• Title/Summary/Keyword: Chemical additives

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Effects of additives and sintering temperature on phase evolution and properties of carbon-clay ceramic composites

  • Aramide, Fatai Olufemi;Adepoju, O.D.;Popoola, Abimbola Patricia
    • Journal of Ceramic Processing Research
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    • v.19 no.6
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    • pp.483-491
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    • 2018
  • Effects of additives on phase development and physico-mechanical properties of mullite-carbon was investigated. Powdered clay, kaolinite and graphite of predetermined compositions were blended with additives using ball mill for 3 hrs at 60 rev/min. Samples were produced by uniaxial compression and sintered between $1400^{\circ}C$ and $1600^{\circ}C$ for one hr. They were characterized for various properties, developed phases and microstructural features. It was observed that the properties and phase developments in the samples were influenced by the additives. 10 wt % SiC served as nucleating point for SiC around $1400^{\circ}C$. 10wt % $TiO_2$ lead to development of 2.5 wt % TiC at $1500^{\circ}C$ which increased to 6.8 wt % at $1600^{\circ}C$. Ifon clay in the sample leads to development of anorthite and microcline in the samples. 10wt % $TiO_2$ is effective as anti-oxidant for graphite up to $1500^{\circ}C$. Base on strength and absorbed energy, sample C (with 10wt % $TiO_2$) sintered at $1500^{\circ}C$ is considered to be optimum.

The Effect of Additives on the Mechanical Properties of Rigid Polyurethane (경질 폴리 우레탄의 기계적물성에 미치는 첨가제의 영향)

  • Na, Seok-En;Choi, Hwan-Oh;Lee, Jeon-Kyu;Kim, Si-Young;Ju, Chang-Sik
    • Korean Chemical Engineering Research
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    • v.50 no.5
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    • pp.783-788
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    • 2012
  • Stern tube bearing is a shaft device playing important roles to reduce the friction of axial rotation and to support the weight of shaft. However, because there is no domestic producer of stern tube bering, imported stern tube bearings have many practical problems including prices, delivery and after services. This is why stern tube bearing should be localization. For the purpose of development of polyurethane resin for stern tube bearings, the effect of additives on the hardness, tensile strength and elongation of the polyurethane resin were systematically investigated. For the preliminary researches, depending on the type of curing agent, MOCA type and non-MOCA type polyurethanes were synthesized. Preliminary researches concluded that MOCA type polyurethane resin has more excellent mechanical properties than non-MPCA type for stern tube bearings that Tensile strength and Hardness of non-MOCA type investigated 23 D, 4.3 Mpa. Therefore, MOCA type polyurethane was adapted as base resin of this research. Silica, calcium carbonate and graphite were selected as additives for the enhancement of mechanical properties of polyurethane resin. Effect of the type and the dosage of these additives on the hardness, tensile strength, elongation of the polyurethane resin were experimentally examined. However, addition of calcium carbonate and graphite showed only minor effect on the hardness of the resin. Polyurethane resin with silica showed relatively excellent hardness, tensile strength and improved elongation.

The Effects of Freezing and Supplementation of Molasses and Inoculants on Chemical and Nutritional Composition of Sunflower Silage

  • Konca, Y.;Buyukkilic Beyzi, S.;Ayasan, T.;Kaliber, M.;Bozkurt Kiraz, A.
    • Asian-Australasian Journal of Animal Sciences
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    • v.29 no.7
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    • pp.965-970
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    • 2016
  • This study was conducted to determine the effects of freezing and supplementation of molasses (M), lactic acid bacteria (LAB) and LAB+enzyme mixture on chemical and nutritional composition of sunflower silage (SF). Sunflower crops were harvested (at about $29.2%{\pm}1.2%$ dry matter) and half of fresh sunflower was ensiled alone and half was frozen (F) at $-20^{\circ}C$ for 7 days. Silage additives were admixed into frozen SF material. All samples were ensiled in glass jars with six replicates for 90 days. The treatments were as follows: i) positive control (non-frozen and no additives, NF), ii) negative control (frozen, no additives, F), iii) F+5% molasses (FM), iv) F+LAB (1.5 g/tons, Lactobacillus plantarum and Enterococcus faecium, FLAB); v) F+LAB+enzyme (2 g/tons Lactobacillus plantarum and Enterococcus faecium and cellulase and amylase enzymes, FLEN). Freezing silage increased dry matter, crude ash, neutral detergent fiber, and acid detergent lignin. The organic matter, total digestible nutrient, non-fiber carbohydrate, metabolizable energy and in vitro dry matter digestibility were negatively influenced by freezing treatments (p<0.05). In conclusion, freezing sunflower plants prior to ensiling may negatively affect silage quality, while molasses supplementation improved some quality traits of frozen silage. Lactic acid bacteria and LAB+enzyme inoculations did not effectively compensate the negative impacts of freezing on sunflower silage.

