• 제목/요약/키워드: Chemical foaming agent

검색결과 57건 처리시간 0.032초

The Investigation of Rheological Properties Development for Polymer Matrix Including Foaming Agent

  • Lee, Seung Hak;Kim, Dong Gun;Lim, Sung Wook;Park, Eun Young;Park, Tae Sun;Hyun, Kyu
    • Elastomers and Composites
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    • 제51권1호
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    • pp.24-30
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    • 2016
  • Sole in the footwear usually modified with foaming agent on the polymer resin to improve the lightweightness and crush-cushion effect. In this study, we investigated rheological properties for polymer resin filled with the different type and concentration of foaming agent, capsule type foaming agent and organo-chemical foaming agent, under the time sweep test. Curing times of each polymer resin with different kind of foaming agent are delayed than reference material (epoxy resin with curing agent). In case of adding capsule type foaming agent, however, there is appropriate concentration to reduce the curing time, relatively. When foaming agent is activated, foaming force inflates the sample in contrast to condensation force of curing and then axial normal force develop to the (+) direction. Interestingly, by increase concentration of foaming agent, there is a specific point to break down the axial normal force development. The reason for this phenomenon is that coalescence of foams induce the blocking of axial normal force development.

LDPE, EVA 및 발포제 혼합재료의 초미세 발포 공정 적용과 각 인자의 영향성 평가 (Application of a Microcellular Foaming Process of Mixed Materials of LDPE, EVA and Foaming Agent and Estimation of Influence of Each Factor)

  • 박대근;차성운;황윤동
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2001년도 추계학술대회논문집A
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    • pp.853-858
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    • 2001
  • Generally, mixed materials of LDPE, EVA and foaming agent are manufactured by crosslinking foaming or chemical foaming process. Above materials were used in a microcellular foaming injection molding process. Influence of each factor such as injection type, temperature of barrel, rate of mixed materials and contents of foaming agent was estimated by DOE(Design of Experiments). As a result of experiments, injection type and rate of LDPE, EVA have an influence on foaming rate. This data can be used in field of application of LDPE and EVA.

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용제형 저기포성 정련제의 제조 및 정련효과 (Preparation of Solvent-Type Low Foaming Scouring Agents and Their Scouring Effect)

  • 유혁제;정동진;;함현식;박홍수
    • 한국응용과학기술학회지
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    • 제21권2호
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    • pp.156-163
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    • 2004
  • Low foaming scouring agents (LSSA) were prepared by blending of amine salt of dodecylbenzene sulfone, poly (PO-b-EO) glycol, Newpol PP-2000, MJU-100, ethylene glycol and organic solvent. As the results of several tests, LSSA-2 showed good scouring effect, penetrating ability and emulsifiability, and showed not much water pollution. The foaming power of LSSA-2 measured by Ross & Miles method was 11mm foam height immediately after foaming. And the foaming power of LSSA-2 measured by Ross & Clark method were less than 310mm foam height at $30^{\circ}C$, 17mm at $80^{\circ}C$. As a result, LSSA-2 was proved as a good foaming scouring agent.

An Environment-Friendly Surface Pretreatment of ABS Plastic for Electroless Plating Using Chemical Foaming Agents

  • Kang, Dong-Ho;Choi, Jin-Chul;Choi, Jin-Moon;Kim, Tae-Wan
    • Transactions on Electrical and Electronic Materials
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    • 제11권4호
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    • pp.174-177
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    • 2010
  • We have developed an environment-friendly etching process, an alternative to the dichromic acid etching process, as a pretreatment of acrylonitrile-butadiene-styrene (ABS) plastic for electroless plating. In order to plate ABS plastic in an electroless way, there should be fine holes on the surface of the ABS plastic to enhance mechanically the adhesion strength between the plastic surface and the plate. To make these holes, the surface was coated uniformly with dispersed chemical foaming agents in a mixture of environmentally friendly dispersant and solvent by the methods of dipping or direct application. The solvent seeps into just below the surface and distributes the chemical foaming agents uniformly beneath the surface. After drying off the surface, the surface was heated at a temperature well below the glass transition temperature of ABS plastic. By pyrolysis, the chemical foaming agents made fine holes on the surface. In order to discover optimum conditions for the formation of fine holes, the mixing ratio of the solvent, the dispersant and the chemical foaming agent were controlled. After the etching process, the surface was plated with nickel. We tested the adhesion strength between the ABS plastic and nickel plate by the cross-cutting method. The surface morphologies of the ABS plastic before and after the etching process were observed by means of a scanning electron microscope.

