• Title/Summary/Keyword: Chemical compositions

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Influence of Sintering Additives and Temperature on Fabrication of LPS-SiC (액상소결법에 의한 탄화규소 제조시 소결조제와 온도의 영향)

  • JUNG HUN-CHAE;YOON HAN-KI
    • Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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    • 2004.11a
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    • pp.266-270
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    • 2004
  • SiC materials have been extensively studied for high temperature components in advanced energy system and advanced gas turbine because it has excellent high temperature strength, low coefficient of thermal expansion, good resistance to oxidation and good thermal and chemical stability etc. However, the brittle characteristics of SiC such as low fracture toughness and low strain-to fracture still impose a severe limitation on practical applications of SiC materials. For these reasons, SiC/SiC composites can be considered as a promising for various structural materials, because of their good fracture toughness compared with monolithic SiC ceramics. But, high temperature and pressure lead to the degradation of the reinforcing jiber during the hot pressing. Therefore, reduction of sintering temperature and pressure is key requirements for the fabrication of SiC/SiC composites by hot pressing method. In the present work, monolithic Liquid Phase Sintered SiC (LPS-SiC) was fabricated by hot pressing method in Ar atmosphere at $1800^{\circ}C$ under 20MPa using $Al_2O_3,\;Y_2O_3\;and\;SiO_2$ as sintering additives in order to low sintering temperature and sintering pressure. The starting powder was high purity $\beta-SiC$ nano-powder with all average particle size of 30mm. The characterization of LPS-SiC was investigated by means of SEM and three point bending test. Base on the composition of sintering additives-, microstructure- and mechanical property correlation, tire compositions of sintering additives are discussed.

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SiOC Anode Material Derived from Poly(phenyl carbosilane) for Lithium Ion Batteries

  • Lee, Yoon Joo;Ryu, Ji Yeon;Roh, Kwang Chul;Kim, Soo Ryong;Kwon, Woo Teck;Shin, Dong-Geun;Kim, Younghee
    • Journal of the Korean Ceramic Society
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    • v.50 no.6
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    • pp.480-484
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    • 2013
  • Since SiOC was introduced as an anode material for lithium ion batteries, it has been studied with different chemical compositions and microstructures using various silicon based inorganic polymers. Poly(phenyl carbosilane) is a SiOC precursor with a high carbon supply in the form of the phenyl unit, and it has been investigated for film applications. Unlike any other siloxane-based polymers, oxygen atoms must be utilized in an oxidation process, and the amount of oxygen is controllable. In this study, SiOC anodes were prepared using poly(phenyl carbosilane) with different heat treatment conditions, and their electrochemical properties as an anode material for lithium ion batteries were studied. In detail, cyclic voltammetry and charge-discharge cycling behavior were evaluated using a half-cell. A SiOC anode which was prepared under a heat treatment condition at $1200^{\circ}C$ after an oxidation step showed stable cyclic performance with a reversible capacity of 360 mAh/g.

Preparation of Onion Hydrolysates with Enzyme (효소에 의한 양파가수분해액의 제조)

  • 서형주;정수현;손종연;손흥수;조원대;마상조
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.25 no.5
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    • pp.786-790
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    • 1996
  • The changes in chemical constituents of onion in Korea and the degree of hydrolysis in onion by-drolysates by treatment of viscozyme L, celluclast 1.5L, pectinex and cereflo were investigated. Proximate compositions of onion in Korea were as follows; The contents of moisture, protein, lipid, carbohydrate and ash were 89~90%, 1.8~1.9%, 0.4~0.5%, 7.1~8.5% and 0.3~0.5%, respectively. Major free sugars were identified to be glucose, fructose and sucrose and major free amino acids were as cysteine, histidine, arginine and glutamic acid. The degree of hydrolysis by treatment of viscozyme L, celluclast 1.5L, pectinex and cereflo was 69%, 71%, 80% and 62%, respectively. During the enzymatic hydrolysis, free sugar and total sugar content increased however, pyruvic acid content decreased significantly.

