• 한국농공학회:학술대회논문집
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• 한국농공학회 2005년도 학술발표논문집
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• pp.643-648
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• 2005

The objective of this paper is to analyze the environmental effects by the fertilizer change with wastewater reuse for agriculture. For this research, Lysimeter tests are being implemented to cultivate rice with different levels of fertilizer applications with wastewater irrigation., and to analyze the nutrient loading by wastwater reuse in paddy fields was examined the CREAMS-PADDY model. CREAMS-PADDY model is modified from CREAMS model for considering the hydrologic cycles in paddy field. As a result, in the lysimeter treated by irrigation with wastewater and chemical fertilizer with half of the conventional amount showed generally similar tendency to the control plot. This may require the modifications of standard cultural practices for rice in terms of fertilizer and pesticide applications. However, high concentration of sodium in wastewater might cause damage to physico-chemical properties of paddy soil. And the wastewater reuse effects on nutrient loads were quantitatively analyzed and this results provide the reasonable management for agricultural reuse.

• 한국환경과학회지
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• 제14권2호
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• pp.157-165
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• 2005

This study was conducted to determine optimum design parameters in nitrification and denitrfication of chemical fertilizer wastewater using pilot plant, Jet Loop Reactor. The chemical fertilizer wastewater which contains low amounts of organic carbon and has a high nitrogen concentration requires a post-denitrfication system. Organic nitrogen is hydrolyzed above $86\%$, and the concentration of organic nitrogen was influent wastewater 126mg/L and of effluent wastewater 16.4mg/L, respectively. The nitrification above $90\%$ was acquired to TKN volumetric loading below $0.5\;kgTKN/m^3{\cdot}d$, TKN sludge loading below $0.1\;kgTKN/kgVSS{\cdot}d$ and SRT over 8days. The nitrification efficiency was $90\%$ or more and the maximum specific nitrification rate was $184.8\;mgTKN/L{\cdot}hr$. The denitrification rate was above $95\%$ and the concentration of $NO_3-N$ was below 20mg/L. This case was required to $3\;kgCH_3OH/kgNO_3-N$, and the effluent concentration of $NO_3^--N$ was below 20mg/L at $NO_3^--N$ volumetric loading below $0.7\;kgNO_3^--N/m^3{\cdot}d$ and v sludge loading below $0.12\;kgNO_3^-N/kgVSS{\cdot}d$. At this case, the maximum sludge production was $0.83\;kgTS/kgT-N_{re}$ and the specific denitrfication rate was $5.5\;mgNO_3-N/gVSS{\cdot}h$.

• 한국축산시설환경학회지
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• 제3권1호
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• pp.35-42
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• 1997

The purpose of this study is to investigate the effect of the biologically treated animal wastewater as a liquid fertilizer in the paddy rice. The treated water has content of the ammonia nitrogen 24mg/I and nitrate 40 mg/I on an average in the first year. A trace of nitrite has been shown. The phosphate content was 92 mg/I on an average. The amount of yielded rice was 365kg/10a for test 1 (no fertilizer), 388dg/10a for test 2(chemical fertilizer), 526kg/10a for test 3 (treated water) respectively. The treated water showed 35% more in production than the chemical fertilizer. The treated water has content of the ammonia nitrogen 40mg/I and nitrate 67mg/I on an average in the second year. A trace of nitrite has been shown. The phosphate content was 57mg/I on an average. The amount of yielded rice was 402kg/10a for test 1, 505kg/10a for test 2, 607kg/10a for test 3 respectively. Yield of unhulled rice was 20% more in the plot of treated water than that of chemical fertilizer.