무용제형 저기포성 정련제의 제조 및 정련특성 (Preparation of Solvent-Free Low Foaming Scouring Agents and Their Scouring Characteristics)

  • 박홍수;안성환;심일우;조혜진;함현식;김영찬;김성길
    • 한국응용과학기술학회지
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    • 제23권1호
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    • pp.37-44
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    • 2006
  • Solvent-free low foaming scouring agents (LFSC) were prepared by blending of 2-ethylhexylaminoethyl sulfate (2-EHAS), POE(10) octadecylbenzyl- ammonium chloride (POBAC) and Sedlan FF-200 (FF-200). As the results of several tests, 2-EHAS/POBAC/FF-200/water (8g/12g/20g/60g) mixture (LFSC-5) showed good cleaning power, penetrating ability and stability to alkali, and gave less problem in water pollution. The foaming power of LFSC-5 measured by Ross and Miles method was 8mm foam height immediately after foaming, and that measured by Ross and Clark method was less than 300mm foam height at $30^{\circ}C$, and 18mm at $80^{\circ}C$. As a result, LFSC-5 proved a good low foaming scouring agent for fiber.

콘크리트용 기포제 종류 및 농도에 따른 기포의 특성 (Properties of Bubble According to Types and Concentrations of Concrete Foaming Agent)

  • 김진만;곽은구;오광진;강철
    • 콘크리트학회논문집
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    • 제23권2호
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    • pp.151-158
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    • 2011
  • 선발포 방식을 통해 제조되는 기포 콘크리트에서 기포는 밀도, 강도, 공극 등의 물리적 특성에 영향을 끼치는 주요인이다. 기포 콘크리트에 대한 연구가 꾸준하게 진행되었지만, 기포 자체의 특성에 관한 연구는 화학적인 분야를 제외하고는 거의 없는 실정이다. 그러므로 용도에 적합한 기포 콘크리트를 제조하기 위해서는 기포의 성상에 대한 연구가 필수적으로 선행되어야 한다. 기포 콘크리트의 제조에서 기포를 유효하게 이용하기 위해서는 기포의 특성을 평가해야만 한다. 이 연구에서는 기포의 특성을 알아보기 위해 기포제 종류 및 농도 변화에 따른 기포의 특성에 관한 검토를 수행하였다. 기포의 특성을 알아보기 위해 사용한 기포제는 계면활성제계, 수지비누계, 단백질계 기포제를 사용하였고 기포제의 농도는 기포제 종류에 따라 0.05~13% 범위로 설정하였다. 측정 항목은 발포율, 기포 용적, 수용액 용적, 기포 크기 및 분포를 측정하였다. 분석 결과, 기포제 종류와는 상관없이 기포제 농도가 높을수록 발포율은 증가하는 것으로 나타났고, 기포제 농도는 기포, 수용액 용적 변화, 기포 크기 분포에도 영향을 끼치는 것으로 나타났다. 기포의 안정성 측면에서 단백질계가 계면활성제, 수지비누계 보다 높은 안정성을 나타냈다. 기포의 형상에서는 계면활성제계, 수지 비누계는 다각형의 기포를, 단백질계는 구형의 기포를 형성하였다.

