• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1997년도 추계학술대회 논문집
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• pp.275-278
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• 1997

We investigated effectness of sort and volume of conductive agent to charge/discharge capacity of LiMn$_2$O$_4$. LiMn$_2$O$_4$is prepared by reacting stoichiometric mixture of LiOH . $H_2O$ and MnO$_2$(mole ratio 1 : 2) and heating at 80$0^{\circ}C$ for 24h, 36h, 48h, 60h and 72h. All LiMn$_2$O$_4$cathode active materials show spinel structure. Cathode active materials calcined at 80$0^{\circ}C$ for 36h, charge/discharge characteristics and cycle stability have remarkable advantages. Used that super-s-black and 20wt% as conductive agent in LiMn$_2$O$_4$, it is excellent than property of cathode used Acetylene black or mixture of Super-s-black and acetylene black at charge/discharge capacity and cycle stability. Also, specific efficiency of cathode is excellent as over 98% and that of first cycle is excellent as 92%.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1999년도 춘계학술대회 논문집
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• pp.362-365
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• 1999

The electrochemical properties of flyash obtained from combustion of fuel in fossil power plants and their performance as anode material of secondary battery have been investigated Various flysh pellets molded at various molding pressure have been used as anode lithium secondary battery. The best Performance was achieved when flyash pellet molded at pressure of 400kgf/$\textrm{cm}^2$ is utilized, that is, charge capacity of 300kgf/$\textrm{cm}^2$ and Coulombic efficiency of larger than 95% have been achieved. In addition, this battery exhibited good cycling performance. Considering these results, we predicted that utilization of the flyash as anode material and polyaniline conducting polymer as cathode material in a secondary will show capacity of 300mAh/g and Coulombic efficiency of higher than 95%.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2000년도 추계학술대회 논문집
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• pp.335-338
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• 2000

Carbon is an attractive candidate for use in eletrochemical supercapacitors that depend on charge storage in the electrode/electrolyte international double layer. Property of an electrical double layer capacitor depend both on the technique used to prepare the electrode and on the current collector structure. The study is to research that V$_2$O$_{5}$-flyash-AC composite electrode for supercapacitor. The discharge capacitance of V$_2$O$_{5}$-flyash-AC(70wt%) in 1st and 50th cycle was 18.6F/g and 15.13F/g at current density of 0.5mA/cm$^2$. The discharge process of V$_2$O$_{5}$-flyash (3 : 97)-AC composite electrode is larger than that others.thers.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1997년도 하계학술대회 논문집 C
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• pp.1594-1596
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• 1997

$LiMn_2O_4$ is prepared by reacting stoichiometric mixture of LiOH $H_2O$ and $MnO_2$ (mole ratio 1 : 2) and calcinating at $800^{\circ}C$ for 24h, 36h, 48h, 60h and 72h. At X-ray diffraction, cathode active materials calcined at $800^{\circ}C$ for 36h. (111)/(311) peak ratio was 0.37. It was that crystal structure is formed very well. In the result of charge/discharge test, when heated at $800^{\circ}C$ for 36h, charge/discharge characteristics of $LiMn_2O_4$ is the best and Super-s-black sort of conductive agent showed well property. Also, AC impedance creased gradually during cycling and stabilized after 10cycle.

• 한국전기전자재료학회논문지
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• 제14권8호
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• pp.663-669
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• 2001

Spinel LiM $n_2$ $O_4$ and LiM $n_{1.9}$M $g_{0.1}$ $O_4$ power was synthesized with solid-state method by calcining the mixture of LiOH.$H_2O$, Mn $O_2$ and MgO at 80$0^{\circ}C$ for 36 h in an air atmosphere. To investigate the effect of temperature on he cycle performance of cathode material during cycling, charge-discharge experiments and ac impedance measurement were performed. Initial discharge capacity was gradually increased with the increase of charge-discharge temperature. Discharge capacity at high temperature was suddenly decreased during cycling. On the other hand, discharge capacity at low temperature was almost constant during cycling. It confirmed that Mn dissolution is serious at high temperature than at low temperature. LiM $n_2$ $O_4$ and LiM $n_{1.9}$M $g_{0.1}$ $O_4$ showed the best capacity and stability at room temperature.ure.ure.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1996년도 하계학술대회 논문집 C
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• pp.1703-1706
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• 1996

