• 패션비즈니스
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• 제12권6호
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• pp.23-33
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• 2008

The physico-chemical characteristics by bleaching treatments were assessed by several instrumental analyses such as surface morphology, chemical structural change, color change as well as tensile strength. The change of morphological characteristic was observed through scanning electron microscope(SEM). The observation of the fine structure on hair surface by SEM showed the bleached hair had much damaged to hair cuticle, and some of cuticle surface were worn away. To investigate the chemical structural changes in hair keratin, the cross-sections of hair samples were directly analysed using Fourier transform infrared microspectroscopy(FT-IRM). The results showed the cysteic acid S=O band intensity was distinctively increased by performing the bleaching treatment. The cleavage of cystine was appeared to proceed primarily through the sulfur-sulfur (-S-S-) fission whereby cysteic acid was formed as a principal oxidation products. The distribution of amide I band in hair keratin was determined by attenuated total reflectance(ATR) FT-IR mapping image. The results showed that the outer side of hair cortex was more damaged than the inner side of the hair cortex. Also, during chemical bleaching of the hair with alkaline peroxide, the hair was turned to reddish yellow due to the oxidative degradation of eumelanin. This means the eumelanin is more unstable than pheomelanin in chemical oxidation. With bleaching, the tensile strength was also reduced as a results of the chemical oxidation.

• 대한화학회지
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• 제43권4호
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• pp.475-484
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• 1999

중학교 2학년 과학 교과서 물질의 구성 단원의 주요 개념인 화학 변화 관련 개념을 학습함에 있어 논리적 위계에 따라 제시된 과학 교과서의 교수 학습 순서인 화학 변화${\rightarrow}$원자${\rightarrow}$분자${\rightarrow}$분자 운동과, 분자와 원자를 화학 변화의 선행 조직자로 하여 새롭게 배열한 분자${\rightarrow}$ 분자 운동${\rightarrow}$원자${\rightarrow}$화학 변화의 교수 학습 순서 중, 어떠한 교수 학습 순서가 화학 변화 관련 개념을 이해하는데 효과적인가를 알아보았다. 이를 위하여 서울에 위치한 1개 중학교에서 남, 여 학생 각각 2개 반 씩 168명을 표집하여 실험반과 통제반으로 나누어 연구를 실시하였다. 연구 결과, 과학 교과서에서 제시하고 있는 교수 학습 순서 보다 본 연구에서 새롭게 배열한 교수 학습 순서가 학생들의 화학 변화 관련 개념 이해에 효과적이었음을 나타내었다. 그러나 학생들은 수업 처치가 효과가 있었음에도 불구하고 혼란스러웠다는 문제점을 제기하였으므로, 학생들에게 혼란스러움을 주지 않으면서도 효과적인 개념 학습을 위해서는 모든 과학 교과서의 획일적인 교수 학습 순서를 지양하고 교과서마다 특색 있고, 다양한 교수 학습 순서를 제시하는 것이 필요할 것으로 생각된다.

• Carbon letters
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• 제11권3호
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• pp.176-183
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• 2010

PAN precursor fibers were produced via wet-spinning process, and effects of polymerization and spinning processes, especially the stretching process, were investigated on mechanical properties and micro-morphologies of precursor fibers. An increase in molecular weight, dope solid and densification and a decrease in surface defects were possible by controlling polymerization temperature, the number of heating rollers for densification and the jet stretch ratio, which improved the mechanical properties of precursor fibers. The curves for strength, modulus, tensile power and diameter as a function of stretch ratio can be divided into three stages: steady change area, little change area and sudden change area. With the increase of stretch ratio, the fiber diameter became smaller, the degree of crystallization increased and the structure of precursor fibers became compact and homogeneous, which resulted in the increase of strength, modulus and tensile power of precursor fibers. Empirical relationship between fiber strength and stretch ratio was studied by using the sub-cluster statistical theory. It was successfully predicted when the strengths were 0.8 GPa and 1.0 GPa under a certain technical condition, the corresponding stretch ratio of the fiber were 11.16 and 12.83 respectively.

• 한국산업보건학회지
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• 제16권1호
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• pp.68-80
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• 2006

