• 제목/요약/키워드: Chemical condition

검색결과 4,183건 처리시간 0.029초

Characteristics of AlW thin film for TFT-FCD bus line

  • Kim, Dong-Sik;Yi, Chong-Ho;Chung, Kwan-Soo
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2000년도 제18회 학술발표회 논문개요집
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    • pp.58-58
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    • 2000
  • Recently low resistance of bus line is required for large screen size RFT-CLD panels. As a result, lower resistance Al-alloy is currently reviewed extensively. The resistivity is required smaller than 10$\mu$$\Omega$cm and high resistance of chemical attack is required. In this paper, Al-W thin film were deposited on glass substrates by D.C magnetron sputtering system under various condition for high chemical resistance. Its properties were characterized by SEM, AFM, XRD, 4-point-probe, and cyclic voltammertry. The optimal condition of Al-W was 10$0^{\circ}C$, 100W, 0.4Pa, 23sccm(Ar) and 35$0^{\circ}C$, 20min. annealing. At that condition the resistivity of Al-W(3 wt.%) was about 11$\mu$$\Omega$cm. And when wt.% of W in Al-W alloy was higher than about 4%, Al-W alloy thin film has high chemical resistance.

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Coalescence of Two Oppositely Charged Droplets at Constant Electric Potential

  • Lee, Dong Woog;Kang, In Seok
    • Korean Chemical Engineering Research
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    • 제59권2호
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    • pp.247-253
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    • 2021
  • Electrocoalescence is an active technique in petroleum industry, formation of raindrop in cloud, and digital microfluidics. In the present work, electrocoalescence of two droplets under the constant electric potential in air was studied. Through this experiment, we found that the electrocoalescence process could be divided three phases; deformation, formation of liquid bridge, and merging. And the condition for formation of liquid bridge between two droplets was obtained. For the connection of experimental result in constant potential condition with general case in constant charge condition, relationship of charge and potential difference was deduced by numerical computation. In high electric potential case, flat interfaces after recoiling were observed. It was interpreted through a numerical simulation of electric field.

혼합물 실험계획과 다수 반응변수 최적화를 통한 속경화 초저온접착제 개발 사례 (A Case Study of Developing Rapid-Hardening Ultra-Low Temperature Adhesives by Mixture Design and Multiple Response Optimization)

  • 변재현;서판석;신지은;이륜규;염지현
    • 품질경영학회지
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    • 제42권4호
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    • pp.757-768
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    • 2014
  • Purpose: In this paper we present a case study of developing fast curing adhesives for insulation material of LNG carriers using an extreme vertices design with four mixture components. Three material properties are considered - shear strength, viscosity, and tensile strength. In the optimization experiment, we used hardness instead of tensile strength due to shortage of specimens. Methods: We employ four-factor extreme vertices design with 19 runs and desirability function approach for simultaneously optimizing three responses. After selecting optimal condition of the mixture components, we do confirmation experiments to verify the reproducibility of the optimal condition under manufacturing circumstance. Results: Simultaneous optimal condition for the three responses, that is, shear strength, viscosity, and harness is obtained. At the optimal condition, confirmation experiments are executed in manufacturing circumstance. The variation for the shear strength is not satisfactory, which is due to the variation of the humidity. Conclusion: At the optimal condition three material properties are satisfactory. To reduce the variability for the shear strength, robust design is needed.

저압 화학 기상 증착법을 이용한 실리콘 표면 위의 텅스텐 박막의 증착 (Deposition of Tungsten Thin Film on Silicon Surface by Low Pressure Chemical Vapor Deposition Method)

  • 김성훈
    • 대한화학회지
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    • 제38권7호
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    • pp.473-479
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    • 1994
  • 저압 화학 기상 증착법을 사용하여 $WF_6$의 환원반응으로 텅스텐 박막을 p형 실리콘 (100)표면위에 증착하였다. Cold-wall조건에서는 실리콘 기판과 $SiH_4$를 각각 이용하여 $WF_6$를 환원시켜 텅스텐 박막을 증착하였으며 hot-wall 조건에서는 $WF_6$$SiH_4$로 환원시켜 증착하였다. 박막의 결정구조는 어느 조건에서나 체심입방구조를 이루었으며, 증착조건에 따른 박막의 물리적 및 전기적 특성을 조사하였다. 증착된 박막을 온도 $800^{\circ}C$에서 열처리한 결과 hot-wall 조건의 박막이 $WSi_2$로 변화하였다. Hot-wall과 cold-wall조건에서의 박막을 분석한 결과 박막의 특성은 cold-wall조건이 우수하나 hot-wall조건에서는 열처리 방법에 의하여 실리콘 기판과 적합성이 우수한 것으로 알려진 $WSi_2$ 박막의 제조가 가능함을 알 수 있었다.

