• 분석과학
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• 제13권6호
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• pp.705-711
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• 2000

리튬 이차전지용 부극 재료로 페놀 수지로 부터 유도된 boron을 doping한 polyacene에 구조적 특성, 표면 특성 및 전기적 특성을 연구하였다. Polyacene탄소질에 boron의 함유량을 각각 5%, 10%, 15%, 20% 첨가하여 특성화하였다. X-선 회절 결과에 따르면, 이들 시료들은 대표적인 무정형 탄소의 회절형태를 나타내었다. 표면 상태는 반구형의 표면상태를 가지고 있음을 SEM 결과로부터 알 수 있었다. 전지의 이온과 전자전달효과를 알아보기 위한 전기 화학적 충전/방전 특성과 임피던스 측정의 결과에 의하면, 10%와 15% boron이 첨가된 시료는 다소 우수한 특성을 나타내고 있다.

• 대한화학회지
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• 제34권3호
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• pp.248-254
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• 1990

5각-이종원자 방향족 고리화합물들인 푸란, 피롤 그리고 티오펜과 이소프로필 양이온간의 친전자성 친환반응에 관하여 MNDO 방법을 사용하여 이론적으로 연구하였다. ${\alpha},{\beta}$ 그리고 이종원자 방향족 고리화합물의 HOMO간의 전하전이 안정화(Charge transfer stabilization) 효과에 의하여 주로 결정됨을 알 수 있었다. 한편 $\alpha$ 와 $\beta$ 위치에 대한 반응성의 순서는 피롤>푸란>티오펜의 순서를 가지며 이러한 순서는 기체상 및 용액상 실험결과와 잘 일치하는 것이다.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2010년도 춘계학술대회 초록집
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• pp.89.2-89.2
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• 2010

The dye-sensitized solar cell (DSSC) is a device for the conversion of visible light into electricity, based on the sensitization of wide bandgap semiconductors. The performance of the cell mainly depends on a dye used as sensitizer. The absorption spectrum of the dye and the anchorage of the dye to the surface of $TiO_2$ are important parameters determining the efficiency of the cell. Generally, transition metal coordination compounds(ruthenium polypyridyl complexes) are used as the effective sensitizers, due to their intense charge-transfer absorption in the whole visible range and highly efficient metal-to ligand charge transfer. However, ruthenium polypyridyl complexes contain a heavy metal, which is undesirable from point of view of the environmental aspects. Moreover, the process to synthesize the complexes is complicated and costly. Alternatively, organic dyes can be used for the same purpose with an acceptable efficiency. The advantages of organic dyes include their availability and low cost. We designed and synthesized a series of organic sensitizers containing long wavelength absorption-chromophores for the dye sensitized solar cell. The DSSC composed of Blue-chromophores for the sensitization absorbed long wavelength region which is different also applied into the dye-cocktail (mixing) system. The photovoltaic property of DSSCs organic long wavelength absorption-chromophores were measured and evaluated by comparison with that of individual chromophores.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2011년도 춘계학술대회 초록집
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• pp.118.1-118.1
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• 2011

The dye-sensitized solar cell (DSSC) is a device for the conversion of visible light into electricity, based on the sensitization of wide bandgap semiconductors. The performance of the cell mainly depends on a dye used as sensitizer. The absorption spectrum of the dye and the anchorage of the dye to the surface of TiO2 are important parameters determining the efficiency of the cell. Generally, transition metal coordination compounds(ruthenium polypyridyl complexes) are used as the effective sensitizers, due to their intense charge-transfer absorption in the whole visible range and highly efficient metal-to ligand charge transfer. However, ruthenium polypyridyl complexes contain a heavy metal, which is undesirable from point of view of the environmental aspects. Moreover, the process to synthesize the complexes is complicated and costly. Alternatively, organic dyes can be used for the same purpose with an acceptable efficiency. The advantages of organic dyes include their availability and low cost. We designed and synthesized a series of organic sensitizers containing long wavelength absorption-chromophores for the dye sensitized solar cell. The DSSC composed of Blue-chromophores for the sensitization absorbed long wavelength region which is different also applied into the dye-cocktail (mixing) system. The photovoltaic property of DSSCs organic long wavelength absorption-chromophores were measured and evaluated by comparison with that of individual chromophores.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2006년도 추계학술대회 논문집 Vol.19
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• pp.166-167
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• 2006

Dendrimers represent a new class of synthetic macromolecules characterized by a regularly branched treelike structure. Multiple branching yields a large number of chain ends that distinguish dendrimers from conventional star-like polymers and microgels. The azobenzene dendrimer is one of the dendrimeric macromolecules that include the azo-group exhibiting a photochromic character. Due to the presence of the charge transfer element of the azo-group and its rod-shaped structure, these compounds are expected to have potential interest in electronics and photoelectronics, especially in nonlinear optics. In the present paper, we give pressure stimulation to organic thin films and detect the induced displacement current. Functional photoisometrization organic molecular the photo-stimulus to organic monomolecular L-films and LB films of dendrimer and 8A5H were performed. The 8A5H organic monolayer in case of pressure stimulus occurred that positive course but in case of the photo-stimulus compared positive and negative. It is assumed that generation forms of displacement current were measured when photo-stimulus for Impression.

