• Title/Summary/Keyword: Charge capacity

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The crystal growth and the electrochemical property of $LiZn_xMn{2-x}O_4(0\leqq x \leqq$ 0.15) cathode material ($LiZn_xMn{2-x}O_4(0\leqq x \leqq$ 0.15) 정극 활물질의 결정 성장 변화와 전기 화학적 특성)

  • Jeong, In-Seong;Gu, Hal-Bon;Lee, Jin;Park, Gye-Choon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.05a
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    • pp.133-136
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    • 1999
  • We report on the electrochemical properly of LiZ $n_{x}$Mn $_{2-x}$ $O_4$ for different degrees of Zn substitution(x) Though all cathode material showed spinel phase based on cubic phase in X-ray diffraction, other peaks(M $n_2$ $O_3$ or M $n_3$ $O_4$) gradually exhibited and became intense with the increase of x vague in LiZ $n_{x}$Mn $_{2-x}$ $O_4$. In addtion, TG-DTA analysis exhibited that both LiM $n_2$ $O_4$ and LiZ $n_{0.1}$ M $n_{1.9}$ $O_4$ occurred the weight loss(TG) and the endothermic and exothermic reaction(DTA) until 80$0^{\circ}C$ When x=0.1 in LiZ $n_{x}$Mn $_{2-x}$ $O_4$ cathode materials showed the charge and discharge capacity of about 100mAh/g at first cycle and about 70mAh/g after tooth cycle.cle.e.cle.e.e.e.

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Organic Solvents Containing Zwitterion as Electrolyte for Li Ion Cells

  • Krishnan, Jegatha Nambi;Kim, Hyung-Sun;Lee, Jae-Kyun;Cho, Byung-Won;Roh, Eun-Joo;Lee, Sang-Gi
    • Bulletin of the Korean Chemical Society
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    • v.29 no.9
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    • pp.1705-1710
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    • 2008
  • Imidazolium based zwitterions, 1,2-dimethylimidazolium-3-n-propanesulfonate (DMIm-3S) and 1-Butylimidazolium-3-n-butanesulphonate (BIm-4S), were synthesized, and utilized them as additive for Li ion cell comprising of graphite anode and $LiCoO_2$ cathode. The use of 10 wt% of DMIm-3S in 1 M $LiPF_6$, EC-EMCDMC (1:1:1 (v/v)) resulted in the increased high rate charge-discharge performance. The low temperature performance of the Li ion cells at about −20 ${^{\circ}C}$ was also enhanced by these zwitterion additives. The DMIm- 3S additive resulted in the better capacity retention by the Li-ion cells even after 120 cycles with 100% depth of discharge (DOD) at 1 C rate in room temperature. Surface morphology of both graphite and $LiCoO_2$ electrode before and after 300 cycles was studied by scanning electron microscopy. An analogous study was performed using liquid electrolyte without any additive.

A Study on the Change of Fishes Market and Inland Market Brokers on Gunsan,1899-1919 (한말$\cdot$일제강점 초기 군산 어물시장의 변동과 객주)

  • Kim Tae-Woong
    • The Journal of Fisheries Business Administration
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    • v.36 no.1 s.67
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    • pp.103-120
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    • 2005
  • This study aims to examine the change of fish market(魚物市場) and inland brokers(客主, kaegju) on Gunsan(群山), (1899-1919). The increasement of productive capacity in the agriculture and the development of exchange economy in the late period of Chosun Dynasty activated the distribution of fishery products. As a result, the inland brokers who participated in the production and distribution of fishes grew largely. They made the basement of fishery modernization by providing the funds for the fisheries and making the national distribution network. But Japanese fishermen began to hold the domestic market as the Japan government supported legislatively and economically after the opening ports of Korea. On the contrary, the distribution of fishery products had the characteristics different from the production of some. The case of Gunsan which opened in 1899 showed these characteristics as Gunsan is a short distance from Kangkyung(江景), one of three biggest markets and was a base of fishery, That is to say, though the fishery merchants from Japan set up 'a fish market'(魚市場), they didn't hold the sales network on Gunsan, Because the inland brokers on Gunsan had a sales network and began the socio-economic movement. It goes without saying that the instability of price, the difficulties of charge and the racial taste difference in fish made the fish sales from Japan confronted with the difficulties. After Japanese Imperialism enforced the Company Law, the Market Regulation, the Chamber of Commerce Law before or after 1910, Korean inland brokers were disprited and Japanese 'fish market' began to grow largely. These phenomena appeared on Gunsan, too. Especially, the opening of a railway was the main factor which strengthened Japanese 'fish market'. After 1915, Japanese 'fish market' on Gunsan defeated the distribution network of inland brokers.