• Environmental Engineering Research
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• 제17권1호
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• pp.3-8
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• 2012

A scaled-up bioconversion of fishmeal wastewater (FMW) into liquid fertilizer was performed five times in a $1m^3$ reactor in order to examine the feasibility of commercialization. The importance of aeration was marked. Analyses indicated that dissolved oxygen (DO) level was closely related to the value of oxidation-reduction potential (ORP) and it was crucial to achieve high-quality liquid fertilizer. When pure oxygen was supplied through four diffusers into the reactor, DO levels and ORP values were maintained over 1.2 mg/L and 0.2 mV, respectively all the time during 52 hr of bioconversion. The pH changed from 6.8 to 5.9. The average removal percentages of chemical oxygen demand ($COD_{Cr}$) and total nitrogen (TN) were 75.0% and 71.6%, respectively. Compared to the result acquired in a 5-L reactor, bioconversion of FMW into liquid fertilizer was achieved in a shorter time under the same removal percentages of $COD_{Cr}$ and TN. The 52-hr culture of inoculated FMW was phytotoxic-free and it possessed comparable fertilizing ability to a liquid fertilizer made from the fish waste in hydroponic culture with amino acid contents of 5.93 g/ 100 g sample. From all the above results, transferring lab-scale data to large-scale production appeared to be successful. As a result, the commercialization of a liquid fertilizer made from FMW was feasible.

• 한국농공학회논문집
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• 제53권4호
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• pp.59-65
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• 2011

The purpose of this study was to analyze the water quality change when wastewater applied to study paddy fields. CREAMS-PADDY (Chemical, Runoff and Erosion from Agricultural Management System) model was used to estimate the field-scale water quality. Simulated results were compared with observed data monitored from Byeongjeom study paddy fields which is located near the Suwon sewage treatment plant in Gyeonggi-do. Significance analysis was performed for the three different irrigation water quality level and five fertilizer reduction scenarios using LSD (Least Significant Difference) and DMRT (Duncan's Multiple Range Test). Total nitrogen was found to be significant for both irrigation water quality level and fertilizer reduction while total phosphorus was not. Annual drainage load for total nitrogen was reduced by 66~92 % compared to irrigation load when treated wastewater irrigated to study paddy fields from 2002 to 2007. Total phosphorus was reduced by 70~86 %.

• 한국물환경학회지
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• 제32권4호
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• pp.343-348
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• 2016

A chemical sequencing batch reactor was operated to test the feasibility of nutrient recovery from a biological livestock wastewater treatment plant. Both phosphate and ammonia could be successfully recovered as magnesium ammonium phosphate (MAP) crystals. The contents of TP and TN in the recovered MAP crystals were 26.2% and 4.0%, respectively. Zn, Cr and Ti were identified in the crystals, but the contents remained below the Korean standard for an organic fertilizer. Chemical analyses confirmed that the MAP crystals could be useful phosphate fertilizers. On the other hand, the results of physical analyses using an X-ray diffractometer and an energy dispersive X-ray spectrometer strongly suggested that crystalline materials like magnesium potassium phosphate (KMP) and hydroxyapatite (HAP) were also formed during the MAP crystallization, depending on the availability of K⁺ and Ca²⁺.

• 한국환경과학회:학술대회논문집
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• 한국환경과학회 2019년도 정기학술대회 발표논문집
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• pp.134-134
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• 2019

Utilization of organic waste as a renewable energy source is promising for sustainability and mitigation of climate change. Pyrolysis converts organic waste to gas, oil, and biochar by incomplete biomass combustion. Biochar is widely used as a soil conditioner and adsorbent. Biochar adsorbs/desorbs metals and ions depending on the soil environment and condition to act as a nutrient buffer in soils. Biochar is also regarded as a carbon storage by fixation of organic carbon. Phosphorus (P) and nitrogen (N) are strictly controlled in many wastewater treatment plants because it causes eutrophication in water bodies. P and N is removed by biological and chemical methods in wastewater treatment plants and transferred to sludge for disposal. On the other hand, P is an irreplaceable essential element for all living organisms and its resource (phosphate rock) is estimated about 100 years of economical mining. Therefore, P and N recovery from waste and wastewater is a critical issue for sustainable human society. For the purpose, intensive researches have been carried out to remove and recover P and N from waste and wastewater. Previous studies have shown that biochars can adsorb and desorbed phosphates implying that biochars could be a complementary fertilizer. However, most of the conventional biochar have limited capacity to adsorb phosphates and nitrate. Recent studies have focused on biochar impregnated with metal salts to improve phosphates and nitrate adsorption by synthesizing biochars with novel structures and surface properties. Metal salts and metal oxides have been used for the surface modification of biochars. If P removal is the only concern, P adsorption kinetics and capacity are the only important factors. If both of P and N removal and the application of recovery are concerned, however, P and N desorption characteristics and bioavailability are also critical factors to be considered. Most of the researches on impregnated biochars have focused on P removal efficiency and kinetics. In this study, coffee waste is thermally treated to produce biochar and it was impregnated with Mg/Al to enhance phosphates and nitrate adsorption/desorption and P bioavailability to increase its value as a fertilizer. Kinetics of phosphates and nitrate adsorption/desorption and bioavailability analysis were carried out to estimate its potential as a P and N removal adsorbent in wasewater and a fertilizer in soil.

