• Title/Summary/Keyword: Chemical Composition test

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Effect of Diluted H2SO4 and NaOH Treatment on Chemical Composition of Larch and Yellow Poplar (황산 및 수산화나트륨처리가 낙엽송과 백합나무의 주요 화학조성에 미치는 영향)

  • Lee, Soo-Min;Lee, A-Ram;Ahn, Byoung Jun;Kim, Yong Sik;Yang, In;Cho, Sung Taig
    • Journal of the Korean Wood Science and Technology
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    • v.41 no.4
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    • pp.358-373
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    • 2013
  • In this study, both mild acid and alkali treatments with 1.0 wt% and 2.0 wt% of $H_2SO_4$ and NaOH solution were applied to evaluate the effects on chemical compositions of wood biomass. Yellow poplar (Liriodendron tulipifera L.) and larch (Larix kaempferi C.) were chosen due to major species planted in Korea. Chemical treatments of biomass were carried out by being soaked in either acid or alkali solution with 1:20 ratio for 72 hours at ambient temperature. Afterward, lignin, 5 major reduced sugars, ash contents and elemental composition were determined. To statistically understand the relationship between samples and chemical treatments, the Tukey test, simple linear regression model and ANOVA analysis were introduced using a statistical software R. As results from both wet chemistry and statistical analysis, yellow poplar was more affected on the lignin and xylose contents by acid treatments under these experimental conditions. Meanwhile, larch was more affected on the composition of galactose and lignin by alkali treatments. A series of results in this study would show that equivalent chemical treatment makes a change the chemical composition of each species.

Material Properties of 400MPa Grade Hot Rolled H-beam(SHN400) for Building Structure (400MPa급 건축구조용 열간압연 H형강(SHN400)의 소재 특성)

  • Kim, Hee-Dong;Choi, Byoung-Jeong;Kim, Sang-Sub;Kim, Chul-Hwan;Oh, Young-Suk
    • Journal of Korean Society of Steel Construction
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    • v.23 no.4
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    • pp.515-522
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    • 2011
  • The purpose of this study was to evaluate the material characteristics of SHN400 steel, which is suitable as a steel material for building structures, using the experimental approach. For this purpose, the chemical composition test, tensile test, macro test, micro test, and charpy notch impact test were conducted with specimens taken from the highest, thickest, and commonly used H-beams for girder or beam members. Each test was conducted under the Korean Standard(KS) test conditions. All the test results satisfied the requirements of KS (KS D 3866) and the steel material for seismic design. The carbon equivalent value (Ceq), which is related to weldability, and the yield ratio, which is related to inelastic behavior, showed especially good results. Thus, SHN400 is definitely suitable as the steel material for building structures.

High Temperature Oxidation Characteristics of the (Ti, Al)N Coating on the STS 304 by D.C. Magnetron Sputtering (D.C. Magnetron Sputter를 이용한 (Ti, Al)N 피막의 고온산화특성)

  • 최장현;이상래
    • Journal of the Korean institute of surface engineering
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    • v.25 no.5
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    • pp.235-252
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    • 1992
  • (Ti, Al)N films were deposited on 304 stainless steel sheet by D.C. magnetron sputtering using Al target and Ti plate. The high temperature oxidation of (T, Al)N films with the variation of composition has been investigated. The chemical composition of (Ti, Al)N films with the variation of composition has been investigated. The chemical composition of (Ti, Al)N films was similar to the sputter area ratio of titanium to aluminum target by means of EDS and AES survey. The high temperature oxidation test of (Ti, Al)N showed that (Ti, Al)N has better high temperature resistance than TiN and TiC films. TiC films were cracked at 40$0^{\circ}C$ in air TiN films quickly were oxidised at $600^{\circ}C$, were spalled more than $700^{\circ}C$. But (Ti, Al)N films are relatively stable to$ 900^{\circ}C$. The good resistance to high temperature oxida-tion of (Ti, Al)N films are due to the formation of dense Al2O3 and TiO2 oxide layer. Especially, Al2O3 oxide layer is more important. The results obtained from this study show, it is believe that the (Ti, Al)N film by D.C. magnetron sputtering is promising for the use of high temperature and wear resistance mate-rials.

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A Study on Test Methods for Performance Appraisal of Root Barrier Appling to Green Roofs (옥상 및 인공지반녹화용 방근재의 성능기준 설정을 위한 방근성 시험방법에 관한 연구)

  • Oh, Sang-Keun;Kwak, Kyu-Sung;Sun, Yoon-Suk;Kwon, Shi-Won
    • Journal of the Korea Institute of Building Construction
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    • v.7 no.1 s.23
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    • pp.79-84
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    • 2007
  • Selection of proper root barrier as destination part of greening is very important in Root penetration resistance plan. To select proper root barrier, it need to understand composition of greening part, size, kind of plant, connection with waterproofing layer. In this point of view, we have establish greening on the roof or concrete structure, not been understand the structural mechanism. It means that we misunderstood about purpose of greening and using it. So, chosen materials and construction method was not proper for greening, it caused water leakage and decrease performance of concrete structure. Therefore, we would suggest 5 items of test methods considering environmental condition for green roof. Watertightness by water of greening part, root penetration resistance test by root penetration, bacteria resistance by must or bacteria in soil, chemical resistance by rain and chemical agent of fertilizer, and load resistance by soil depth, size of plant. These suggested test methods could be referred as guideline to test in green roof system because of not exist any performance appraisal guideline or standard. Consequently, it should be analysis as technical and institutional subdividing test methods and it need to study constantly as varied angles.

