• Title/Summary/Keyword: Chemical Products

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Studies on the Amino Acid Composition of Korean Fermented Soybean Meju Products and the Evaluation of the Protein Quality (장류제품의 아미노산 조성과 그 단백질 품질평가에 관한 연구)

  • Lee, Cherl-Ho
    • Korean Journal of Food Science and Technology
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    • v.5 no.4
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    • pp.210-214
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    • 1973
  • This study analyses and compares the amino acid composition and available lysine content between Korean fermented soybean Meju and its products as well as home-made and commercially made products. The protein quality of the products was evaluated by the result, and the biological value of the proteins was estimated by using the regression equation for chemical score to biological value as calculated by B.O. Eggum. The amino-N content of soybean is found to be 85% of the total nitrogen content and is reduced to approximately 75% in the fermented products except home-made soysauce, where as the content of ammonia-N and other N-compounds is increased. The difference in protein quality between home-made and commercially made products is not found to be significant. The protein quality of soybean is not damaged greatly in the making of Meju but is seriously damaged during the long periods of ripening. After the ripening the chemical score of the products' protein is reduced to approximately one half of the original soybean protein and the available lysine content to $1/3{\sim}1/2$.

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Improving Feed Value of Agricultural By-Products (농산부산물(農産副産物)의 사료화(飼料化))

  • Kang, Tae-Hong
    • Applied Biological Chemistry
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    • v.27
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    • pp.18-28
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    • 1984
  • In order to improve feed values of Korean agricultural by-products, various treatments including physical, chemical, physicochemical and fermentation were suggested in th is review article. Physical treatments such as chopping, grinding and pelleting reduce partiole size of agricultural by-products, and increase passage rate from the rumen, thus may increase voluntary feed intake and weight gain. Digestibility and voluntary feed intake of straw, rice hull and sawdust, also, may be increased by chemical treatment using sodium hydroxide or ammonia. Especially, because nitrogen content of by-products increase and toxic problem is not posed by ammonia treatment, it's practical usage is recommended in Korea. Silage or fermentation treatment using principles of microbial fermentation may improve palatability of low quality by-products. As mentioned above, it is concluded that various treatments suggested are desirable and improve feed value but may raise several problems. Unfortunately, because cost for installation and products is great and processing work is complicate, farmers are not using well these processing methods until now. Therefore, in order to increase the practical usage at farm level, it is thought that many research works be achieved for efficient process which have simple operation and low installation cost.

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Gaseous by-products from the TiO2 Photocatalytic Oxidation of Benzene

  • Han, Sang-Wook;Lee, Jin-Hong;Kim, Jin-Seog;Oh, Sang-Hyub;Park, Young-Kwon;Kim, Hyun-Ook
    • Environmental Engineering Research
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    • v.13 no.1
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    • pp.14-18
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    • 2008
  • Photocatalytic oxidations of benzene gas using the closed system (batch reactor) were induced to determine its by-products and investigate the effect of humidity and oxygen concentration on their generation. The study was able to identify 11 gaseous by-products: 2-methylpropene, acetaldehyde, acetone, pentane, methylcyclobutane, methylcyclopentane, cyclohexane, 2,3-dimethylbutane, 2-methylpentane, 3-methylpentane, and hexane. All the by-products were saturated hydrocarbons, which are less toxic than benzene and were probably formed through hydrogenation reaction on the photocatalytic surface. The photocatalytic oxidation of benzene under higher humidity produced less by-products. However, the amount of acetone released increased with higher humidity and oxygen concentration.

Mild Isomerative Opening of Tetrahydrofuranyl Subunits in Steroids Using TFAT (trifluoroacetyl trifluoromethanesulfonate): Application to Synthesis of C17-OH Rockogenin Acetate

  • Lee, Jong-Seok;Kim, Byung-Sook;Shin, Jun-Ho;Lee, Yeon-Ju;Shin, Hee-Jae;Lee, Hyi-Seung
    • Bulletin of the Korean Chemical Society
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    • v.33 no.1
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    • pp.76-82
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    • 2012
  • A novel and efficient tetrahydrofuranyl ring opening method was developed using the highly reactive TFAT reagent in the presence of an acid scavenger, 2,6-di-tert-butyl-4-methylpyridine. Various acid sensitive groups are compatible with the reaction condition, making it generally applicable to many tetrahydrofuranyl steroids. Moreover, it is a synthetic equivalent of 'Marker degradation' affording an efficient synthesis of C17-OH rockogenin acetate.

Influence of the Structural Characteristics of Amino Acids on Direct Methylation Behaviors by TMAH in Pyrolysis

  • Choi, Sung-Seen;Ko, Ji-Eun
    • Bulletin of the Korean Chemical Society
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    • v.30 no.11
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    • pp.2542-2548
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    • 2009
  • Direct methylation behaviors of 20 amino acids with tetramethylammonium hydroxide (TMAH) were studied under diluted conditions with silica. Amino acid concentration was controlled by dilution with silica ($SiO_2$) and the molar ratios of amino acid/silica were 0.20, 0.50, and 2.0. The molar ratios of amino acid/TMAH (0.51 - 4.64) also varied. It was found that arginine, asparagine, aspartic acid, cysteine, glutamic acid, and glutamine did not generate any directly methylated pyrolysis products, whereas alanine, glycine, isoleucine, leucine, methionine, phenylanaline, valine, and proline generated all the directly methylated pyrolysis products. Tri- and tetra methylated products of lysine consisted of two types. Histidine and threonine hardly generated the partly methylated products. Mono- and dimethylated products of serine, tryptophan, and tyrosine were not observed. Relative intensities of the methylated products varied with the amino acid concentration, TMAH concentration, and pyrolysis temperature. Direct methylation behaviors of amino acids were explained by the structural characteristics of amino acids.

Chemical Recycling of Rigid and Flexible Polyurethanes as Raw Materials

  • Lee, Dai-Soo
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.212-212
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    • 2006
  • Polyurethane wastes can be depolymerized with glycols and/or amines. The depolymerization products may be recycled for the preparation of various polyurethanes. Caprolactam was employed to depolymerize Spandex fibers and the depolymerization products were evaluated as raw materials for the preparation of polyurethane elastomers. The depolymerization products were homogeneous and could be used to prepare polyurethane elastomers acceptable for various applications as binders.

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