• 한국토양비료학회지
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• 제29권2호
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• pp.137-144
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• 1996

소규모(小規模) 축산농가(畜産農家)에서 배출(排出)되는 돼지(돈(豚))분뇨폐수(糞尿廢水)를 처리(處理)함과 동시(同時)에 재활용(再活用)할 수 있는 방법(方法)을 찾기 위하여 볏짚을 살수여상법(撒水濾床法)의 충전재(充塡材)로 사용(使用)하였다. 폐수처리후(廢水處理後) 볏짚을 부숙(腐熟), 건조(乾燥), 분쇄(粉碎)하여 토양(土壤)에 첨가(添加)한 후(後) 오그라기 상치를 재배(栽培)한 결과(結果)는 다음과 같다. 1. 농가퇴비(農家堆肥)에 비(比)해 부숙(腐熟)된 짚을 처리(處理)했을 시(時) 수량지수(收量指數)가 월등(越等)히 높았으며 N.P.K. 기본(基本) 시비(施肥)에 부숙(腐熟)된 짚 1750 kg/10a로 시용(施用)했을 때 수량지수(收量指數)가 가장 높았다. 2. 부숙(腐熟)된 짚을 시용(施用)한 토양(土壤)의 화학적(化學的)인 성질(性質) 중(中) pH, T-N, ava.P2O5, OM, 그리고 Ex.K, Ca, Mg이 증가(增加)했는데 반(反)하여 CEC은 본래(本來)의 값으로 귀착(歸着)되는 경향(傾向)이었다. 3. 짚을 살수여상법(撒水濾床法)의 충전재(充塡材)로 사용(使用)했을 경우(境遇)의 BOD, COD, SS의 제거(除去) 효율(效率)이 통상적(通常的)인 충전재(充塡材)와 별(別) 차이(差異)가 없었다.

• 한국수산과학회지
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• 제8권2호
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• pp.68-72
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• 1975

1. 본 조사항목중 비료공장 발수중에 많이 함유된 인산염이 해성에 따른 변동이 가장 심했다. 2. 해역별 년중 표층 인산염의 분포는 사비료공장이 위치한 행암만이 만외해역에 비해 평균 20배 이상의 가장 높은 농도분포를 보였으며 이것이 진해만 전역으로 확산되어 해외해역과 구별될 수 있는 양상을 보였다. 3. 사비공장이 설립되던 1967년도의 인산염의 분포와 비교하면 행암만 입구해역에서 평균 10배정도의 높은 농도를 보였다. 4. 굴 양식장이 많은 거제만은 만외해역보다 오히려 낮은 빈영양염 상태를 보였다. 5. 마산암은 도시하수 등의 오염에 의한 부식수역으로 하수 정화시설이 시급히 필요하다.

• 상하수도학회지
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• 제32권2호
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• pp.131-143
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• 2018

Phosphorus (P) is a limited, essential, and irreplaceable nutrient for the biological activity of all the living organisms. Sewage sludge ash (SSA) is one of the most important secondary P resources due to its high P content. The SSA has been intensively investigated to recover P by wet chemicals (acid or alkali). Even though $H_2SO_4$ was mainly used to extract P because of its low cost and accessibility, the formation of $CaSO_4$ (gypsum) hinders its use. Heavy metals in the SSA also cause a significant problem in P recovery since fertilizer needs to meet government standards for human health. Therefore, P recovery process with selective heavy metal removal needs to be developed. In this paper some of the most advanced P recovery processes have been introduced and discussed their technical characteristics. The results showed that further research is needed to identify the chemical mechanisms of P transformation in the recovery process and to increase P recovery efficiency and the yields.