기포제가 모르터의 제성질에 미치는 영향에 관한 실험적 연구 (Experimental Studies on Influence of Foaming Agents on the Properties of Mortar)

  • 성찬용;황은
    • 한국농공학회지
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    • 제27권1호
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    • pp.46-61
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    • 1985
  • This study was performed to obtain the basic data which can be applied to the use of foaming mortars. The data was based on the properties of foaming mortars depending upon various mixing ratios and addings to compare those of cement mortar. The foaming agents which was used at this experiment were pre-foamed type and mix-foaming type which is being used as mortar structures. The foaming mortar, mixing ratios of cement to fine aggregate were 1:1, 1: 2, 1 : 3 and 1 : 4. The addings of foaming agents were 0.0%, 0.5%, 1.0%, 1.5%, 2.0%, 2.5% and 3.0% of cement weight. The results obtained were summarized as follows; 1. At the mixing ratio of 1 : 1, the lowest water-cement ratios were showed by foaming mortars, respectively. But it gradually was increased in poorer mixing ratio and decreased in more addition of foaming agent. The water-cement ratios were decreased up to 1. 8~22. 0% by G, 2. 2~24. 1 % by U and 0. 7~53. 1% by J foaming mortar than cement mortar. 2, At the mixing ratio of 1 : 1, the highest bulk densities were showed by foaming mortars, respectively. But, it gradually was decreased in poorer mixing ratio and more addition of foaming agent. The bulk densities were decreased up to 1. 4~20. 7% by G, 2. 3~23. 7% by U and 26. 5~56. 5% by J foaming mortar than cement mortar. Therefore, foaming mortar could be utilized to the constructions which need low strengths. 3. At the mixing ratio of 1:1, the lowest absorption rates were showed by foaming mortars, respectively. But, it gradually was increased in poorer mixing ratio and more addition of foaming agent. Specially, according to the absorption rate when immersed in 72 hours, the absorption rates were showed up to 1. 01~1. 24 times by G, 1. 03~1. 58 times by U and 1. 10~5. 91 times by J foaming mortar than cement mortar. It was significantly higher at the early stage of immersed time than cement mortar. 4. At the mixing ratio of 1:1, the lowest air contents were showed by foaming mortars, respectively. But, it gradually was increased in poorer mixing ratio and more addition of foaming agent. Air contents were contented up to 4. 0~17. 2 times by G, 5. 2~23. 2 times by U and 23. 8~74. 5 times by J foaming mortar than cement mortar. 5. At the mixing ratio of 1 : 1, the lowest decreasing rates of strengths were showed by foaming mortars, respectively. But, it gradually was increased in poorer mixing ratio and more addition of foaming agent. Specially, the strengths of 28 days were decreased 0. 4~2. 2% than those of 7 days by foaming mortar, respectively. Also, the correlations between compressive and tensile strength, compressive and ending strength, tensile and bending strength were highly significant as a straight line shaped, respectively. 6. The correlations between absorption rate, air content, compressive strength and bulk density, absorption rate, compressive strength and air content were highly significant, respectively. The multiple regression equations of water-cement ratio, bulk density, absorption ate, air content, compressive strength, tensile strength and bending strength were computed depending on a function of mixing ratio and addition of foaming agent. It was highly significant, respectively. 7. At the mixing ratio of 1 : 1, the highest strengths were showed by cement mortar and foaming mortars, by chemical reagents. But, it gradually was decreased in poorer mixing ratio. The decreasing rates of strengths were in order of H $_2$S0 $_4$, HNO$_3$ and HCI, J,U,G foaming mortar and cement mortar. Specially, at the each mixing ratio, each chemical reagent and 3.0% of foaming agent, J foaming mortar was collapsed obviously. Therefore, for the structures requiring acid resistence, adding of foaming agent should be lower than 3.0%.

