• Bulletin of the Korean Chemical Society
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• 제20권10호
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• pp.1181-1185
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• 1999

The reaction of FeC5H5+ ion with ferrocene molecule is investigated using FT-ICR mass spectrometry. FeC5H5+ ions are generated by dissociative ionization of ferrocenes using an electron beam. The reaction gives rise to the formation of the adduct ion, Fe2(C5H5)3+, in competition with charge transfer reaction leading to the formation of ferrocene molecular ion, Fe(C5H5)2+·. The branching ratio of the adduct ion increases as the internal energy of the reactant ion decreases and correspondingly the branching ratio for the charge transfer reaction product decreases. The observed rate of the addition reaction channel is slower than that of the charge transfer reaction. The observation of the stable adduct ions in the low-pressure ICR cell is attributed to the radiative cooling of the activated ion-molecule complex. The mechanism of the reaction is presented to account for the observed experimental results.

• Journal of Advanced Marine Engineering and Technology
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• 제37권6호
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• pp.575-581
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• 2013

본 논문은 R744-R404A 캐스케이드 냉동시스템의 최적 냉매 충전을 위해 과냉도, 과열도, 내부열교환기 효율 등에 대한 영향을 분석한 것이다. 연구에 사용된 캐스케이드 냉동시스템의 고온 사이클에는 R404A, 저온 사이클에는 R744를 적용하였다. 그 주요 결과는 다음과 같다 : 고온 사이클의 과냉도, 과열도, 내부열교환기 효율과 저온 사이클의 증발온도와 압축효율은 크게 할수록 질량유량비가 작게 나타났다. 그리고 캐스케이드 온도차와 고온 사이클의 증발온도, 응축온도와 저온 사이클의 과냉도, 과열도, 내부열교환기 효율은 작을수록 질량유량비가 작게 나타났음을 확인하였다.

• 한국자동차공학회논문집
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• 제11권3호
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• pp.48-57
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• 2003

A cylindrical constant volume combustion chamber was used to investigate the flow characteristics at spark plug and the combustion characteristics of homogeneous charge methane-air mixture under various initial pressure, excess air ratio and ignition times in quiescent mixture. The flow characteristics such as mean velocity and turbulence intensity was analyzed by hot wire anemometer. Combustion pressure development measured by piezoelectric pressure transducer and flame propagation acquired by ICCD camera were used to investigate the effect of initial pressure, excess air ratio and ignition times on pressure, combustion duration, flame speed and burning velocity. Mean velocity and turbulence intensity had the maximum value at 200 or 300ms and then decreased to near 0 value gradually after 3 seconds. Combustion duration, flame speed and burning velocity were observed to be promoted with excess air ratio of 1.1, lower initial pressure and ignition time of 300ms.

• International Journal of Aeronautical and Space Sciences
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• 제15권1호
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• pp.82-90
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• 2014

In this paper, the effect of Lorentz force on the stability of attitude orientation of a charged spacecraft moving in an elliptic orbit in the geomagnetic field is considered. Euler equations are used to derive the equations of attitude motion of a charged spacecraft. The equilibrium positions and its stability are investigated separately in the pitch, roll and yaw directions. In each direction, we use the Lorentz force to identify an attitude stabilization parameter. The analytical methods confirm that we can use the Lorentz force as a stabilization method. The charge-to-mass ratio is the main key of control, in addition to the components of the radius vector of the charged center of the spacecraft, relative to the center of mass of the spacecraft. The numerical results determine stable and unstable equilibrium positions. Therefore, in order to generate optimum charge, which may stabilize the attitude motion of a spacecraft, the amount of charge on the surface of spacecraft will need to be monitored for passive control.

• 대한전기학회논문지:전기물성ㆍ응용부문C
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• 제50권8호
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• pp.419-422
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• 2001

This paper presents the principle and fabrication of a novel micro mass spectrometer and emission test of hot electron for ionization. A micro mass spectrometer consists of a micro ion source and a micro ion separator. The micro ion source consists of a hot filament and grid electrodes. Electrons emitted from a hot filament are to ionize some sample molecules. The ions are accelerated to an ion detector by an electric field. Mass can be analyzed by using the time of fight depending on the mass-to-charge ratio. The current of hot electron emission from the hot filament is measured for various input voltages.

• 한국수소및신에너지학회논문집
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• 제12권3호
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• pp.231-238
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• 2001

Electrocatalytic activity of palladium for hydrogen oxidation and reduction was studied using AC impedance method. The system under study was arranged in electrolytic mode consisting of Pd electrode under study, Pt counter electrode and Nafion electrolyte between them. Two types of Pd electrodes were used - carbon-supported Pd (Pd/C) and Pd foil electrode. Pd/C anode contacting pure hydrogen showed a steady decrease of charge transfer resistance with the increase of anodic overpotential, which is an opposite trend to that found with Pd foil anode. But Pd foil cathode also exhibited a decrease of the resistance with the increase of cathodic overpotential. The relationship between imposition of overpotential and subsequent change of the charge transfer resistance is determined by the ratio of the rate of faradaic process to the rate of mass transportation; if mass transfer limitation holds, increase of overpotential accompanies the increase of charge transfer resistance. Regardless of the physical type of Pd electrode, the anode contacting hydrogen/oxygen gas mixture did not reveal any independent arc originated from local anodic oxygen reduction.