Effect of Additive-added Epoxy on Mechanical and Dielectric Characteristics of Glass Fiber Reinforced Epoxy Composites (유리섬유강화 에폭시 레진 복합체의 기계적, 유전체 특성에 미치는 첨가제 함유 에폭시 영향)

  • Vu, Cuong Manh;Nguyen, Liem Thanh;Nguyen, Thai Viet;Choi, Hyoung Jin
    • Polymer(Korea)
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    • v.38 no.6
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    • pp.726-734
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    • 2014
  • Three different types of additives, thiokol, epoxidized natural rubber (ENR) and epoxidized linseed oil (ELO), were dispersed in an epoxy matrix before being used in glass fiber (GF) composites, and their effects on the mechanical and dielectric properties of epoxy resin and glass fiber reinforced epoxy composites (GF/EP) were examined. The addition of each of 7 phr ENR, 9 phr ELO and 5 phr thiokol into the epoxy resin increased the fracture toughness significantly by 56.9, 43.1, and 80.0%, respectively, compared to the unmodified resin. The mode I interlaminar fracture toughness of the GF/EP at propagation was also improved by 26.9, 18.3 and 32.7% when each of 7 phr ENR, 9 phr ELO, and 5 phr thiokol, respectively, was dispersed in the epoxy matrix. Scanning electron microscopy showed that the additives reduced crack growth in the GF/EP, whereas their dielectric measurements showed that all these additives had no additional effect on the real permittivity and loss factor of the GF/EP.

MOLECULAR BASIS OF LUBRICATION

  • Hsu, S.M.
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2002.10b
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    • pp.49-50
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    • 2002
  • Rapid advancements in analytical instrumentations and techniques in the last several decades offer an unprecedented opportunity to analyze the complex chemistry and probe the surfaces for chemical evidence. Recent developments in nanotechnology provide further ability to examine phenomena and mechanisms at the nanometer level. As a result of these advances, our understanding of the complex lubrication system has improved significantly. This paper will attempt to provide a molecular basis of how lubricant and additives function in lubrication.

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Effects of wilting and additives on the ensiling quality and in vitro rumen fermentation characteristics of sudangrass silage

  • Wan, Jiang Chun;Xie, Kai Yun;Wang, Yu Xiang;Liu, Li;Yu, Zhu;Wang, Bing
    • Animal Bioscience
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    • v.34 no.1
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    • pp.56-65
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    • 2021
  • Objective: This study was conducted to investigate the effects of molasses and Lactobacillus plantarum on the ensiling quality and in vitro rumen fermentation of sudangrass silage prepared with or without wilting. Methods: The ensiling experiment, measured with 3 replicates, was carried out according to a 2×4 (wilted stages×additives) factorial treatment structure. Dry matter of the fresh (210 g/kg fresh matter) or wilted (305 g/kg fresh matter) sudangrass were ensiled (packed into 5.0-L plastic jars) without additive (control) or with molasses (M), Lactobacillus plantarum (LP), or molasses + Lactobacillus plantarum (M+LP). After 60 days of ensiling, the silages were analyzed for the chemical, fermentation, and in vitro characteristics. Results: After 60 days of ensiling, the fermentation parameters were affected by wilted, the additives and the interactions of wilted with the additives (p<0.05). The M+LP treatment at wilted had higher lactic acid levels and V-score (p<0.05) but lower pH values and butyric acid concentrations than the other treatments. In comparison with sudangrass before ensiling, after ensiling had lower dry matter and higher non-fibrous carbohydrate. The in vitro gas production, in vitro dry matter digestibility, in vitro crude protein digestibility, and in vitro acid fiber detergent digestibility changed under the effects of the additives. Significant interactions were observed between wilted and the additives in terms of in vitro gas production at 48 h, asymptotic gas production, gas production rate, half time, and the average gas production rate. The total volatile fatty acid levels in the additive treatments were higher than those in the control. Conclusion: Wilting and supplementation with molasses and Lactobacillus plantarum had the ability to improve the ensiling quality and in vitro nutrient digestibility of sudangrass silage. The M+LP treatment at wilted exhibited the strongest positive effects on silage quality and in vitro ruminal fermentation characteristics.

