• Clean Technology
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• v.11 no.3
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• pp.147-152
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• 2005

For estblishing the best technique for the micronization of Ibuprofen using supercritical fluids, the solubility should be known. The solubility of Ibuprofen in supercritical carbon dioxide was measured by observing the cloud point. The cloud point was observed using high pressure equipment equipped a variable volume view cell between temperature of 35, 40 and $45^{\circ}C$. The solubility data was correlated by the Peng-Robinson equation of state Solute physical properties, such as critical temperature (Tc), critical pressure (Pc) and acentric factor (${\omega}$) were estimated by the some group contribution method. As pressure was increased, the solubility increased at constant temperature. The retrograde phenomenon by a solute vapor pressure and a density of solvent was observed at the pressure of around 150bar. It was found that $CO_2$ can be used as a supercritical solvent in micronization of ibuprofen by RESS.

• Journal of Korean Society of Water and Wastewater
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• v.29 no.1
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• pp.133-138
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• 2015

Pressure retarded osmosis (PRO) process is one of membrane processes for harvesting renewable energy by using salinity difference between feed and draw solutions. Power is generated by permeation flux multiplied by hydraulic pressure in draw side. Membrane fouling phenomena in PRO process is presumed to be less sever, but it is inevitable. Membrane fouling in PRO process decreases water permeation through membrane, resulting in significant power production decline. This study intended to investigate the effect of hydraulic pressure in PRO process on alginate induced organic fouling as high and low hydraulic pressures (6.5 bar and 12 bar) were applied for 24 h under the same initial water flux. In addition, organic fouling in draw side from the presence of foulant (sodium alginate) in draw solution was examined. As major results, hydraulic pressure was found to be not a significant factor affecting in PRO organic fouling as long as the same initial water flux is maintained, inidicating that operating PRO process with high hydraulic pressure for efficient energy harvesting will not cause severe organic fouling. In addition, flux decline was negligible from the presence of organic foulant in draw side.

• Clean Technology
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• v.11 no.4
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• pp.165-170
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• 2005

The aim of this study is to provide vapor-liquid equilibrium (VLE) information for the study of process which directly synthesize dimethyl carbonate (DMC) from $CO_2$. For this study we collected some necessary VLE systems data of Methanol-Water, Methanol-DMC, $CO_2$-DMC, $CO_2$-Methanol, $CO_2$-Methanol, and performed VLE calculation with Peng-Robinson equation of state, Wong-Sandler mixing rules that widely used in chemical industry. These calculation results relatively agreed with VLE data well. Optimized Parameters of EoS given through this calculation will be used as some valuable information for fundamental study, process development and process optimization of DMC direct synthesis.

• 제어로봇시스템학회:학술대회논문집
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• 2002.10a
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• pp.46.3-46
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• 2002

Most of the process control algorithms in practice are based on the finite dimensional control theory. However, many chemical processes are described by partial differential equations (PDE's) and are infinite dimensional in nature due to spatial variation. Especially when the convection is dominant and thus diffusion can be ignored, chemical processes that are described by a system of first order hyperbolic PDE's. Such processes include tubular reactors, fixed bed reactors and pressure swinging adsorption. Conventionally such infinite dimensional systems described by PDE's are controlled by finite dimensional controllers that are designed through finite dimensional reduction of the process m...

• Clean Technology
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• v.11 no.3
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• pp.141-146
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• 2005

The composite membranes were made by grafting using supercritical carbon dioxide (scCO2) impregnation and polymerization procedures. The membranes were synthesized by changing amount of monomer. The polypropylene grafted polystyrene sulfonic acid (PP-g-pssa) membranes were characterized with various methods. The morphology and structure of PP-g-pssa membranes were analyzed with scanning electron microscopy (SEM) and energy dispersive spectrometer (EDS). As amount of monomer was increased, ion conductivity, cell performance was increased and methanol permeability was decreased. However PP-g-pssa membranes with 1.5g monomer and over had similar values of methanol permeability, ion conductivity and cell performance.