• Applied Biological Chemistry
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• 제35권6호
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• pp.449-456
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• 1992

인산처리가 근류의 bacteroid 함량과 energy 상태에 미치는 영향을 살펴보기 위하여 Bradyrhizobium japonicum MN10을 접종한 대두식물(Glycine max [L.] Merr.)에 저해농도(0.05 mM-P)와 정상농도(1.0 mM-P)를 처리하여 온실에서 재배하였다. 인산결핍은 식물체의 근류량과 근류량 식물체량의 비에 유의성있는 감소를 보였다. 잎, 줄기, 뿌리의 인산농도는 인산결핍에 의하여 75%가 감소하였으나 근류의 인산농도는 40%만 감소하였다. 근류의 bacteroid 함량과 근류에서 전인산, 전질소의 bacteroid와 식물세포로의 분배는 인산결핍의 영향을 받지 않았으며 전질소의 22%, 전인산의 27%가 bacteroid에 존재하였다. 근류의 ATP농도, 전 adenylate 농도와 energy charge는 인산결핍에 의하여 각각 77%, 46%, 37%가 감소되었다. 인산결핍은 근류내 식물세포의 ATP 농도와 energy charge를 각각 86%, 59%를 감소시켰으나 bacteroid의 ATP농도와 energy charge에는 영향을 미치지 않았다. 이러한 결과는 근류가 인산의 강한 보유원이며, 기주식물에 대한 인산결핍조건하에서 bacteroid는 정상적인 인산 농도와 energy양을 함유한다는 것을 나타낸다.

• Journal of Astronomy and Space Sciences
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• 제34권1호
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• pp.31-35
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• 2017

Optical observation is one of the most common techniques used for characterizing the physical properties of unknown objects and debris in space. This research presents measurements and properties of the new object 96019 from ground-based optical methods. Optical observations of this small object were performed using a charge-coupled device (CCD) camera and the Santel-500 telescope at the Zvenigorod Observatory. The orbital elements and physical properties of this object, such as area-to-mass ratio, have been determined. The results show that this small object has a low area-to-mass ratio, between 0.009 and $0.12m^2/kg$. The light curve of object 96019 is given: Over the time intervals, variations in brightness are analyzed and the maximum brightness was found to be 12.4 magnitudes. The observational results show that, this object brightens by about three magnitudes over a time span of three minutes. Based on these observations, the characteristics and physical properties of this object are discussed.

• 한국전기전자재료학회논문지
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• 제22권2호
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• pp.169-173
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• 2009

We studied driving characteristics according to the ratio of mass and charging (m/q) value for charged toner particles with black and yellow color in charged particle type display panel. After biasing rectangle pulse to the transparency electrodes of putted panel with toner particles, its response time and contrast ratio are simultaneously measured using a laser as a optical source, photodiode as a detector and reflective system. As a results, contrast ratio is largest at the shortest response time region which is different to the particle because of m/q. We proposed relational equation for response time, m/q, cell gap and biasing voltage. It has not been studied and reported to analyze the relationship of response time, biasing voltage, lumping phenomena, cell gap, and contrast ratio for toner particle type display.

• Bulletin of the Korean Chemical Society
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• 제17권10호
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• pp.939-943
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• 1996

Reactions that proceed within mixed acetylene-methanol and ethylene-methanol cluster ions were studied using an electron-impact time-of-flight mass spectrometer. When acetylene and methanol seeded in helium are expanded and ionized by electron impact, the ion abundance ratio, [CH3OH+]/[CH2OH+] shows a propensity to increase as the acetylene/methanol mixing ratio increases, indicating that the initially ionized acetylene ion transfers its charge to adjacent methanol molecules within the clusters. Investigations on the relative cluster ion intensity distributions of [CH3OH2+]/[CH3OH+] and [(CH3OH)2H+]/[CH3OH·CH2OH+] under various experimental conditions suggest that hydrogen-atom abstraction reaction of acetylene molecule with CH3OH ion is responsible for the effective formation of CH2OH ion. In ethylene/methanol clusters, the intensity ratio of [CH3OH2]/[CH3OH] increases linearly as the relative concentration of methanol decreases. The prominent ion intensities of (CH3OH)mH over (CH3OH)m-1CH2OH ions (m=1, 2, and 3) at all mixing ratios are also interpreted as a consequence of hydrogen atom transfer reaction between C2H4 and CH3OH to produce the protonated methanol cluster ions.