• 한국연소학회:학술대회논문집
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• 한국연소학회 2001년도 제22회 KOSCI SYMPOSIUM 논문집
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• pp.90-98
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• 2001

Characteristics of high temperature rocket nozzle flow is discussed along with the aspects of computational analysis. Three methods of nozzle flow analysis, frozen-equilibrium, shifting-equilibrium and non-equilibrium approaches, were discussed, those were coupled with the methods of computational fluid dynamics code. A chemical equilibrium code developed for the analysis of general hydrocarbon fuel was coupled with three approaches of nozzle flow analysis. The approaches were used for the performance prediction of KSR-III Rocket, and compared with the theoretical results from NASA CEA (Chemical Equilibrium with Applications) code.

• 한국수소및신에너지학회논문집
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• 제17권4호
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• pp.440-447
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• 2006

Solid polymer electrolyte(SPE) membrane with electrodes embedded on both faces offer unique possibilities for the electrochemical cells like water electrolyzer with fuel cell. The Nafion 117 membrane was used as the SPE, and $Pt(NH_3)_4Cl_2$ and $NaBH_4$ as the electrocatalysts and reducing agent, respectively. The 'impregnation-reduction(I-R) method' has been investigated as a tool for the preparation of electrocatalysts for water electrolyzer by varying the concentration of reducing agent and reduction time at fixed concentration of platinum salt, 5 mmol/L. Pt-SPE electrocatalysts prepared by non-equilibrium I-R method showed the lowest cell voltage of 2.17 V at reduction time, 90 min and with concentration of reducing agent 0.8 mol/L and the cell voltage with those by equilibrium I-R method was 2.42 V at reduction time, 60 min and with concentration of reducing agent 0.8 mol/L. The cell voltage were obtained at a current density $1\;A/cm^2$ and $80^{\circ}C$. In water electrolysis, hydrogen production efficiency by Pt-SPE electrocatalyst is 68.2% in case of non-equilibrium I-R method and 61.2% at equilibrium I-R method.

• 한국항공우주학회지
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• 제31권1호
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• pp.85-96
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• 2003

로켓 엔진 노즐의 설계에서 동결 유동 해법과 동일한 수치적 특성을 가지는 화학 평형 해석은 노즐의 열역학적 최대 성능을 예측하는 효율적인 설계 도구로 이용될 수 있다. 본 연구에서는 탄화수소 연료 로켓 엔진 설계를 위한 화학적 평형 유동 해석 코드를 개발하였다. 로켓 노즐을 통한 팽창과정에서 일어나는 화학 성분의 재결합 효과와 이에 수반하는 에너지 회복과 같은 열화학적 특징을 이해하기 위하여, KSR-III 로켓 노즐에 대하여 동결유동 해석 및 비평형 유동의 해석과 더불어 화학적 평형 유동 해석을 수행하였다. 유동 해석 결과에 기초한 KSR-III 엔진 성능 평가로부터 노즐에서의 열화학적 특징을 이해할 수 있었으며, 이와 더불어 열화학적인 효과를 고려할 때 출구 면적비를 줄여서 수정된 새로운 노즐 형상이 지상 추력을 증대시키기 위한 적절한 설계임을 확인할 수 있었다.

• 대한화학회지
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• 제53권2호
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• pp.99-110
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• 2009

본 총설에서는 유리 전이에 관계되는 상태인 과냉각 액체와 유리의 특성, 그리고 유리 전이 관련 이론에 살펴보았다. 이 상태들은 비평형 상태로, 유리 전이는 일반적인 상전이와는 다르다. 유리와 관련 실 험 방법에 관하여 간략히 요약하였다.

• 한국항공우주학회지
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• 제34권7호
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• pp.89-96
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• 2006

액체 로켓의 가스발생기의 연소 온도는 터빈 깃의 열 손상을 방지하기 위하여 1,000K 이하로 유지되며 이를 위하여 농후 연소 또는 산화제 과다 연소를 유지한다. 이러한 이유로 연소는 비평형 화학반응이 주로 발생하며 연소반응을 예측하기가 매우 어렵다. 한편 케로신은 여러 가지 탄화수소 연료로 이루어진 혼합연료로 화학반응 메커니즘에 대한 모델이 매우 어려운 실정이다. 본 연구에서는 Dagaut가 개발한 207 화학종, 1592 화학반응 단계를 이용하였으며 완전혼합반응기 연소모델을 적용하여 계산하였다. 계산결과와 실험결과를 비교하여 보면 사용된 화학반응 기구가 검댕 예측을 하지 않고 있음에도 불구하고 계산 결과는 연소가스 온도 뿐 아니라 가스 물성치 등을 매우 잘 예측하고 있음을 확인하였다.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2008년 영문 학술대회
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• pp.448-451
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• 2008