• 제어로봇시스템학회:학술대회논문집
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• 1996.10a
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• pp.18-18
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• 1996

This paper reviews some of the most prominent and promising areas of chemical process control both in relations to batch and continuous processes. These areas include the modeling, optimization, control and monitoring of chemical processes and entire plants. Most of these areas explicitly utilize a model of the process. For this purpose the types of models used are examined in some detail. These types of models are categorized in knowledge-driven and datadriven classes. In the areas of modeling and optimization, attention is paid to batch reactors using the Tendency Modeling approach. These Tendency models consist of data- and knowledge-driven components and are often called Gray or Hybrid models. In the case of continuous processes, emphasis is placed in the closed-loop identification of a state space model and their use in Model Predictive Control nonlinear processes, such as the Fluidized Catalytic Cracking process. The effective monitoring of multivariate process is examined through the use of statistical charts obtained by the use of Principal Component Analysis (PMC). Static and dynamic charts account for the cross and auto-correlation of the substantial number of variables measured on-line. Centralized and de-centralized chart also aim in isolating the source of process disturbances so that they can be eliminated. Even though significant progress has been made during the last decade, the challenges for the next ten years are substantial. Present progress is strongly influenced by the economical benefits industry is deriving from the use of these advanced techniques. Future progress will be further catalyzed from the harmonious collaboration of University and Industrial researchers.

• 제어로봇시스템학회:학술대회논문집
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• 2004.08a
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• pp.945-949
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• 2004

These days there are so many scheduling systems or softwares. But only few scheduling systems have succeeded in the market. In spite of powerful engine and functions, those systems have difficulties to be applied in real processes. In real processes, there are various constraints caused by physical or systematical environments of plants. Those constraints are too many to be handled in the system. This problem makes it difficult for the system to represent the details of processes. In order to resolve this problem, we have developed a specialized scheduling system for a target process. The system could be developed by the experts for target process and researchers for scheduling. In this study, a scheduling system for PVC process has been developed as an MILP (Mixed integer linear programming) model and coded in $Fortran^{TM}$. The scheduling system has been applied to two processes, which have different characteristics. Simulation results indicate that the profit of the target process can be increased by about 5% by implementing the scheduling system.

• Korean Chemical Engineering Research
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• v.45 no.6
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• pp.536-546
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• 2007

The nanoparticles have several interesting properties which cannot be shown in their bulk materials because of their high ratio of surface area to volume. They can be used to manufacture the nanostructured materials, the industrial materials, or the catalyst materials etc.. We can prepare nanoparticles of various sizes with high degree of monodispersity by gas phase processes and those particles can be used as raw materials for various advanced functional materials. In this paper, we introduced the aerosol reactors to synthesize nanoparticles by gas phase processes and also analyzed several features of those aerosol reactors and tried to introduce the recent interesting studies on nanoparticle synthesis by gas phase processes.

• Journal of the Korean institute of surface engineering
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• v.50 no.5
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• pp.332-338
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• 2017

In this study, we evaluated tendency and degree of corrosion damages of Inconel 600 after chemical decontamination treatments under three different conditions. In the decontamination processes, the oxidation and reduction were performed as one cycle. Each process was continued up to 5 cycles. Characteristics of corrosion under decontamination processes were evaluated by Tafel analysis and weight loss. Characteristics of surface damage were observed by scanning electron microscope(SEM) and three-dimensional(3D) microscope. As the cycle proceeded, weight loss and corrosion current density increased. Intergranular corrosion damage occurred on the surface of the materials. The result revealed that the surface of Inconel 600 was attacked by the strong acid solution under all chemical decontamination processes, but the degree of the corrosion damage was different depending on the processes.

• Korea-Australia Rheology Journal
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• v.11 no.3
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• pp.233-240
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• 1999

In order to understand the flow behavior of Electrorheological (ER) fluid, dynamic simulation has been intensively performed for the last decade. When the shear flow is applied, it is easy to carry out the simulation with relatively small number of particles because of the periodic boundary condition. For the squeezing flow, however, it is not easy to apply the periodic boundary condition, and the number of particles needs to be increased to simulate the ER system more realistically. For this reason, the simulation of ER fluid under squeezing flow has been mostly performed with some representative chains or with the approximation that severely restricts the flow geometry to reduce the computational load. In this study, Message Passing Interface (MPI), which is one of the most widely-used parallel processing techniques, has been employed in a dynamic simulation of ER fluid under squeezing flow. As the number of particles used in the simulation could be increased significantly, full domain between the electrodes has been covered. The numerical treatment or the approximation used to reduce the computational load has been evaluated for its validity, and was found to be quite effective. As the number of particles is increased, the fluctuation of the normal stress becomes diminished and the prediction in general was found to be qualitatively In good agreement with the experimental results.