• Title/Summary/Keyword: Chemical compositions

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Aerosol Characteristics at Tokchok Island in the Yellow Sea (황해상 덕적도의 대기 에어로졸 특성)

  • 이승복;배귀남;김용표;진현철;윤용석;문길주
    • Journal of Korean Society for Atmospheric Environment
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    • v.18 no.4
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    • pp.305-316
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    • 2002
  • Various air pollutants were measured at Tokchok Island in the Yellow Sea that is about 50 km distant from Incheon since April 1999. This study was undertaken to help understanding the level of air pollution and its distribution characteristics over the Yellow Sea. The geographical characteristics of the air pollution monitoring station and emission inventories of Tokchok Island are introduced. The mass concentrations and chemical compositions of TSP and P $M_{2.5}$ measured until March 2000 are discussed in this paper. The overall average mass concentrations are about 37.2 $\mu\textrm{g}$/㎥ for TSP and 18.7 $\mu\textrm{g}$/㎥ for P $M_{2.5}$ , respectively, which are similar to or a little lower than the values observed in other background sites at Kangwha and Taean. However, they are much lower than those observed at Qingdao in China. The low mass concentration and major anthropogenic ion concentrations in aerosols collected at Tokchok Island show that local sources are not dominant at Tokchok Island. The estimated average fractions of anthropogenic non-sea-salt sulfate to the total sulfate concentration of TSP and P $M_{2.5}$ are greater than 80% for both sizes. It hence suggests that the sulfate be mainly affected by anthropogenic sources. If we consider the average mass ratio of P $M_{2.5}$ to TSP, the mass fractions of anthropogenic species to P $M_{2.5}$ , and the molar ratio of nss S $O_4$$^{2-}$ to total N $O_{3-}$, it may be possible to infer that a part of anthropogenic species measured at Tokchok Island be transported from China. The characteristics of neutralization of nss S $O_4$$^{2-}$ and the particle size of major ions are also discussed.

Formation of Lipid-LCG with Hydrogenated Lecithin (수소첨가 레시친을 사용한 Lipid-LCG의 생성)

  • Kim, In-Young;Lee, Gun-Bong;Zhoh, Choon-Ku;Kang, Sam-Woo
    • Journal of the Korean Applied Science and Technology
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    • v.19 no.1
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    • pp.10-18
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    • 2002
  • In this study, it should be mentioned that Lipid-LCG can be prepared with the main compound of hydrogenated lecithin in oil-in water emulsion. The results of its physical property and stability are as follows. First, the best suitable compositions of Lipid-LCG are made from 4.0wt% of the hydrogenated lecithin, 4.0wt% of cetostearyl alcohol as emulsifier and gelling agent, 3.0wt% of butylene glycol and 2.0wt% glycerin as moisturizers, 3.0wt% of cyclomethicone, 3.0wt% of isononyl-isononanoate, 3.0wt% of capric/caprylic triglycerides, 3.0wt% of macadamia oil as emollients. Second, As the optimum conditions to form Lipid-LCG, which figured out 6.0 ${\pm}$ 1.0 for pH level, 32kg/mm, min for hardness to make a .essence to be formed the ternary phase of liquid crystal(multi-lamellar type). Third, as the analytical result of this system, it obtained that particle size is $1{\sim}8{\mu}m$ level, and is certified with it at 400 and 1,000 magnifications by microscope. The stability of Lipid-LCG is very stable on condition of a low temperature ($4^{\circ}C$), a room temperature ($25^{\circ}C$) and a high temperature ($40^{\circ}C$), which is not to be split in for a long time(for 3-month). We produced our own moisturizing essence, which has a good affinity to skin by means of this system.

