• 한국정보디스플레이학회:학술대회논문집
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• 2007.08a
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• pp.493-495
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• 2007

Cinnamate groups are well-known for a dimerization reaction upon exposure to ultraviolet irradiation and a thermal reaction after being heated. In this study, to verify the thermal reaction of the cinnamate group in detail, we investigated the thermal crosslinking of cinnamate oligomers. The thermal reaction of cinnamate oligomers of low molecular weight is induced more readily by thermal energy compared with that of cinnamate polymers. The orientation of the liquid crystal depended on the length of the spacers in the cinnamate oligomers.

• Journal of the Korean Institute of Gas
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• v.24 no.4
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• pp.32-38
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• 2020

Based on the cases of fire and explosion accident in the chemical reactor, thr problems of preventive measures installed in the chemical reactor were analyzed. The chemical reactors produce a variety of chemicals and install rupture disk to relieve the pressure that rises sharply in the event of a runaway reaction. In order to maintain the function of the rupture disk, the emissions was allowed to be discharged into the atmosphere, resulting in fire and explosion accidents. As a way to improve this, safety instrumented system based on the safety integrity level(SIL3) was applied as a preventive measures for chemical reactor. Two emergency shur-off valves are installed in series on pipe dropping raw materials for chemical reactor so that the supply of raw materials can be cut off even if only one of the two emergency shut-off valves is operated during the runaway reaction. The automatic on/off valve is installed in parallel in the supply pipe of the reaction inhibitor so that the reaction inhibitor can be injected even if only one valve is opened at the time of the runaway reaction.

• Journal of the Korean Chemical Society
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• v.47 no.4
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• pp.376-390
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• 2003

The contents of chemical reaction in the science textbooks, used by starting from elementary school to college level, were investigated how much closely connected with them. For this purpose, nineteen subjects of chemistry contents were selected and the articulation analysis, classified into 5 criteria, was carried out. The results indicated that the articulation from elementary school to middle school looked quite acceptable, but there was a big gap from middle school to high school and the articulation from high school to college exhibited a big overlap and gap. Finally, the flow map of chemical reaction was suggested.

• New & Renewable Energy
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• v.19 no.4
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• pp.11-19
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• 2023

Levulinic acid (LA) derived from cellulosic biomass, serves a crucial intermediate that can be used in various chemical conversions. This study focused on optimizing the production of LA using two types of pretreated rice husk (de-ashed and delignificated cellulosic biomass) in a batch reaction system through catalytic conversion with sulfuric acid. To determine the optimal conditions, the conversions of glucose and α-cellulose were examined to compare the effects of pretreatment on the rice husk. The experimental parameters covered a broad spectrum, including temperatures ranging from 140℃ to 200℃, a reaction time was up to 600 minutes, and a substrate to catalyst (acid solution) ratio of 100 g/L. The highest LA yield was 44.8%, achieved from de-ashed rice husk with 3.0 wt.% of sulfuric acid at 180℃ and with a reaction time of 180 minutes. In the case of the delignificated rice husk, a LA yield of 43.6% was obtained with 3.0 wt.% of sulfuric acid at 200℃ and with reaction time of 30 minutes.

• Bulletin of the Korean Chemical Society
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• v.33 no.10
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• pp.3430-3432
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• 2012

• Bulletin of the Korean Chemical Society
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• v.33 no.4
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• pp.1383-1385
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• 2012

• Bulletin of the Korean Chemical Society
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• v.34 no.5
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• pp.1477-1480
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• 2013

The Suzuki cross-coupling reactions proceeded in excellent yields when it was catalyzed by magnetically recyclable nanocatalyst. This nanocatalyst provided very high catalytic activity with low loading level (1 mol %), because the palladium nanoparticles were so small in size (~2 nm) and located on the surface of the nanocomposite. It was also easily recovered from the reaction mixture using a magnet and reused for six consecutive cycles.

• Proceedings of the International Microelectronics And Packaging Society Conference
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• 2004.09a
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• pp.165-180
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• 2004

Phosphor contents are critical to the interfacial reaction and IMC behavior. - If content is too low, the dissolution rate will be very fast. - If content is too much, the cracks during interfacial reaction and the IMCs spalling will easily occur. The spalling of IMCs caused the brittle fracture of solder joint under shear test. IMCs from chemical reaction influences to the mechanical properties and life time. Composition changes from chemical reaction influence to the life time.

• Journal of the Korean Chemical Society
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• v.7 no.1
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• pp.85-90
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• 1963

The Knoevenagel reaction of fluorinated carbonyl compounds, 1,1,1-trifluoro-propanone-2-heptafluoro-butyraldehyde, 1,3-dichloro-1,1,3,3-tetrafluoro-acetone, tetradecafluoro-heptanone-4 and 2,2,2-trifluoro-acetophenone yielded fluorinated ${\beta},{\beta}$-dialkyl-${\beta}$-hydroxy acids. Dehydration of the acids do not give the olefinic acid in the case of the perfluorinated system and gave a lactone. From the consideration of electronic and steric effects a mechanismic path of the reaction via a carbanion intermediate was proposed for the reaction. Preparation of related derivatives are also described.

• Bulletin of the Korean Chemical Society
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• v.34 no.1
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• pp.243-245
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• 2013

Rate equations are exactly solved for the reversible consecutive reaction of the first-order and the time-dependence of concentrations is analytically determined for species in the reaction. With the assumption of pseudo first-order reaction, the calculation applies and determines the concentration of product accurately and explicitly as a function of time in the unimolecular decomposition of Lindemann and in the enzyme catalysis of Michaelis-Menten whose rate laws have been approximated in terms of reactant concentrations by the steady-state approximation.