• 한국세라믹학회지
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• 제37권5호
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• pp.466-472
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• 2000

As cathode materials of LiMn2O4-based lithium-ion secondary batteries, Li(Mn1-$\delta$M$\delta$)2O4 (M=Ni and Co, $\delta$=0, 0.05, 0.1 and 0.2) materials which Co and Ni are substituted for Mn, were syntehsized by the solid state reaction at 80$0^{\circ}C$ for 48 hours. No second phases were formed in Li(Mn1-$\delta$M$\delta$)2O4 system with substitution of Co. However, substitution of Ni caued to form a second phase of NiO when its composition exceeded over 0.2 of $\delta$ in Li(Mn1-$\delta$M$\delta$)2O4. As the results of charging-discharging test, the maximum capacity of Li(Mn1-$\delta$M$\delta$)2O4 appeared in $\delta$=0.1 for both Co and Ni. Also, Li(Mn1-$\delta$M$\delta$)2O4 electrode showed higher capacity and better cycle performance than LiMn2O4.

• 한국세라믹학회지
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• 제42권7호
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• pp.503-508
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• 2005

A simple and effective method for the synthesis of LiMn$_{2}$O$_{4}$ powder as a cathode material for lithium secondary battery is reported. Micrometer size LiMn$_{2}$O$_{4}$ was prepared by combustion synthesis technique employing initial mixture of l.l LiNO$_{3}$ -1.3Mn-0.7MnO$_{2}$-1NaCl composition. Parametric study of the combustion process including molar ratio of Mn/MnO$_{2}$ and NaCl concentration were carried out under air atmosphere. The combustion products obtained were additionally heat treated at the temperature 900$^{\circ}C$ and the washed by distilled water. The results of charging-discharging characteristics revealed that LiMn$_{2}$O$_{4}$ cell synthesized in the presence of NaCl had a high capacity and much better reversibility than one formed without NaCl An approximate chemical mechanism for LiMn$_{2}$O$_{4}$ formation is proposed.

• 전기학회논문지
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• 제62권1호
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• pp.21-28
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• 2013

The paper proposes an optimal sizing method of a customer's battery energy storage system (BESS) which aims at managing the electricity demand of the customer to minimize electricity cost under the time of use(TOU) pricing. Peak load limit of the customer and charging and discharging schedules of the BESS are optimized on annual basis to minimize annual electricity cost, which consists of peak load related basic cost and actual usage cost. The optimal scheduling is used to assess the maximum cost savings for all sets of candidate capacities of BESS. An optimal size of BESS is determined from the cost saving curves via capacity of BESS. Case study uses real data from an apartment-type factory customer and shows how the proposed method can be employed to optimally design the size of BESS for customer demand management.

• 한국표면공학회지
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• 제49권2호
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• pp.191-195
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• 2016

Among the lithium metal oxides for hybrid-capacity, $Li_4Ti_5O_{12}(LTO)$ is an emerging electrode material as zero-stain material in volume change during the with the charging and discharging processes. However, LTO has a limitation of low ionic and electronic conductivity. To enhance the ionic and electronic properties of $Li_4Ti_5O_{12}(LTO)$, we synthesized the spherical LTO/CNT composite by sol-gel process for hybrid capacitors. CNT interconnection networks between CNT-LTO particles enhanced electronic conductivity and electrochemical charging/discharging properties. All of the LTO samples was observed to show the spinel structure and spherical morphology with the diameter of $5{\sim}10{\mu}m$. Especially, spherical LTO/CNT composite of the CNT-3 wt% showed the enhanced capacity from 110 mAh/g to 140 mAh/g at 10 C.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1988년도 춘계학술대회 논문집
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• pp.60-62
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• 1988

In this study, the characteristic of charging current which flows into the polymer by applying the corona discharge carriers on the polymer surface was measured, so as to investigate the phenomenon of charge injection and movement if injected charge on polymer. Also. the characteristics of discharge current which flows by shorting both sides of corona charged polymers were measured. Experimental results are as follows; The amount of charges injected by corona discharge vary according to the state of surface and the type of carriers, and then the charging current varies according to the properties of injected carriers.

• 한국신뢰성학회지:신뢰성응용연구
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• 제17권1호
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• pp.66-71
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• 2017

Purpose: Polymer capacitors are known to have very high reliability as compared with liquid electrolytic capacitors, but their capacity has been reported to decrease in charge and discharge at low temperature. The purpose of this study to clarify these characteristics. Methods: In order to clarify these characteristics, charging-discharging tests were carried out for 200 hours with three different capacities and at 5 different temperature from $5^{\circ}C$ to $100^{\circ}C$. Results: As a result of the test, it was confirmed that the capacity of the polymer capacitor was decreased with higher capacity and lower temperature. Conclusion: Such a failure phenomenon was caused by the shrinkage and expansion characteristics of the polymer used therein, it is presumed that this failure phenomenon is due to the complex pore structure made by etching.