Three methods of nozzle flow analysis, frozen-equilibrium, shifting-equilibrium and non-equilibrium approaches, were used to rocket nozzle flow, those were coupled with the methods of computational fluid dynamics code. For a design of high temperature rocket nozzle, chemical equilibrium analysis which shares the same numerical characteristics with frozen flow analysis can be an efficient design tool for predicting maximum thermodynamic performance of the nozzle. Frozen fluid analysis presents the minimum performance of the nozzle because of no consideration for the energy recovery. On the other hand, the case of chemical-equilibrium analysis is able to forecast the maximum performance of the nozzle due to consideration for the energy recovery that is produced for the fast reaction velocity compared with velocity of moving fluid. In this study, using the chemical equilibrium flow analysis code that is combined the modified frozen-equilibrium and the chemical-equilibrium. In order to understand the thermochemical characteristic components and the accompanying energy recovery, shifting-equilibrium flow analysis was carried out for the 30 $ton_f$-class KARI liquid rocket engine nozzle together with frozen flow. The performance evaluation based on the 30 $ton_f$-class KARI LRE nozzle flow analyses will provide an understanding of the thermochemical process in the nozzle and performances of nozzle.

• Bulletin of the Korean Chemical Society
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• 제25권2호
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• pp.321-324
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• 2004

• 한국분말재료학회지
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• 제10권5호
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• pp.305-309
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• 2003

We report on the formation and chemical leaching of non-equilibrium $Al_{0.6}(Fe_{75}Co_{25})$ alloy produced by rod milling. X-ray diffractometry, transmission electron microscopy, differential scanning calorimetry, scanning electron microscopy, and vibrating sample magnetometry were used to characterize the as-milled and leached specimens. After 400 h, only the $Al_{0.4}Fe_{0.6}$ peak of the body-centered cubic type was present in the XRD pattern. The entire rod milling process could be divided into three different stages of milling: agglomeration, disintegration, and homogenization. The saturation magnetization, $M_s$ decreased with increased milling time, the $M_s$ of the powders before milling was about 113.8 emu/g, the $M_s$ after milling for 400 h was about 11.55 emu/g. Leaching of the Al in KOH of the Al at room temperature from the as-milled powders did not induce any significant change in the diffraction pattern. After the leached specimen had been annealed at $600^{\circ}C$ for 1 hour, the nanoscale crystalline phases were transformed into the bcc Fe, cubic Co, and $CoFe_2O_4$ phases. On cooling the specimen from 85$0^{\circ}C$, the degree of magnetization increased slightly, then increased sharply at approximately 364.8$^{\circ}C$, indicating that the bcc $Al_{0.4}Fe_{0.6}$ phase had been transformed to the Fe and Co phases.

• Bulletin of the Korean Chemical Society
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• 제12권3호
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• pp.315-322
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• 1991

In a recent $paper^1$ we reported equilibrium (EMD) and non-equilibrium (NEMD) molecular dynamics simulations of liquid argon using the Green-Kubo relations and NEMD algorithms to calculate the thermal transport coefficients-the self-diffusion coefficient, shear viscosity, and thermal conductivity. The overall agreement with experimental data is quite good. In this paper the same technique is applied to calculate the thermal transport coefficients of liquid water at 298.15 K and 1 atm using TIP4P model for the interaction between water molecules. The EMD results show difficulty to apply the Green-Kubo relations since the time-correlation functions of liquid water are oscillating and not decaying rapidly enough except the velocity auto-correlation function. The NEMD results are found to be within approximately ${\pm}$30-40% error bars, which makes it possible to apply the NEMD technique to other molecular liquids.

• 한국전산유체공학회:학술대회논문집
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• 한국전산유체공학회 2001년도 춘계 학술대회논문집
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• pp.144-148
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• 2001

Characteristics of high temperature rocket nozzle flow is discussed along with the aspects of computational analysis. Three methods of nozzle flow analysis, frozen-equilibrium, shifting-equilibrium and non-equilibrium approaches, were discussed those were coupled with the methods of computational fluid dynamics. A chemical equilibrium code developed for the analysis of general hydrocarbon fuel was coupled with three approaches of nozzle flow analysis, and a test was made for a bell nozzle at typical operation condition. As a results, the characteristics of the approaches were discussed in aspects of rocket performance, thermal analysis and computational efficiency.