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해포석과 팽창진주암의 복합화에 의한 발포체 제조 (A Foamed Body through the Complexation with the Sepiolite and Expanded Pearlite)

  • 이철태;장문호;박태문
    • 공업화학
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    • 제23권1호
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    • pp.77-85
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    • 2012
  • 팽창진주암(expanded perlite)과 섬유상 해포석(sepiolite)과의 복합화를 통해 유연성을 지닌 세라믹 발포체의 제조가능성을 조사하였다. 무기광물 섬유 해포석의 해섬처리는 팽창진주암과 해포석으로 이루어진 세라믹발포체의 제조를 위해 가장 중요한 전 처리공정이다. 해섬된 해포석과 팽창진주암은 혼합 교반되어 슬러리 상태로 이루어지며, 이 슬러리상의 복합물은 $300^{\circ}C$ 이하의 저온 열처리과정을 통해 형상화 및 발포화되어 괴상의 발포체로 제조된다. 슬러리상 복합물의 열처리공정은 슬러리 복합물 중에 잔존하는 수분의 증발단계, 일정발포온도에서 발포화제가 분해되어 진행되는 발포화단계 및 발포 후 잔류되는 유기물질의 분해제거단계를 포함하는 것으로 설계되어야 한다. 열처리 공정조건과 발포제는 상관성이 있으며 팽창진주암과 해포석섬유로 이루어진 슬러리상 혼합물의 발포에 적절한 발포제는 유기계 발포제가 적절하며 DSS (dioctyl sodium sulfosuccinte)가 효과적이었다.

Ethylene Vinyl Acetate Copolymer 발포체의 발포특성 및 물리적 특성 (Foaming Characteristics and Physical Properties of Ethylene Vinyl Acetate Copolymer Foams)

  • 김진태;손우정;안병현;김원호
    • Elastomers and Composites
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    • 제36권1호
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    • pp.52-60
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    • 2001
  • 발포체의 물성은 발포체의 밀도, 사용된 폴리머의 기계적 물성과 열린 셀(open cell) 함량, 셀 크기, 셀 크기 분포, 셀 형태, 격벽의 두께 등을 포함하는 셀 구조에 의존하며 이러한 발포체의 밀도는 사용된 폴리머의 종류와 가교제의 농도, 발포제의 농도 그리고 가공 기술 및가공 조건 같은 다양한 원료물질과 가교조건에 영향을 받는다. Ethylene vinyl acetate coplymer (EVA) 발포체는 가교 발포체로서 가교속도와 발포제의 분해속도에 의해 발포특성에 영향을 받으며 이에 따라 발포체 물성에도 영향을 미친다. 본 연구에서는 가공 온도인 $155^{\circ}C$에서의 시간에 따른 발포제의 분해 속도 차이와 이에 따른 발포특성과 발포체의 물성에 대한 영향을 평가하였다. 발포제 분해 속도가 보다 느린 경우, 발포제 분해속도가 빠른 경우와 비교하여 낮은 밀도를 보여주었으며, 우수한 충격흡수성을 나타내었고 발포체의 셀 크기는 보다 균일하였다.

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유화중합에 의한 친환경 전분-아크릴 코팅졸의 합성 (Synthesis of Environmental-Friendly Starch-acrylic Coating Sols by Emulsion Polymerization)

  • 이미춘;문우주;조을룡
    • Elastomers and Composites
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    • 제45권4호
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    • pp.272-279
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    • 2010
  • 전분은 친환경적인 천연자원이다. 건축 재료로서 활용 가능한 전분-아크릴 코팅졸을 유화중합으로 합성하였다. 제조된 합성물은 IR, $^1H$-NMR을 이용하여 구조를 분석하였고, X-ray Diffraction, 발포 시험, 백색도 시험, 광택도 시험과 인장 강도를 측정을 통하여 물리적 특성을 조사하였다. 전분-아크릴 폴리머 메트릭스에서 전분의 무정형 상태는 XRD결과로 알 수 있었다. 에멀젼을 60% $CaCO_3$ 수용액과 1%, 3%, 5% 발포제와 배합하였다. 그 결과 전분과 발포제의 양이 증가할수록 발포율이 증가하였다. 전분과 발포제의 양이 증가하면 인장 강도가 증가하였다. 그러나 전분과 발포제의 증가로 인해 백색도와 광택도는 감소하였다.