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Food Component Characteristics of Plain Dried Anchovies on the Market (시판 소건멸치의 식품성분 특성)

  • 김진수;양수경;허민수
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.29 no.1
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    • pp.20-25
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    • 2000
  • This study was conducted to evaluate the quality of the plain dried anchovies on the market by determining chemical components, and compared with those of boiled-dried anchovy. The nutritional(total amino acid contents, mineral contents and fatty acid compositions) and favorite properteis (extratives nitrogen content, color and appearance) of plain dried anchovies were superior to those of boiled-dried anchovy. On the other hand, the lipid properties (peroxide value and acid value), food sanitary properteis (volatile basic nitrogen content) and sensory properties (odor) of plain dried anchovies were inferior to boiled-dried anchovy. These results indicated that the plain dried anchovy was classified into lower grade goods by food quality standards.

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A study on the preparation and characterization of $Zn_xSr_{1-x}S$ thin films ($Zn_xSr_{1-x}S$ 박막의 제작과 특성에 관한 연구)

  • 이상태
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2001.10a
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    • pp.660-664
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    • 2001
  • $Zn_xSr_{1-x}S$ thin films were prepared in the whole composition range by rf sputtering, using powder targets of a mixture of ZnS and SrS with the required mole fraction. The possibility of existence of $Zn_xSr_{1-x}S$ solid solutions was systematically investigated from the results of thin film growth, in terns of structural, optical characteristics and the chemical bonding of the constituent atoms. The XRD, XPS and optical results made it clear that the solid solutions with a single-phased zincblende structure and a single-phased rocksalt structure were formed at $0.86~0.93{\leq}x{\leq}1$ and $0{\leq}x{\leq}0.29$, respectively. The miscibility gap, including phase separation regions was found to exist in $0.3{\leq}x{\leq}0.86~0.91$, in which lattice constants, binding energy and absorption edges kept almost constant by the same values as those at border compositions. The experimental results on phase transition agreed well with the fraction of ionic character $f_{i}$ based on the Phillips'dielectric theory.

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Influence of Physicochemical Characteristic of Donghae-Samcheok Limestones on the Performance of Flue Gas Desulfurization (FGD) (동해-삼척지역 석회석의 물리화학적 특성이 탈황성능에 미치는 영향)

  • Seo, Jun-Hyung;Baek, Chul-Seoung;Kwon, Woo-Tech;Cho, Kye-Hong;Ahn, Ji-Whan
    • Resources Recycling
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    • v.24 no.6
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    • pp.38-44
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    • 2015
  • It studies that effect of limestone of physicochemical characteristic on the performance of flue gas desulfurization (FGD) and application examination for technology of wet type FGD process and to utilize the limestone in Donghae-Samcheok. The experiment method was measured total neutralizing capability (TNC) using the lab scale experimental apparatus based on the HCl titration test. The results of TNC of limestone samples were more dependent on the physical characteristics including particle size rather than chemical compositions such as CaO content and particle size of limestone get smaller, TNC is increased.

Optimization of $Nd^{3+}$ ion co-doping in $CaAl_2O_4:\;Eu^{2+}$ blue phosphor ($CaAl_2O_4:Eu^{2+}$ 청색(靑色) 형광체(螢光體)의 $Nd^{3+}$ 도핑 최적화(最適化)에 관한 연구(硏究))

  • Bartwal, Kunwar Singh;Ryu, Ho-Jin
    • Resources Recycling
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    • v.16 no.5
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    • pp.46-50
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    • 2007
  • Blue phosphor calcium aluminate, $CaAl_2O_4:Eu^{2+}$ co-doped with $Nd^{3+}$ was prepared by solid state synthesis method. Phosphor materials with 1 mol% $Eu^{2+}$ and varying compositions of $Nd^{3+}$ show high brightness and long persistent luminescence. The synthesized phosphor materials were investigated by powder x-ray diffraction (XRD), SEM, TEM, photoluminescence excitation and emission studies. Broad band UV excited luminescence of the $CaAl_2O_4:Eu^{2+}:Nd^{3+}$ was observed in the blue region (${\lambda}_{max}=440\;nm$) due to transitions from the $4f^65d^1$ to the $4f^7$ configuration of the $Eu^{2+}$ ion. $Nd^{3+}$ ion doping in the phosphor results in long afterglow phosphorescence when the excitation light is cut off.