Applications of Artificial Neural Networks for Using High Performance Concrete (고성능 콘크리트의 활용을 위한 신경망의 적용)

  • Yang, Seung-Il;Yoon, Young-Soo;Lee, Seung-Hoon;Kim, Gyu-Dong
    • Journal of the Korean Society of Hazard Mitigation
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    • v.3 no.4 s.11
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    • pp.119-129
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    • 2003
  • Concrete and steel are essential structural materials in the construction. But, concrete, different from steel, consists of many materials and is affected by many factors such as properties of materials, site environmental situations, and skill of constructors. Concrete have two kinds of properties, immediately knowing properties such as slump, air contents and time dependent one like strength. Therefore, concrete mixes depend on experiences of experts. However, at point of time using High Performance Concrete, new method is wanted because of more ingredients like mineral and chemical admixtures and lack of data. Artificial Neural Networks(ANN) are a mimic models of human brain to solve a complex nonlinear problem. They are powerful pattern recognizers and classifiers, also their computing abilities have been proven in the fields of prediction, estimation and pattern recognition. Here, among them, the back propagation network and radial basis function network ate used. Compositions of high-performance concrete mixes are eight components(water, cement, fine aggregate, coarse aggregate, fly ash, silica fume, superplasticizer and air-entrainer). Compressive strength, slump, and air contents are measured. The results show that neural networks are proper tools to minimize the uncertainties of the design of concrete mixtures.

A study on the characteristics of double insulating layer (HgCdTe MIS의 이중 절연막 특성에 관한 연구)

  • 정진원
    • Electrical & Electronic Materials
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    • v.9 no.5
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    • pp.463-469
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    • 1996
  • The double insulating layer consisting of anodic oxide and ZnS was formed for HgCdTe metal insulator semiconductor(MIS) structure. ZnS was evaporated on the anodic oxide grown in H$_{2}$O$_{2}$ electrolyte. Recently, this insulating mechanism for HgCdTe MIS has been deeply studied for improving HgCdTe surface passivation. It was found through TEM observation that an interface layer is formed between ZnS and anodic oxide layers for the first time in the study of this area. EDS analysis of chemical compositions using by electron beam of 20.angs. in diameter and XPS depth composition profile indicated strongly that the new interface is composed of ZnO. Also TEM high resolution image showed that the structure of oxide layer has been changed from the amorphous state to the microsrystalline structure of 100.angs. in diameter after the evaporation of ZnS. The double insulating layer with the resistivity of 10$^{10}$ .ohm.cm was estimated to be proper insulating layer of HgCdTe MIS device. The optical reflectance of about 7% in the region of 5.mu.m showed anti-reflection effect of the insulating layer. The measured C-V curve showed the large shoft of flat band voltage due to the high density of fixed oxide charges about 1.2*10$^{12}$ /cm$^{2}$. The oxygen vacancies and possible cationic state of Zn in the anodic oxide layer are estimated to cause this high density of fixed oxide charges.

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In-vitro and In-vivo Biocompatibility Evaluation of Silica Based Bio-active Glass Prepared by Hydrothermal Method

  • Sarkar, Swapan Kumar;Nguyen, Phuong Thi;Lee, Byong-Taek
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.05a
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    • pp.53.1-53.1
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    • 2011
  • Bioactive glass powders were synthesized by hydrothermal chemical route by the use of ultrasonic energy irradiation. We used sodalime, calcium nitrate tetra hydrate and di ammonium hydrogen phosphate as the precursor material to synthesize $SiO_2$ rich bio-active glass materials. The $SiO_2$ content was varied in the precursor mixture to 60, 52 and 45 mole%. Dense compacts were obtained by microwave sintering at $1,100^{\circ}C$. Mechanical properties were characterized for the fabricated dense bioactive glasses and were found to be comparable with conventional CaO-$SiO_2$-$Na_2O$-$P_2O_5$ bioactive glass. Detailed biocompatibility evaluation of the glass composition was investigated by in-vitro culture of MG-63 cell and mesenchyme stem cell. Cell adhesion behavior was investigated for both of the cell by one cell morphology for 30, 60 and 90 minutes. Cell proliferation behavior was investigated by culturing both of the cells for 1, 3 and 7 days and was found to be excellent. Both SEM and confocal laser scanning microscopy were used for the investigation. Western blot analysis was performed to evaluate the bimolecular level interaction and extent and rate of specific protein expression. The ability to form biological apatite in physiological condition was observed with simulated body fluid (SBF). In-vivo bone formation behavior was investigated after implanting the materials inside rabbit femur for 1 and 3 month. The bone formation behavior was excellent in all the bioglass compositions, specially the composition with 60% $SiO_2$ content showed most promising trend.