Effect of Fineness Modulus of Reactive Aggregate on Alkali Silica Reaction

  • Jun, Ssang-Sun;Jin, Chi-Sub
    • International Journal of Concrete Structures and Materials
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    • v.4 no.2
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    • pp.119-125
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    • 2010
  • In this study, the effects of the fineness modulus of reactive aggregate on ASR expansion and ASR products have been investigated. The reactive aggregate used was metamorphic aggregate originated from Korea. ASR tests were conducted according to accelerated mortar bar test. The morphology and chemical composition of products formed in mortar bars, 5 years after the mortar bar test had been performed, were studied by scanning electron microscopy equipped with energy dispersive spectroscopy. Test results indicated that ASR expansion of mortar bars decrease in linear proportion to the fineness modulus of reactive aggregate. SEM images indicated that mortar bars showed reactive products formed in cement paste, within air voids and within cracks through particles except for the mortar bar with the fineness modulus of 3.25. The EDS analysis of the reactive products showed presence of silica, calcium and sodium, typical of ASR product composition.

Physico-Chemical Characteristics Evaluation of White Pork Rind and Black Pork Rind (백돈피와 흑돈피의 이화학적 품질특성 평가)

  • Jeon, Ki-Hong;Hwang, Yoon-Seon;Kim, Young-Boong;Choi, Yun-Sang;Kim, Byoung-Mok;Kim, Dong-Wook;Jang, Aera
    • The Korean Journal of Food And Nutrition
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    • v.28 no.4
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    • pp.544-550
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    • 2015
  • In order to determine the material characteristics of pork rinds according to the breeds, the chemical composition, color, pH, collagen contents, shear force, fatty acid and amino acid contents of pork rinds were investigated. White pork rinds (WPR) and black pork rinds (BPR) were evaluated before and after heating to compare the differences between breeds and the effects of heating treatment. In the chemical composition test, the respective moisture contents for WPR and BPR before heating were 49.90% and 53.75% but increased to 60.75% and 61.09% after heating. The test for crude protein and crude fat contents showed lower values after heating but WPR was higher than BPR. In the color test, the L value decreased rapidly with heating, dropping from 68.75 to 45.11 in WPR and from 67.22 to 49.64 in BPR. WPR had a higher L value and a lower a value than BPR before heating but had a higher L value and a lower a value than WPR after heating. pH was significantly higher in WPR than BPR regardless of heating (p<0.05). The collagen content for WPR and BPR was 10.38 g/100 g and 11.54 g/100 g but increased to 12.00 g/100 g in WPR and decreased to 11.40 g/100 g in BPR after heating. The shear force of 26.14 kgf in WPR was significantly higher than 12.89 kgf in BPR before heating (p<0.05), but the values decreased significantly after heating in both WPR and BPR. Linoleic acid in WPR was 17.29%, which was higher than 15.13% in BPR. The USFA for BPR was also higher than WPR. In amino acid composition, the EAA contents in WPR was 7,190 mg%, which was higher than 5,520 mg% in BPR.

Pervaporation of TFEA/MA/Water Mixtures through PVA Composite Membranes

  • Ahn, Sang-Man;Kim, Jeong-Hoon;Lee, Yong-Taek;Lee, Soo-Bok
    • Proceedings of the Membrane Society of Korea Conference
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    • 2005.11a
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    • pp.133-147
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    • 2005
  • In order to investigate applicability for 2,2,2-trifluoroethyl methacrylate (TFEMA) produced by esterification of 2,2,2-trifluoroethanol(TFEA) and methacrylic acid(MA) using pervaporation membrane, poly(vinyl alcohol) (PVA) composite membranes were prepared with glutaraldehyde(GA) onto porous polyethersulfone(PES) support. The degree of crosslinking and thickness of PVA coating layer were analyzed by swelling test and SEM(scanning electron microscopy), respectively. Pervaporation test was done with two feed mixures; TFEA/water, MA/water. The pervaporation data were obtained as a function of content of crosslinking agent, feed composition, and operating temperature, respectively. In case of TFEA-water(90/10 wt%) feed mixture at $80^{\circ}C$, the optimized membrane showed the high permeation flux of 1.5 $kg/m^2hr$ and separation factor of 320. In case of MA-water(90/10 wt%) feed mixture, the membranealso showed high permeation flux of 2.3 $kg/m^2hr$ and separation factor of 740 in same conditions.