The purpose of this study is to research and develop polypyrrole(PPy) positive for thin film rechargeable lithium battery. We investigated cyclic voltammetry, AC impedance response and charge/discharge cycling of PPy/SPE/Li cells as a function of temperature. The redox capacity of $PPy/CF_{3}SO_{3}$ film was the most large. The discharge capacity of PPy/SPE/Li cell with $PPy/CF_{3}SO_{3}$ film was higher than those of $PPy/ClO_{4}$ and $PPy/AsF_6$ films at all cycles. The energy density of PPy/SPE/Li cells during 1st cycle was 73, 90 and 101Wh/kg at $25^{\circ}C$, $45^{\circ}C$ and $60^{\circ}C$, respectively. The improvement of energy density is due to reduction of charge-transfer resistance associated doping-undoping process in PPy film with Increasing temperature. $PPy/CF_{3}SO_{3}$ film shows a good property on charge/discharge cycling in PEO-$LiClO_4$-PC-EC electrolyte.

• 한국수소및신에너지학회논문집
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• 제7권2호
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• pp.165-171
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• 1996

The effect of rolling on the charge-discharge property was studied for metal hydride negative electrode. $(LM)Ni_{3.6}Al_{0.4}Co_{0.7}Mn_{0.3}$(pleateau pressure : below 1 atm at room temperature, volume expansion : 9%, entalpy : $8.7kcal/molH_2$) alloy was prepared by arc melting, and then it was coated with various copper weight percent. The copper coated alloys were then rolled with the different reduction ratio. From the results, it was found that the maximum discharge capacity increased with increasing reduction ratio, and 15wt% copper coated sample shows the highest discharge capacity, 324mAh/g, after rolling with 30% reduction ratio. In view of cycle life for the negative electrode, the 15wt% copper coated electrode which was rolled with 13% reduction ratio showed the longest cycle life compared with other electrodes.

• 전력전자학회:학술대회논문집
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• 전력전자학회 1998년도 Proceedings ICPE 98 1998 International Conference on Power Electronics
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• pp.934-937
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• 1998

Charge/discharge property of LiMn2O4 was investigated with LiMn2O4/Li cell for use of lithium ion battery in electric vehicle. LiMn2O4 calcined at $800^{\circ}C$ for 36hr show high charge/discharge capacity and excellent cycle stability than that of others. This is found to be in agreement with expectation in the X-ray diffraction analysis. In addition, the kind and volume of conductive agent involved in LiMn2O4 cathode is excellent at super-s-black and 20wt%, respectively.

• Bulletin of the Korean Chemical Society
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• 제30권3호
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• pp.657-660
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• 2009

The surface of $Li[Ni_{0.8}Co_{0.15}Al_{0.05}]O_2$ cathode particle was modified by lanthanum based oxide to improve electrochemical property and thermal stability. The XRD pattern of surface layer was indexed with that of $La_4NiLiO_8$. The discharge capacity of modified electrode was higher than that of pristine sample, specially at fast charge-discharge rate and high cut-off voltage. In the DSC profile of the charged sample, the generation of heat by exothermic reaction was decreased by surface modification. Such enhancement may by attributed to the presence of stable lanthanum based oxide, which effectively suppressd the reaction between electrode and electrolyte on the surface of $Li[Ni_{0.8}Co_{0.15}Al_{0.05}]O_2$ electrode.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2001년도 하계학술대회 논문집
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• pp.474-477
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• 2001

The properties of LiMnO$_2$ was studied as a cathode active material for lithium polymer batteries. LiMnO$_2$ cathode active materials were synthesized by the reaction of LiOH . $H_2O$ and Mn$_2$O$_3$at various temperature under argon atmosphere. For lithium polymer battery applications, the LiMnO$_2$cell was characterized electrochemically by charge-discharge experiments and a.c. impedance spectroscopy. And the relationship between the characteristics of powders and electrochemical properties was studied in this research. A maximum discharge capacity of 160-170 mAh/g for ο-LiMnO$_2$ cell was achieved. Used that SP270 as electric active material in LiMnO$_2$, it is excellent than property of electric active material used Acetylene black or KS6 at charge/discharge capacity.