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Study on the Performance of Laser Welded joint of Aluminum alloys for Car Body

  • Kutsuna, Muneharu;Kitamura, Shuhei;Shibata, Kimihiro;Salamoto, Hiroki;Tsushima, Kenji
    • Proceedings of the KWS Conference
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    • 2002.10a
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    • pp.620-625
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    • 2002
  • Considering the fuel consumption of car, a light structure of aluminum alloys is desired for car body nowadays. However, fusion welding of aluminum alloys has some problems of reduction of joint efficiency, porosity formation and hot cracking. ill the present work, investigation to improve the joint performance of laser welded joint has been carried out by addition of Cu, Ni, and Zr to A6N01 alloy welds. Aluminum alloy plate of 2.0mm in thickness with filler metal bar was welded by twin beam Nd:YAG laser facility (total power:5kW). The filler metals were prepared by changing the chemical compositions for adding the elements into the weld metal. Thirteen filler metal bars were prepared and pre-placed into the base metal before welding. Ar gas shielding with a flow rate of 10 l/min was used. The defocusing distance is kept at 0 mm. At travel speeds of 3 to 9 m/min and at laser power of 5kW (front beam 2kW rear beam 3kW), full penetration welds were obtained, whereas at travel speeds of 12 to 18 m/min and same power, partial penetration was observed. The joint efficiency of laser-welded joint was improved by the addition of Cu, Ni, and Zr due to the solid solution hardening, grain refining and precipitation hardening. The type of hardening has been further considered by metallurgical examination.

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Hot Cracking Behavior in Inconel 690 Overlay Welds on Mn-Ni-Cr-Mo Steel for Pressure Vessels (Mn-Ni-Cr-Mo강에 대한 Inconel 690 오버레이 용접부에서의 고온균열의 발생거동)

  • 양병일;김정태;신용범;안용식;박화순
    • Journal of Welding and Joining
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    • v.20 no.2
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    • pp.82-89
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    • 2002
  • In order to clarify hot cracking phenomena occurred in Inconel 690 welds and it's prevention, in this study, the cracking behavior and the influence of welding variables on cracking in Inconel 690 overlay welds on Mn-Ni-Cr-Mo steel(SA 508 cl.3) for pressure vessel were investigated by using mock-up test. The main results are as follows: The cracks in Inconel 690 overlay welds were mainly generated near the start and the end part of welding beads adjacent to STS 309L welded outside of Inconel 690 welds. Most of the cracks showed typical solidification crack, and also it was assumed that there was possibility of liquation cracking in HAZ. The existence of Nb constituents or concentration of Nb was recognized on the fracture facets of the solidification cracks in the welds by SMAW. Therefore Nb was considered to be the main factor of the solidification cracking. As the weld heat input was more increased and the weld bead length was longer, the extent of cracking was more increased. Moreover the extent of cracking was considerably decreased by changing of welding sequence to the start and the end part of welds. Hot cracking in welds by GTAW was considerably decreased as compared with that of SMAW. And cracks were well generated in the Inconel 690 overlay welds adjacent to 575 309L welds. This means that the hot cracking susceptibility of Inconel 690 welds was largely varied by chemical components and/or compositions of filter metals, base metals and neighboring welds.