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A COMPARATIVE STUDY OF THE PHYSICOCHEMICAL PROPER TIES AND BOND STRENGTH TO METAL BETWEEN THE REGULAR OPAQUE POWDER AND CORE POWDER (도재소부전장금관용 Opaque 분말과 도재전장관용 core 분말의 물리화학적 성질 및 금속과의 결합력에 대한 비교연구)

  • Lim, Jang-Seop;Chung, Chang-Mo;Jeon, Young-Chan
    • The Journal of Korean Academy of Prosthodontics
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    • v.35 no.1
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    • pp.144-164
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    • 1997
  • The purpose of this study were to investigate the chemical composition, mean particle size, linear thermal expansion coefficient and metal-bonding strength of the regular opaque powder and core powder. In this study, 4 types of ceramic powders, namely Duceram Jacket Opaque powder, Duceram Opaque powder, Vita Hi-Ceram powder, Vita VMK Paint On-88 powder were used. Chemical composition was evaluated by EDS(Energy Dispersive X-ray Spectrophotometer, Oxford QX-2000, England), particle size was measured by MALVERN Instruments(MALVERN Instruments SB. OC., U.S.A.. ad linear thermal expansion coefficient was measured by dilatometer(Motoyama, Japan). Bond strength was measured by the Universal tsting machine(Istron Co., Ltd., U.S.A.). The Results were as follows : 1. Through recognition of the relative difference in chemical composition between the core powder and the regular opaque powder, the difference in the proportion of $Al_2O_3$ in each type of material is demonstrated ; Duceram Jaket Opaque powder : 30.16%, Duceram Opaque powder : 16.60%, Vita Hi-Ceram : 63.64%, Vita VMK Paint-On 88 : 16.16%. 2. There was no significant difference in the proportion of metal-bonding materials between the core powder and the regular opaque powder. 3. In the regular opaque powder, alkaline materials were incoporated in order to increase the coefficient of thermal expansion. 4. In the particle size analysis, there was no significant difference in mean particle size or in the particle size distribution between the core powder and the regular opaque powder. 5. In the thermal expansion test for temperature range of $25-600^{\circ}C$, the regular opaque powder had higher coefficient of thermal expansion than that of core powder. 6. In the 4 point flexural bending test, there was no statistically significant difference in the mean bond strength between the core powder and the opaque powder among the Duceram products.

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Evaluation of Applicability of Heavy Oil Upgrading By-Product (Pitch) as A Pavement Paving Material (중질유 고도정제 부산물의 도로포장용 역청재료로서의 적용성 평가)

  • Yang, Sung Lin
    • International Journal of Highway Engineering
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    • v.16 no.5
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    • pp.9-18
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    • 2014
  • PURPOSES : The objective of this study is to evaluate the applicability of the pitch, which is produced during SDA petroleum upgrading process, as a pavement paving material. In order for the purpose, the physical and chemical properties of the pitch are analyzed, and then the various plasticizers are applied in the pitch. METHODS : Two types of pitch are selected from oil refinery companies, which are owned the SDA petroleum upgrading process. Also, two types of asphalt binders, PG 64-22 and PG 58-22, are employed to compare with the pitch because these two types of asphalt binders are currently used as paving materials. For the chemical property of the pitch, the composition of SARA (Saturate, Aromatic, Resin, Asphaltene), the elementary composition, and the functional group are analyzed. For the physical property of the pitch, the basic material property tests, such as penetration test, softening point test, flash point test, ductility test, and rotational viscometer test, are performed. Also, the DSR (Dynamic Shear Rheometer) test and the BBR (Bending Beam Rheometer) test are conducted using asphalt binder specimens obtained by both short term aging (Rolling Thin Film Oven, RTFO) and long term aging (Pressure Aging Vessel, PAV) processes. The rheological property of each pitch type is evaluated as a function of temperatures and loading cycles. PG 64-22 asphalt binder is used as a control material. RESULTS AND CONCLUSIONS : The Pitch may not be suitable for the pavement paving material without modifications, but the pitch can be used as alternatives of modified addictive or asphalt. If low molecular component, such as saturate and aromatic components, are added in the pitch based on the development of various plasticizers, it has a strong possibility for the pitch to be used as a alternative. However, in order to verify the performance property of the pitch, further research is needed.

A Study for the Weldability and Welded Joint Performance on the SAW of HSA800 Steel (HSA800 강재의 SAW 용접성 및 이음성능 연구)

  • Choi, Young Han;Kim, Sang Seup
    • Journal of Korean Society of Steel Construction
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    • v.29 no.1
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    • pp.37-48
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    • 2017
  • In this research, 9 SAW welding specimens with 1 hour post-heat treatment (PH1) and 2 hours (PH2) were experimented to confirm the weldability and the joint performance of 60mm thickness HSA800 steel. SAW tests with PH1 & PH2, including weld impact test, bend test, hardness test, macroscopic test, and microscopic test, had a good test results. However, from the chemical composition test results, P composition was not satisfied with Korean Industrial Standards(KS). According to the weld-zone tensile tests, 2 hours post-heat SAW is recommended because the mechanical characteristics of SAW PH2 were better than those of SAW PH1.