• 대한안전경영과학회지
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• 제4권4호
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• pp.137-146
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• 2002

In order to investigate the effect of irradiation by $^{60}Co-\gamma$rays as well as the e thermal treatment on the dielectric deterioration in ethylene propylene rubber, insulating material for electric cables used in atomic power plants, charging discharging current, residual built- up voltage and dielectric properties are measu discussed in this study. Variance in the characteristic of relative dielectric constant as a function of tem was observed in relatively high dose of irradiation. Since glass transition tem appeared at tens of degree Celsius below zero, the characteristic is attributed orientation polarization. Dielectric loss is generally increased, with increasing d irradiation in the characteristic of dielectric loss as a function of temperature, No d loss by thermal treatment was observed. Dielectric resistance decreases with increa of irradiation in the characteristic of charging current as a function of temperature be considered that dielectric resistance seems to be recovered by thermal treatm characteristic of discharging current as a function of time in the specimen less ir become similar to that of the unirradiated, when thermal treated. A peak is shown residual built- up voltage as a function of time, and the corresponding time of the shorten as increasing dose of irradiation. It is also observed that the corresponding the peak is lengthened by thermal treatment.

• 한국수소및신에너지학회논문집
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• 제5권2호
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• pp.81-90
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• 1994

The hydrogen fuel tanks having hydrogen storing capacity of about 300g and 1200g are manufactured using $MmNi_{4.7}Al_{0.25}V_{0.05}Fe_{0.001}$ alloy. They are composed of several unit reactor made of Cu-tube(outer diameter = 50.1mm, thickness = 2mm). In order to increase the heat and mass transfer property of the hydride bed, Al-plates are inserted perpendicular to axial direction at intervals of 5mm and three arteries of diameter 8mm are installed symmetrically in each unit reactor. Hydrogen absorption is proceeded about 80% within 30 minute and is completed within 60 minute at the conditions of charging hydrogen pressure of 25atm and temperature of $22^{\circ}C$. On desorbing hydrogen at a constant rate of 30 slm at $20^{\circ}C$, discharging hydrogen pressure is sustained at 3~5atm for 120 minutes. The discharging pressure is increased upto 5~8atm as the increase of the reactor temperature to $30^{\circ}C$. From the experimental results and the brief discussions about the hydrogen absorption and disorption behaviors of the hydrogen storage tank, it is suggested that the behaviors of hydrogen charging and discharging could be controlled by adjusting the operating parameters and the reactor design parameters.

• 전력전자학회논문지
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• 제24권2호
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• pp.134-137
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• 2019

A wide-bandwidth current controller is required for fast charging/discharging of super capacitor applications. Peak current mode is generally used to accomplish fast charging/discharging because this mode has fast response characteristics. However, the peak current mode control must have a slope compensation function to restrain sub-harmonics oscillation. The slope must be changed accordingly if the controlled output voltage is varied. However, changing the slope for every changed output voltage is not easy. The other solution, selecting the slope as the maximum value, causes a slow response problem to occur. Therefore, we propose a hybrid mode controller that uses a peak current and a newly specified valley current. Through the proposed hybrid mode control, the sub-harmonic oscillation does not occur when the duty is larger than 0.5 because of the fast response.

• 해양환경안전학회지
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• 제18권2호
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• pp.161-165
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• 2012

충전과 방전이 빈번히 발생하는 축전지의 사용수명을 늘리고 안정적인 사용을 위해서는 과 방전을 방지하는 것이 가장 중요한 요인중 하나이다. 축전지의 건강상태를 파악하는 방법에는 여러 가지로 연구가 진행되고 있으며, 그 중에서도 본 논문에서는 가장 간단하게 축전지의 상태를 파악할 수 있는 단자전압을 이용하는 방법을 활용하여 축전지의 잔존용량을 파악하였다. 일정 전압 이하로 축전지의 전압이 떨어지지 못하도록 간단하게 비교기를 이용하여 과 방전이 되지 못하도록 설계 제작하였다. 상수도 시설이 없는 장소의 저수조탱크의 물 소독을 목적으로 제작된 태양광발전을 응용한 소독약 자동 주입장치의 축전지에 설계한 회로를 제작 설치하여 그 동작실험을 하고 그 유용함을 확인하였다.