Characterization of the heat treatment of $AL_2O_3$ thin films by MOCVD (MOCVD법으로 제조한 $AL_2O_3$ 박막의 열처리에 의한 특성 평가)

  • 이상화;김종국;박병옥
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.7 no.2
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    • pp.216-223
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    • 1997
  • By using aluminum iso - propoxide($Al(OC_3H_7)_3$, AIP), $Al_2O_3$thin films were deposited on (100) single crystal silicon wafer by MOCVD method. The compositions of deposited films were analysed by electron spectroscopy for chemical analyse(ESCA). The morphology and thickness of the deposited films were characterized by scanning electron microscopy. The refractive index and C-V propertied were studied by using ellipsometery and HP4192A, respectively. From the results of ESCA and SEM analysis at low pressure, more uniform and stable stoichiometric film can be obtained compared with that of atmospheric pressure. For optical film usage, required refractive index can be obtained by heat treatment of deposited film. To improve C -V characteristics in NMOS device, it is requred to control OH-which is mobile charge in oxide, to form $SiO_2$ layer between $Al_2O_3$ and Si by heat treatment.

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Characteristics of Quality and Flow of Water Resources at Palaces in Seoul Metropolitan (서울 시내 궁궐 수원의 수질과 유동 특성)

  • Naranchimeg., B;Lee, Jae-Min;Woo, Nam-C.;Kim, Youn-Tae;Lee, Kang-Jin
    • Journal of Soil and Groundwater Environment
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    • v.16 no.2
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    • pp.61-76
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    • 2011
  • This study was objected to provide suggestions for best management practices to restore the cultural and historical values of the wells in Palaces as well as their water qualities. Water resources in the five Palaces in Seoul Metropolitan, including Gyeongbokgung, Changdeokgung, Changgyeonggung, Jongmyo Shrine, and Deoksugung, were surveyed for their physical flows and chemical compositions from April to July in 2010. Ground waters in most wells were found at depths within 5 m from the ground surface, showing typical water-table aquifer systems. Hydraulic gradients indicate water resources in Gyeongbokgung, Changdeokgung, and Changgyeonggung flowing toward south, and toward east in Deoksugung area. Especially, water-level fluctuation data at S-10 in Deoksugung implied the influence of groundwater discharge facility. In Jongmyo Shrine, water was not detected in wells, indicating the water level was lower than the well depth. Based on the water chemistry and stable isotope analyses, water resources and their qualities appeared to be formed by the water-rock interaction along the groundwater paths. S-10 (Deoksugung) and S-14 (Changgyeonggung) samples were contaminated with nitrate ($NO_3$) in levels of higher than Korean drinking water standard, 10 mg/L as $NO_3$-N, but once in four sampling campaigns. In the situation that water resources in Palaces still maintain natural characteristics, the materials that will be used for the restoration and improvement of the Palace water supplies should be carefully selected not to disturb the natural integrity. In addition, because the wells are located in the center of metropolitan area, a systematic monitoring should be applied to detect and to manage the potential impacts of underground construction and various pollution sources.

Effect of Citrus Byproduct on Quality and Fatty Acid Composition of Chicken Eggs (감귤부산물의 급여가 계란의 품질 및 지방산 조성에 미치는 영향)

  • Moon, Yoon-Hee;Jung, In-Chul
    • Journal of Life Science
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    • v.20 no.9
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    • pp.1358-1364
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    • 2010
  • In this study, the effects of feeding citrus by-products on the quality and fatty acid compositions of chicken eggs were investigated. Two samples of chicken eggs were used for this study: T0 (eggs of chickens that were not fed citrus byproducts) and T1 (eggs of chickens that were fed 4% citrus byproducts). There was no statistically meaningful difference between T0 and T1 in terms of various properties, such as chemical composition, cholesterol content, minerals, vitamins, pigments, and total structural amino acid. The caloric content of the egg yolk was higher in T1 than in T0, and total free amino acid of egg albumin and egg yolk was higher in T1 than in T0 (p<0.05). There was a not significant difference in SFA:UFA ratio between T0 and T1, but the linolenic acid content was higher in T1 than in T0 (p<0.05). The results of this study show that citrus by-products can be used for feed for laying hens by adding them to general feed.