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고분자 전해질 연료전지 구동 조건에 따른 MEA 열화 및 배출수 특성 (Degradation of MEA and Characteristics of Outlet Water According to Operation Condition in PEMFC)

  • 황병찬;이세훈;나일채;박권필
    • Korean Chemical Engineering Research
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    • 제55권4호
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    • pp.478-482
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    • 2017
  • 고분자 전해질 연료전지의 구동과정 중 습도제어는 매우 중요한 제어 조건이다. 물 관리 측면에서는 저가습 조건이 유리하고, 배출수 활용 및 에너지 효율면에서는 고가습이 유리하다. 본 연구에서는 배출수 활용면에서 저가습과 고가습 구동 과정에서 배출수의 특성에 대해서 연구하였다. 배출수의 불순물은 막과 전극의 열화 과정에서 발생하는 것이므로 저가습과 고가습 조건에서 막전극합체(MEA)열화에 대해서도 연구하였다. 연료극 0% RH의 저가습 조건에서 라디칼 발생속도가 커 고분자 막 열화의 주요 원인임을 보였다. 양쪽 극 모두 고가습(RH 100%) 0.6 V에서 불소 이온 농도 약 20 ppb로 낮은 농도를 나타내서, 수전해 원료수로 사용하기에 충분하였다. 고가습 조건에서 배출한 응축수에서 0.2 ppb 이하의 매우 낮은 농도의 백금이 검출되었다.

Metabolic Roles of Carotenoid Produced by Non-Photosynthetic Bacterium Gordonia alkanivorans SKF120101

  • Jeon, Bo Young;Kim, Bo Young;Jung, Il Lae;Park, Doo Hyun
    • Journal of Microbiology and Biotechnology
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    • 제22권11호
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    • pp.1471-1477
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    • 2012
  • Carotenoids produced by non-photosynthetic bacteria protect organisms against lethal photodynamic reactions and scavenge oxygenic radicals. However, the carotenoid produced by Gordonia alkanivorans SKF120101 is coupled to reducing power generation. SKF120101 selectively produces carotenoid under light conditions. The growth yield of SKF120101 cultivated under light conditions was higher than that under dark condition. In the cyclic voltammetry, both upper and lower voltammograms for neutral red (NR) immobilized in intact cells of SKF120101 were not shifted in the condition without external redox sources but were commonly shifted downward by glucose addition and light. Electric current generation in a biofuel cell system (BFCS) catalyzed by harvested cells of SKF120101 was higher under light than dark condition. The ratio of electricity generation to glucose consumption by SKF120101 cultivated in BFCS was higher under light than dark condition. The carotenoid produced by SKF120101 catalyzes production of reducing power from light energy, first evaluated by the electrochemical technique used in this research.

ZnCl2를 이용하여 폐감귤박으로부터 활성탄 제조 (Preparation of Activated Carbon from Waste Citrus Peels by ZnCl2)

  • 강경호;감상규;이민규
    • 한국환경과학회지
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    • 제16권9호
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    • pp.1091-1098
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    • 2007
  • Activated carbon was prepared from waste citrus peels by chemical activation with $ZnCl_2$. The optimal condition of carbonization was at $300^{\circ}C$ for 1.5 hr. Activation experiments with carbonized samples prepared at optimal carboniztion condition were carried out under various conditions such as activation temperature of 400 to $900^{\circ}C$, activation time of 0.5 to 2.0 hr, and $ZnCl_2$ ratio of 100 to 300%. In order to investigate the physical properties of the activated carbons prepared, iodine adsorptivities and specific surface areas were measured and their morphologies were observed from scanning electron microscopy. As $ZnCl_2$ ratio increased, activation yield decreased, while iodine adsorptivity and specific surface area increased. The optimal condition of activation was at 300% $ZnCl_2$ ratio and $300^{\circ}C$ for 1.5 hr, and then iodine adsorptivity and specific surface area was measured as about 862 mg/g and $756m^2/g$, respectively. SEM photography showed that the surface morphology was changed and many active pore were produced by chemical activation.

주기적인 약품역세를 적용한 침지형 MBR 시스템의 운전성능에 관한 연구 (Operational Performance of Submerged Membrane Bioreactor Combined with Periodic Chemical Backwash)

  • 김관엽;이의종;송준섭;김지훈;김형수
    • 상하수도학회지
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    • 제22권1호
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    • pp.87-92
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    • 2008
  • Purposes of this study were to evaluate operational performance of submerged membrane bioreactor (MBR) combined with periodic chemical backwash. Five lab-scale submerged MBRs were performed in accordance with NaOH dose, backwash solution volume. While filtration resistance of MBR system without backwash (Control) was increased persistently from startup, those of four MBR systems (RUN 1-4) with chemical backwash were maintained at $(1.4{\pm}0.16){\times}10^{12}$, $(8.6{\pm}0.90){\times}10^{11}$, $(1.9{\pm}0.10){\times}10^{12}$, $(1.4{\pm}0.10){\times}10^{12}l/m$, respectively. Under chemical backwash condition of 0.0230 M, 375 mL, permeability of membrane was highest at flux of $30L/m^2/hr$. According to results from experiment that changing condition of dose and volume, it was estimated that effect of chemical dose acts more greatly than backwash solution volume. Because COD removal rates of all MBR systems with chemical backwash were more than 96%, it was proved that NaOH added to backwash solution did not affect microorganism.