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Performance of HFC32/HFC125 Mixtures for Heat Pumps (HFC32/HFC125 혼합냉매의 히트펌프 성능 평가)

  • Kim, Wook-Jin;Kang, Dong-Gyu;Lee, Yo-Han;Jung, Dong-Soo
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.23 no.12
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    • pp.791-798
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    • 2011
  • In this study, performance of R410A(50%R32/50%R125) and HFC32/HFC125 mixture is measured to examine the effect of composition shift of R410A used for various air-conditioners and heat pumps. The composition of HFC32/HFC125 mixture varies from the reference composition of R410A ${\pm}10%$ with 5% interval. Tests carried out in a heat pump bench tester at the evaporation and condensation temperatures of $7/45^{\circ}C$ and $-7/41^{\circ}C$ for summer and winter conditions, respectively. Test results show that both the coefficient of performance (COP) and compressor power of the HFC32/HFC125 mixture have the maximum difference of 2.0% as compared to those of R410A. Compressor discharge temperatures of HFC32/HFC125 mixture are increased up to $6.7^{\circ}C$ as compared to that of R410A. The amount of charge for HFC32/HFC125 mixture vary within 5.6% as compared to that of R410A. Overall, performance of R410A is not appreciably affected by the composition shift of ${\pm}10%$ of R32 under both air-conditioning and heat pumping conditions.

DC Traction Regenerative Energy Storage Devices using Super-capacitor (슈퍼 커패시터를 이용한 직류철도 회생에너지 저장장치)

  • Kim, Jong-Yoon;Jung, Doo-Yong;Jang, Su-Jin;Lee, Byoung-Kuk;Won, Chung-Yuen
    • The Transactions of the Korean Institute of Power Electronics
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    • v.13 no.4
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    • pp.247-256
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    • 2008
  • Regenerative energy generated by regenerative braking of DC traction can cause the system malfunction or damage to the rectifier, or malfunction of the power conversion device in power supply system by DC Line voltage rise in feeder line. Regenerative energy storage system using super capacitor is one of the ways to stabilize DC line voltage. In this paper, energy storage system of DC traction system using super-capacitor bank is implemented and using the field measurement data of the station N and the station S on the Line 2, the operation characteristics of line voltage caused by regenerative energy of electric trains are verified. Also, charge/discharge characteristics of super capacitor are verified as well. Thus, we can verify the operation characteristics of super-capacitor bank for regenerative energy storage system installed in DC Traction. And if we can use field measurement data of DC line voltage, we have obtained cost reduction. The stabilization of the system will be improved by measuring the operation characteristics of regenerative energy storage system in certain section operated by DC traction and predicting the capacity and lifetime of super-capacitor.

Synthesis of $LiCoO_{2}$ Nanoparticles From Leach Liquor of Lithium Ion Battery Wastes by Flame Spray Pyrolysis

  • Lee Churl Kyoung;Chang Hankwon;Jang Hee Dong;Sohn Jeong-Soo
    • Resources Recycling
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    • v.14 no.6 s.68
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    • pp.37-43
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    • 2005
  • [ $LiCoO_{2}$ ] nanoparticles were synthesized from leach liquor of lithium ion battery waste using flame spray pyrolysis. Electrode Materials containing lithium and cobalt could be concentrated with thermal and mechanical treatment. After dissolution of used cathode materials of the lithium battery with nitric acid, the molar ratio of Li/Co in the leach liquor was adjusted at 1.0 by adding a fresh $LiNO_{3}$ solution. The nanoparticles synthesized by the flame spray pyrolysis showed clear crystallinity and were nearly spherical, and their average primary particle diameters ranged from 11 to 35 nm. The average particle diameter increased with an increase in the molar concentration of the precursor. Raising the maximum flame temperature by controlling the gas flow rates also led to an increase in the average diameter of the particles. The $LiCoO_{2}$ powder was proved to have good characteristics as cathode active materials in charge/discharge capacity and cyclic performance.

P2P DICOM System using Multiagent Systems Communicating with XML Encoded ACL (XML 기반 ACL로 통신하는 멀티에이전트 시스템을 이용한 P2P DICOM 시스템)

  • Kwon, Gi-Beom;Kim, Il-Kon
    • Journal of KIISE:Computing Practices and Letters
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    • v.8 no.5
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    • pp.598-606
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    • 2002
  • We suggest a distributed communication and management methodology using PC to PC Query multicasting strategy for efficient management of medical images produced by DICOM(Digital Imaging and Communications in Medicine) Modalities. It is absolutely necessary to reduce strict degradation of PACS system due to large sire of medical images and their very high transport rates. DICOM PC to PC Component is composed of a Service Manager to execute requested queries, a Communication Manager to take charge of file transmission, and a DICOM Manager to manage stored data and system behavior Each Manager itself is a component to search for requested file by interaction or to transmit the file to other PCs. Distributed management and transformation of medical information based on PC to PC Query multicasting methodology will enhance performance of central server and network capacity, reducing overload on both. We organize three major components for system operation. Each component is implemented as Agent. Communication between agents uses XML encoded Agent Communication Language.

