angle and flexibility. For the flexible application, it is essential to develop thin film encapsulation (TFE) to protect oxidation of organic materials from oxidative species such as oxygen and water vapor [1]. In many TFE research, the inorganic film by atomic layer deposition (ALD) process demonstrated a good barrier property. However, extremely low throughput of ALD process is considered as a major weakness for industrial application. Recently, there has been developed a high throughput ALD, called 'spatial ALD' [2]. In spatial ALD, the precursors and reactant gases are supplied continuously in same chamber, but they are separated physically using a purge gas streams to prevent mixing of the precursors and reactant gases. In this study, the $Al_2O_3$ thin film was deposited by spatial ALD process. We characterized various process variables in the spatial ALD such as temperature, scanning speed, and chemical compositions. Water vapor transmission rate (WVTR) was determined by calcium resistance test and less than $10-^3g/m^2{\cdot}day$ was achieved. The samples were analyzed by x-ray photoelectron spectroscopy (XPS) and field emission scanning electron microscope (FE-SEM).

• 한국산학기술학회논문지
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• 제12권4호
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• pp.1812-1816
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• 2011

본 연구에서는 약액 주입 후 미 도포로 인한 복합적인 공정불량을 예방하기 위하여 100nm 이하의 나노 반도체 제조공정에서 필수적인 스피너(spinner) 장비를 위한 약액 흐름제어 시스템을 개발하였다. 본 연구개발을 통하여 실시간으로 상태요소들을 감시할 뿐만 아니라 상태요소의 비정상적 변화나 웨이퍼 가공불량이 발생할 경우 해당 유니트를 정지시킴과 동시에 원격지에 있는 엔지니어에게 경보를 전송함으로써 즉각적인 대처가 가능하여 모듈의 수율을 향상시킬 수 있을 것으로 기대된다. 또한 세부 동작 시퀀스를 제어하기 위한 H/W와 S/W 시스템을 생산라인에 실장하고 성능점검 및 인증을 수행한 결과 5가지의 유형별 비정상적 프로세스를 정확히 검출하였다.

• Korea-Australia Rheology Journal
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• 제12권1호
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• pp.83-92
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• 2000

In resin transfer molding (RTM) process, preplaced fiber mat is set up in a mold and thermoset resin is injected into the mold. An important interest in RTM process is to minimize cycle time without sacrificing part quality or increasing cost. In this study, the numerical simulation and optimization process in filling stage were conducted in order to determine the optimum gate locations. Control volume finite element method (CVFEM) was used in this numerical analysis with the coordinate transformation method to analyze the complex 3-dimensional structure. Experiments were performed to monitor the flow front to validate simulation results. The results of numerical simulation predicted well the experimental results with every single, simultaneous and sequential injection procedure. We performed the optimization analysis for the sequential injection procedure to minimize fill time. The complex geometry of an automobile bumper core was chosen. Genetic algorithm was used in order to determine the optimum gate locations with regard to 3-step sequential injection case. These results could provide the information of the optimum gate locations in each injection step and could predict fill time and flow front.

• 한국표면공학회지
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• 제49권4호
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• pp.363-367
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• 2016

For the industrial application of electropolishing process, we investigated electropolishing characteristics of stainless steel through increasing the specimen size or electrode gap. In this study, we performed a set of experiment with the specimen size of $10cm{\times}10cm$ and the electrode gap of 1 cm or more. In the view of the electropolishing process, the electrolyte temperature and the polishing time were most important factors compared with the current density and the electrode gap. Especially, the electrolyte temperature most importantly affected surface roughness and current efficiency on electropolishing characteristics. For the industrial application of electropolishing process, it should be considered for important factors such as electrolyte temperature, polishing time, current density and electrode gap, etc.

• 한국가스학회지
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• 제8권2호
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• pp.28-34
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• 2004

Enhanced methodologies for process diagnosis and abnormal situation management have been developed for the last two decades. However, there is no single method that always shows better performance over all kinds of diagnostic problems. In this paper, a framework of message-passing, cooperative, intelligent diagnostic agents is presented for improved on-line fault diagnosis through cooperative problem solving of different expertise. A group of diagnostic agents in charge of different process functional perform local diagnoses in parallel; exchange related information with other diagnostic agents; and cooperatively solve the global diagnostic problem of the whole process plant or business units just like human experts would do. For their better understanding, sharing and exchanging of process knowledge and information, we also suggest a way of remodeling processes and protocols, taking into account semantic abstracts of process information and data. The benefits of the suggested multi-agents-based approach are demonstrated by the implementations for solving the diagnostic problems of various chemical processes.

• Tribology and Lubricants
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• 제38권1호
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• pp.1-7
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• 2022

Chemical-mechanical polishing (CMP) process is a semiconductor process that planarizes a wafer surface using mechanical friction between a polishing pad and a substrate surface during a specific chemical reaction. During the CMP process, polishing pad conditioning is applied to prevent the rapid degradation of the polishing quality caused by polishing pad glazing through repeated material removal processes. However, during the conditioning process, uneven wear on the polishing pad is inevitable because the disk on which diamond particles are electrodeposited is used. Therefore, the abrasion of the polishing pad should be considered not only for the variables during the conditioning process but also when designing the CMP conditioning system. In this study, three design variables of the conditioning system were analyzed, and the effect on the pad wear profile during conditioning was investigated. The three design variables considered in this study were the length of the conditioner arm, diameter of the conditioner disk, and distance between centers. The Taguchi method was used for the experimental design. The effect of the three design variables on pad wear and uniformity was assessed, and new variables used in conditioning system design were proposed.

• 품질경영학회지
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• 제52권3호
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• pp.575-591
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• 2024

Purpose: Storage furniture in a laboratory where chemical experiments are conducted should satisfy both the chemical reactivity and stability required in the experimental environment, commonality with general households, and economic feasibility for the mass production system. Therefore, the development of storage furniture used in the laboratory should be done quickly through a process verified by utilizing various ideas and using a method suitable for the special environment called the laboratory. This study deals with the process of developing materials for inner drawers of laboratory furniture that meet these requirements. Methods: TRIZ methodology and ARIZ-85C process were applied to satisfy the requirements arising from the product development process, ARIZ process was applied step by step to resolve the contradictions that occurred during the development process, and 40 invention principles and ideal solutions (Ideal Final Results: IFR) were derived through clear analysis of the problem to select materials suitable for the special environment of the laboratory. Results: This study focused on the selection of materials that meet the durability and chemical stability required in the special environment of laboratory furniture. Through this, various solutions were sought with the aim of reducing cost and increasing productivity, and the process of maximizing useful functions and minimizing irrational parts in use was focused on TRIZ's contradiction resolution method. As a result, we found a way to improve the performance and efficiency of laboratory furniture through the selection of optimized furniture materials and problem solving methods. Conclusion: In this study, a methodology for the development of efficient and safe laboratory furniture materials was found and verified. In the use of furniture products in a laboratory, corrosion or damage caused by chemical generators may occur, making it difficult to use as a product. As a result, a method to reduce cost and increase productivity while maintaining the durability and chemical stability of laboratory furniture was found, and by finding a solution to the two relationships between chemical safety and production efficiency in the process of selecting materials for optimized furniture materials, and applying the ARIZ development process, the effectiveness of the product development process in a special environment could be verified.