• 대한화학회지
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• 제21권6호
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• pp.434-439
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• 1977

4-피리돈과 루티돈의 전자구조를 SCF MO-CI PPP 방법과 configuration analysis 법을 사용하여 연구하였다. 계산결과와 스펙트럼 분석치와는 잘 일치하였으며 첫번째 $({\pi},{\pi}^*)$ 단일상태는 두 화합물 모두 장축 방향으로 편극되어 있다. Configuration analysis 결과 가장 낮은 $({\pi},{\pi}^*)$ 단일 상태에서는 C=O 작용기의 ${\pi}$ 결합궤도로 부터 디비닐아민 부분의 ${\pi}^*$ 반결합 궤도로 전하가 이동되어 있으나 가장 낮은 $({\pi},{\pi}^*)$ 삼중상태에서는 반대로 디비닐아민 부분으로 부터 C=O 작용기 쪽으로 전하가 이동되어 있음을 알 수 있다.

• 대한전기학회논문지:전기물성ㆍ응용부문C
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• 제55권12호
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• pp.586-590
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• 2006

Dendrimers represent a new class of synthetic macromoleculcs characterized by a regularly branched treelike structure. Multiple branching yields a large number of chain ends that distinguish dendrimers from conventional star-like polymers and microgels. The azobenzene dendrimer is one of the dendrimeric macromolecules that include the azo-group exhibiting a photochromic character. Due to the presence of the charge transfer element of the azo-group and its rod-shaped structure, these compounds are expected to have potential interest in electronics and photoelectronics, especially in nonlinear optics. In the present paper, we give pressure stimulation to organic thin films and detect the induced displacement current. Functional photoisometrization organic molecular the photo-stimulus to organic monomolecular L films and LB films of dendrimer and 8A5H were performed. The 8A5H organic monolayer in case of pressure stimulus occurred that positive course but in case of the photo-stimulus compared positive and negative. It is assumed that generation forms of displacement current were measured when photo-stimulus for impression.

• Journal of Electrochemical Science and Technology
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• 제4권2호
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• pp.61-70
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• 2013

Corrosion inhibition of carbon steel in 2M HCl by some benzohydrazide derivatives (I-III) was studied using weight loss, potentiodynamic polarization, and electrochemical impedance spectroscopy (EIS) techniques at $30^{\circ}C$. Polarization studies showed that all the investigated compounds are of mixed type inhibitors. Temperature studies revealed a decrease in efficiency with rise in temperature and corrosion activation energies increased in the presence of the hydrazide derivatives, probably implying that physical adsorption of cationic species may be responsible for the observed inhibition behavior. Electrochemical impedance studies showed that the presence of benzohydrazide derivatives decreases the double layer capacitance and increases the charge transfer resistance. The adsorption of these compounds on carbon steel surface was found to obey Temkin's adsorption isotherm. Synergistic effects increased the inhibition efficiency in the presence of halide additives namely KI and KBr. An inhibition mechanism was proposed in terms of strongly adsorption of inhibitor molecules on carbon steel surface.

• 한국응용과학기술학회지
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• 제25권4호
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• pp.411-417
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• 2008

A group of new N,N-bis(5-acetylpyridin-2-yl)phenylamine derivatives was synthesized in good yield applying an optimized Buchwald-Hartwig amination protocol. The synthesized compounds showed UV absorption maxima in the range of 320-360 nm, and showed good luminescence at dilute concentrations in the blue region of the spectra (in the range of 480-497 nm). They showed also a bathochromic shift associating the increase in solvent polarity. The synthesized compounds could be investigated for use in OLEDs or as potential monomers for PLEDs.

• 한국결정성장학회지
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• 제31권2호
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• pp.69-72
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• 2021

The reaction of ammonium ferric sulfate with sodium borohydride in laponite sol yields nanoiron colloidal solution. This solution in air forms transparent yellow brown solution. The resulting solution reacts with bidentate chelating ligands. The reaction products are characterized by UV-Vis absorption spectroscopy and X-ray diffraction. All compounds show metal to ligand charge transfer band in the region of 400~650 nm in UV-Vis absorption spectra. This indicates the formation of iron-ligand complex by air oxidation of nanoiron. Also, XRD patterns exhibit that the iron-ligand complex is intercalated in the interlayer of laponite.