A Study on the Application of Phase Change Material for Electric Vehicle Battery Thermal Management System using Dymola (전기자동차 배터리팩 열관리시스템에서 상변화물질 적용에 관한 고찰)

  • Choi, Chulyoung;Choi, Woongchul
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.66 no.12
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    • pp.1889-1894
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    • 2017
  • Global automobile manufacturers are developing electric vehicles (EVs) to eliminate the pollutant emissions from internal combustion vehicles and to minimize fossil fuel consumptions for the future generations. However, EVs have a disadvantage of shorter traveling distance than that of conventional vehicles. To answer this shortfall, more batteries are installed in the EV to satisfy the consumer expectation for the driving range. However, as the energy capacity of the battery mounted in the EV increases, the amount of heat generated by each cell also increases. Naturally, a better battery thermal management system (BTMS) is required to control the temperature of the cells efficiently because the appropriate thermal environment of the cells greatly affects the power output from the battery pack. Typically, the BTMS is divided into an active and a passive system depending on the energy usage of the thermal management system. Heat exchange materials usually include gas and liquid, semiconductor devices and phase change material (PCM). In this study, an application of PCM for a BTMS was investigated to maintain an optimal battery operating temperature range by utilizing characteristics of a PCM, which can accumulate large amounts of latent heat. The system was modeled using Dymola from Dassault Systems, a multi-physics simulation tool. In order to compare the relative performance, the BTMS with the PCM and without the PCM were modeled and the same battery charge/discharge scenarios were simulated. Number of analysis were conducted to compare the battery cooling performance between the model with the aluminum case and PCM and the model with the aluminum case only.

Non-volatile Molecular Memory using Nano-interfaced Organic Molecules in the Organic Field Effect Transistor

  • Lee, Hyo-Young
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.31-32
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    • 2010
  • In our previous reports [1-3], electron transport for the switching and memory devices using alkyl thiol-tethered Ru-terpyridine complex compounds with metal-insulator-metal crossbar structure has been presented. On the other hand, among organic memory devices, a memory based on the OFET is attractive because of its nondestructive readout and single transistor applications. Several attempts at nonvolatile organic memories involve electrets, which are chargeable dielectrics. However, these devices still do not sufficiently satisfy the criteria demanded in order to compete with other types of memory devices, and the electrets are generally limited to polymer materials. Until now, there is no report on nonvolatile organic electrets using nano-interfaced organic monomer layer as a dielectric material even though the use of organic monomer materials become important for the development of molecularly interfaced memory and logic elements. Furthermore, to increase a retention time for the nonvolatile organic memory device as well as to understand an intrinsic memory property, a molecular design of the organic materials is also getting important issue. In this presentation, we report on the OFET memory device built on a silicon wafer and based on films of pentacene and a SiO2 gate insulator that are separated by organic molecules which act as a gate dielectric. We proposed push-pull organic molecules (PPOM) containing triarylamine asan electron donating group (EDG), thiophene as a spacer, and malononitrile as an electron withdrawing group (EWG). The PPOM were designed to control charge transport by differences of the dihedral angles induced by a steric hindrance effect of side chainswithin the molecules. Therefore, we expect that these PPOM with potential energy barrier can save the charges which are transported to the nano-interface between the semiconductor and organic molecules used as the dielectrics. Finally, we also expect that the charges can be contributed to the memory capacity of the memory OFET device.[4]

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Photocatalytic Properties of the Ag-Doped TiO2 Prepared by Sol-Gel Process/Photodeposition (졸-겔공정/광증착법을 이용한 Ag-Doped TiO2 합성 및 광촉매 특성)

  • Kim, Byeong-Min;Kim, Jung-Sik
    • Korean Journal of Materials Research
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    • v.26 no.2
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    • pp.73-78
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    • 2016
  • $TiO_2$ nanoparticles were synthesized by a sol-gel process using titanium tetra isopropoxide as a precursor at room temperature. Ag-doped $TiO_2$ nanoparticles were prepared by photoreduction of $AgNO_3$ on $TiO_2$ under UV light irradiation and calcinated at $400^{\circ}C$. Ag-doped $TiO_2$ nanoparticles were characterized for their structural and morphological properties by X-ray diffractometry (XRD), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), and transmission electron microscopy (TEM). The photocatalytic properties of the $TiO_2$ and Ag-doped $TiO_2$ nanoparticles were evaluated according to the degree of photocatalytic degradation of gaseous benzene under UV and visible light irradiation. To estimate the rate of photolysis under UV (${\lambda}=365nm$) and visible (${\lambda}{\geq}410nm$) light, the residual concentration of benzene was monitored by gas chromatography (GC). Both undoped/doped nanoparticles showed about 80 % of photolysis of benzene under UV light. However, under visible light irradiation Ag-doped $TiO_2$ nanoparticles exhibited a photocatalytic reaction toward the photodegradation of benzene more efficient than that of bare $TiO_2$. The enhanced photocatalytic reaction of Ag-doped $TiO_2$ nanoparticles is attributed to the decrease in the activation energy and to the existence of Ag in the $TiO_2$ host lattice, which increases the absorption capacity in the visible region by acting as an electron trapper and promotes charge separation of the photoinduced electrons ($e^-$) and holes ($h^+$). The use of Ag-doped $TiO_2$ nanoparticles preserved the option of an environmentally benign photocatalytic reaction using visible light; These particles can be applicable to environmental cleaning applications.