Effect of Calcium Sulfate Dihydrate (Gypsum) on the Fundamental Properties of Slag-based Mortar (이수석고가 고로슬래그 미분말 베이스 무시멘트 모르타르의 기초물성에 미치는 영향)

  • Baek, Byung Hoon;Han, Cheon Goo
    • Journal of the Korea Institute of Building Construction
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    • v.14 no.3
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    • pp.252-258
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    • 2014
  • With the vision of 'a low carbon green develop' various industrial by-products were used as replacement of cement, in order to reduce $CO_2$ emissions from the manufacturing process of cement. Blast furnace slag is one of the industrial by-products. Due to the similar chemical compositions to ordinary Portland cement, blast furnace slag have been widely used in concrete with minimum side effects. Hence, in recent years, alkali activated slag-based composites are extensively studied by many researchers. However, the alkali activator can cause a number of problems in practice. Therefore, in this study, an alternative way of activating the slag was investigated. To activate the slag without using an alkali activator, calcium sulfate dihydrate was chosen and mixed with natural recycled fine aggregate. Fundamental properties of the slag-based mortar were tested to evaluate the effect of calcium sulfate dihydrate.

On the composition of free sugars, fatty acids, free amino acids and minerals in Lycium fructus (구기자의 당, 아미노산, 지방산, 무기물 조성)

  • Sung, Chang;Oh, Man Jin;Kim, Chan Jo
    • Korean Journal of Agricultural Science
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    • v.21 no.1
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    • pp.22-27
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    • 1994
  • Gugija, Lycium fructus, grown widely in Korea has long been used as a chinese herbal medicine. For utilization as a new resource in food industry, and as a fundamental study for processing various gugija products, the chemical compositions of Lycium fructus were studied. Three different kinds of free sugar were analyzed by HPLC, and the composions were glucose, 5.6% : fructose, 5.81% : sucrose, 4.39%, respectively. Free amino acids isolated as a major components in dried Lycium fructus were aspartic acid/asparagine, and glutamic acid/glutamine. The major fatty acids were linoleic, oleic, and palmitic acids, and these composed about 82.98~89.64% of total fatty acids. There are not much differences in contents of the major fatty acids among varieties in the fruits, Lycium fructus. The $Ca^{{+}{+}}$, $Fe^{{+}{+}}$ contents of chinese variety were higher than those of other fruit varities studied.

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Water Quality Characteristics and Fish Community of the Gucheon Reservoir and Yeoncho Reservoir in Geoge Island

  • Han, Jeong-Ho;Paek, Woon-Kee;An, Kwang-Guk
    • Korean Journal of Environment and Ecology
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    • v.29 no.1
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    • pp.29-45
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    • 2015
  • Water chemistry and fish community, based on fish compositions and ecological characteristics(trophic/tolerance guilds and condition factor), were compared in Gucheon Reservoir($G_cR$) and Yeoncho Reservoir($Y_cR$). Chemical parameters of water quality such as BOD, COD, nutrient(N, P) and suspended solids indicated that water quality was better in the $Y_cR$ than $G_cR$, and the temporal variability in seasonal and interannual patterns were greater in the $Y_cR$. The greater variability was mainly attributed to intense dilutions of reservoir water by Asian monsoon rain during July-August. Fish guild analysis indicated that species diversity was higher in the $G_cR$ than the $Y_cR$, and that the proportion of tolerant and omnivore species were greater in the $Y_cR$. Regression analysis of body weight-total length showed that the regression coefficient(b value) was lower in the $G_cR$(2.15 ~ 2.40) than the $Y_cR$(2.59 ~ 3.14). Condition factor(K) of fish against the total length showed negative slope of Zacco temminckii, Carassius auratus, Pseudorasbora parva and Rhinogobius brunneus population in the $G_cR$, and a positive slope of Carassius auratus and Rhinogobius brunneus population in $Y_cR$. Overall, our data suggest that the growth of the fish populations, based on the length-weight relations and condition factor, reflected the trophic regime of nutrients and organic matter.