A Study on Surface Mixing Method by Chemical Stabilizer (화학약액에 의한 표층혼합공법에 관한 연구)

  • 진병익;유재일
    • Geotechnical Engineering
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    • v.1 no.2
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    • pp.55-66
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    • 1985
  • This paper is studied about the character of mixed soil which is applied lime and water-glass The effectiveness of mining such as cut-off effect and shear strength increasement of the chemically treated soils are investigated. For the main purpose of this study is to develope economical and practical method in chemical mixing method. The principal contents are described as follow. (1) Lime and water-glass series are used as chemical stabilizer and secondary additives in this experiment. (2) This study was analized and compared with engineering properties by the quantity of additives and by the character of chemical stabilizer. (3) And the effects of improvement in those treated soils are investigated as below; the increasement of shear strength, cut.off effect and consolidation character.

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The Function of Hydrogen Chloride on Methane-Air Premixed Flame (메탄-공기 예혼합 화염에서 염화수소의 역할)

  • Shin, Sung-Su;Lee, Ki-Yong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.29 no.9 s.240
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    • pp.979-987
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    • 2005
  • Numerical simulations were performed at atmospheric pressure in order to understand the effect of additives on flame speed, flame temperature, radical concentrations, $NO_x$ formation, and heat flux in freely propagating $CH_4-Air$ flames. The additives were both carbon dioxide and hydrogen chloride which had a combination of physical and chemical behavior on hydrocarbon flame. In the flame established with the same mole of methane and additive, hydrogen chloride significantly contributed toward the reduction of flame speed, flame temperature, $NO_x$ formation and heat flux by the chemical effect, whereas carbon dioxide mainly did so by the physical effect. The impact of hydrogen chloride on the decrease of the radical concentration was about $1.4\~3.0$ times as large as that of carbon dioxide. Hydrogen chloride had higher effect on the reduction of $EI_{NO}$ than carbon dioxide because of the chemical effect of hydrogen chloride. The reaction, $OH+HCl{\rightarrow}Cl+H_2O$, played an important role in the heat flux from flames added by hydrogen chloride instead of the reaction, $OH+H_2{\rightarrow}H+H_2O$ which was an important reaction in hydrocarbon flames.

Generation of Hazardous Gas and Corrosion Originated from Anaerobic Digestion of Process Water in OCC Recycling Mill (골판지 재활용 공정수의 혐기성 분해에 따른 유해 기체의 생성과 부식)

  • Park, Dae-Sik;Ryu, Jeong-Yong;Song, Bong-Keun;Seo, Yung-Bum;Sung, Yong-Joo
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.37 no.3
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    • pp.59-65
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    • 2005
  • There are accumulations of remained chemical additives and contaminants in the process water of semi-closed linerboard mill. High temperature of the process water aggravates the anaerobic digestion of contaminated process water and causes the generation of hazardous gases, which are from the biological reaction of varied additives and contaminants. The hydrogen sulfide in the gases easily combine with moisture in the air, and become sulfuric acid, which causes corrosion of paper machinery. This hydrogen sulfide is from the reduction of sulfate ions in the process water, and the sulfate ions are mostly from the alum. We changed the alum to PAC (Poly Aluminum Chloride). The results were preventing generation of hydrogen sulfide, and equivalent sizing effect by the use of PAC.