This study aimed to prepare the fundamental data and assess the status and trend of exposure level for 5 chemical substances such as sulfuric acid, hydrogen chloride, ammonia, formaldehyde and phenol in manufacturing industry by type of industry, working process, and size of factory, chronological change. Subjects related to this study consist of 146 factories, 12 industries and 17 working processes located in Busan area from Jan. 1997 to Dec. 2001. 1. All 5 kinds of chemical substances by type of industry, working process were generated in chemical manufacturing industry. There were founded in 8 types of industries and 13 types of working processes for ammonia, which is the highest number of in all 5 chemical substances. 2. In terms of the exposure level for 5 chemical substances by type of industry, working process, geometric mean concentration for sulfuric acid was $0.40mg/m^3$ in manufacture of chemicals and chemical products, $0.30mg/m^3$ in compounding process, for hydrogen chloride was 0.57 ppm in manufacture of basic metal, 0.48 ppm in dyeing process, for ammonia was 1.11 ppm in manufacture of rubber and plastic products, 0.94 ppm in buffing process, for formaldehyde was 0.49 ppm in manufacture of wood and of products of wood and cork, except furniture; manufacture of articles straw and plating materials, 0.53 ppm in mixing process, and for phenol were 0.53 ppm in manufacture of chemical and chemical products, 0.55 ppm in compounding process, respectively. Results for 5 chemical substances by type of industry and working process were significantly higher than those of the others(p<0.05). 3. The exposure level for hydrogen chloride, formaldehyde were significantly increased by size of industry (p<0.01). ammonia was significantly decreased by size of industry (p<0.01). 4. In trend of the concentration difference of five chemical substances by chronology, geometric mean concentration for sulfuric acid was significantly increased (p<0.01), hydrogen chloride and ammonia were significantly decreased by year (p<0.05) and for formaldehyde and phenol were decreased in chronological change. According to the above results 5 chemical substances were founded together in a way mixed in the same places one another and concentrations of chemical substances by industry, working process, size of industry and year appeared markedly. The authors recommend more systemic and effective work environmental management should be conducted in workplaces generating five chemical substances.

• Korean Chemical Engineering Research
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• 제44권3호
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• pp.289-293
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• 2006

탄산칼슘을 제조하는 연속식 결정화 공정에서 결정의 입도분포에 대한 온도와 교반속도 영향을 연구하였다. 연속식조업에서 용액의 산도 변화는 적었다. 교반속도가 300 RPM 이하, 용액의 온도가 낮으면 탄산칼슘 결정의 부피 평균크기는 안정하였고, 전자현미경 사진 관찰에서 calcite와 aragonite가 만들어졌음을 알 수 있었다

• Bulletin of the Korean Chemical Society
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• 제24권5호
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• pp.667-670
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• 2003

• 대한화학회지
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• 제65권2호
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• pp.145-150
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• 2021

The present study describes a hands-on experiment to help students understand the concept of phase change or phase transition and its application in a phase change material (PCM). PCMs are substances that have the capability of storing and releasing large amounts of thermal energy. They act as energy storage materials that provide an effective way to save energy by reducing the electricity required for heating and cooling. Lauric acid (LA) was selected as an example of the PCM. Students investigated the temperature change of LA and the temperature (of air) inside the test tube. The differences in the temperatures of the systems helped students understand how PCMs work. A one-group pretest and posttest design was implemented with 34 grade-11 students in science and mathematics. Students' understanding was assessed using a multiple-choice test and a questionnaire. The findings revealed that the designed activity helped students understand the concept of phase change and its application to materials for thermal energy storage.

• Macromolecular Research
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• 제11권4호
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• pp.236-240
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• 2003

Fabrication of a graded index profile was possible via photochemical reaction of cinnamoyl groups with 350 nm wavelength UV light to form crosslinked structures. Such structural change may induce the change in the refractive index. In order to generate graded index profile in the PMMA polymer optical fiber (POF) with cinnamoyl groups by photochemistry, a methyl methacrylate monomer containing a cinnamoyl functional group in the side chain were prepared. This monomer was then copolymerized with methyl methacrylate with various compositions not only to utilize advantages of poly(methyl methacrylate) but also to overcome the drawbacks of the cinnamate homopolymer. Changes of refractive indices were investigated with various contents of cinnamoyl group and varying irradiation time. Large change in the refractive index (${\Delta}{\approx}0.01$) and its proper profile shape ($g{\approx}2.2$) can be obtained by changing irradiation time.

• 대한화학회지
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• 제48권1호
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• pp.53-65
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• 2004

이 연구에서는 물질의 성질을 나타내는 기본 단위 중 분자에 대한 개념과 물리변화와 화학변화로 대변되는 물질변화 개념의 변천을 과학사적으로 고찰하여 특징적인 관점의 변화에 따라 구분하였다. 이 연구에서는 물질의 성질을 나타내는 기본 단위를 과학사적 변천에 따라 5가지 관점으로 유목화하였다. 그리고 물리변화와 화학변화의 정의는 물질의 성질을 나타내는 기본 단위의 개념과 밀접한 관련성을 가지는 3가지 관점으로 유목화하였다. 중학교 과학 교과서와 고등학교 화학 교과서, 그리고 대학교 일반화학 교과서에 제시된 개념을 분석한 결과, 분자의 정의와 물질 변화의 정의 안에는 이러한 여러 시대의 정의들이 혼재된 상태로 제시되어 있음을 확인할 수 있었다. 경우에 따라서는 진술 자체에 논리적 모순점이 있는 경우도 있었다. 이러한 경향은 제 4차 과학 교육과정에서부터 제 7차 과학 교육과정까지의 과학 교과서에서 지속되었다.

• Bulletin of the Korean Chemical Society
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• 제29권8호
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• pp.1451-1458
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• 2008