• Transactions of the Korean hydrogen and new energy society
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• v.24 no.2
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• pp.179-185
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• 2013

The behavior of surface film formation was greatly dependent on the speed of potential cycling. In $LiClO_4$ / EC + DEC, cyclic voltammetry results showed that the peaks originated from surface film formation on graphite electrode at the high charge-discharge rate was shifted to the lower potentials as the charge-discharge rate decrease. This indicates that surface films with different morphology and thickness were formed by different charge-discharge rate. Transmission electron microscopy (TEM) results indicated that the properties such as thickness and morphology of the surface film were greatly affected by the charge-discharge rate. Electrochemical impedance spectroscopy (EIS) showed that the resistance of surface film was affected by the speed of potential cycling. In addition, the charge transfer resistance was also dependent on the charge-discharge rate indicating that the charge transfer reaction was affected by the nature of surface film. TEM and EIS results suggested that the chemical property as well as the physical property of the surface film was affected by the charge-discharge rate.

• Proceedings of the KIPE Conference
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• 1998.10a
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• pp.554-559
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• 1998

Equalizing the state of charge of cell that affects the charge/discharge quality and efficiency of the battery through the charge/discharge characteristic experiments of battery source, we develope the high efficiency charge/discharge system which would be used in serial HEV with the constant engine-generator output. For this, establishes the electrical model of Ni-MH battery appropriate to the high efficiency charge/discharge conditions. There is no model of Ni-MH cell, so we used Ni-Cd model and obtain the Ni-MH model through the experiment. A reason that each cell has the same charge/discharge property for applying the cell model to serial/parallel connected battery source extensively is needed. Therefore, in this paper, propose the Ni-MH charger/discharger has the equalization charging function and selectable cut-off function.

• Journal of the Korea Safety Management & Science
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• v.2 no.2
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• pp.187-200
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• 2000

The charge and discharge current in EPR(Ethylene Propylene Rubber), which were irradiated with the radiant capacity of 0~600 ［kgy/h］, have been measured in order to investigate the influence of the atmosphere (oxygen, air and vacuum) on electrical properties. It has been shown that the charge and discharge current increase as the amount of radiant capacity increases in air and vacuum atmosphere. This electrical property degradation can be speculated due to that the C＝O radicals or impurities, which comes from during shaping process, may act as dipoles. On the other hand, the charge and discharge current are shown to be higher in the amount of 1［kgy/h］ than these in 10［kgy/h］ in air atmosphere, because the charge and discharge current can be increased as the exposure time is extended with slower rate. Under the same amount of irradiation, the charge and discharge current in oxygen atmosphere are shown to be higher than those in vacuum. This is possibly due to that the main chain can be broken by oxidation when it is exposed to the $\gamma$ -rays.

• Proceedings of the KIEE Conference
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• 1997.07d
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• pp.1603-1605
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• 1997

$LiNiO_2$ is prepared by heating LiOH $H_2O$ and $Ni(OH)_2$ (mole ratio 1:1). In this study, we investigated X-ray diffraction, and charge/discharge property heat treatment condition and conductive agent sort and volume of $LiNiO_2$ prepared at various temperature and time. All $LiNiO_2$ prepared at this study showed hexagonal structure. In charge/discharge capacities, heated at $O_2$ than air and $750^{\circ}C$ than $700^{\circ}C$, specific capacity is higher. Therefore, when preliminary heat at $650^{\circ}C$ $O_2$ and heat at $750^{\circ}C$ carried out, charge/discharge property is best.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1996.11a
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• pp.369-372
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• 1996

We prepared LiMn$_2$O$_4$ by reacting stoichiometric mixture of LiOH.$H_2O$ and MnO$_2$ (mole ratio 1 : 1) and heating at 80$0^{\circ}C$ for 24h, 36h, 48h, 60h and 70h. We obtained through X-ray diffraction that lattice parameter varied as function of heat treatment time. heated cathode active materials at 80$0^{\circ}C$ for 36h, (111)/(311) peak ratio was 0.37. It expected good charge/discharge characteristics. When (111)/(311) peak ratio was 0.37, it will be that crystal structure is farmed very well. In the result of charge/discharge test When heated at 80$0^{\circ}C$ for 36h, charge/discharge characteristic of LiMn$_2$O$_4$is the most property. It agree with our expectation.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2000.07a
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• pp.507-510
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• 2000

The purpose of this study is to research and developV$_2$O$_{5}$-SP270 composite electrode for supercapacitor. Property of an electrical double layer capacitor depend both on the technique used to prepare the electrode and on the current collector structure. The study is to research that V$_2$O$_{5}$-carbon composite electrode for supercapacitor with different voltage range. Suprcapacitor cell of V$_2$O$_{5}$-SP270 composite electrode with 25PVDFLiC1O$_4$PC$_{10}$ polymer electrolyte bring out good capacitor performance below 3V. The discharge capacitance of SP270 in 1st cycles was 13F/g at 0.1mA/cm$^2$, 3V. We performed cycle voltammogram, charge/discharge property.y.rty.y.

• Journal of the Korean Ceramic Society
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• v.37 no.2
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• pp.128-133
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• 2000

In this work, soft carbons produced by pyrolysis of petroleum and coal-tar pitch were used as the negative electrode for Li-ion batteries. We studeid the charge/discharge capacity and the interfacial reaction of these electrodes by constructing a half cell. Charge/discharge property was studied by a constant-current step and the interfacial reaction between the electrolyte and the surface of a carbon electrode was studied by the cyclic voltammetry. The initial charge/discharge capacity for the coal-tar pitch carbon increased exceedingly with the heat treatment temperature. On hte other hand, the capacity of the petroleum pitch carbon increased with temperature up to 1000$^{\circ}C$, thereafter decreased continuously. While the charge capacity decreased with the cycle number, the reversibility increased above 90%. In addition, the thermal stability and crystallization of petroleum and coal-tar pitches were analyzed by TGA and XRD, respectively.

• Journal of the Semiconductor & Display Technology
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• v.15 no.2
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• pp.55-60
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• 2016

This study was developed through the secondary battery module charging/discharger possible utilization in the production process equipment circuit. The developed module is ensuring construction of efficient and productive charging and discharger through this research a limit on the yield and the price of existing single -channel charge and discharger circuit as a 5V 70A grade secondary battery Formation charge and discharger for up to 1 board 4 channels. In order to improve the sensing accuracy, through a robust differential amplifier circuit described using 16bit Analog-Digital Converter and noise was secured 16bit resolution sensing. The configuration also made demands for property Rise / Fall Time. Data Acquisition, discharge efficiency and also to fit the sink circuit temperature level for mass production.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1999.11a
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• pp.383-386
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• 1999

The importance of rechargeable lithium cells has been emphasized. So a large variety of materials has been discovered and evaluated for use as reversible cathodes and electroyltes. This paper examines the charge/discharge properties and the charge/discharge cycling life of Li$_2$O-P$_2$O-V$_2$O$_{5}$Li cells. In audition, DTA tests were carried out on Li$_2$O-P$_2$O-V$_2$O$_{5}$ glass. As a result the best performance was achieved when 0.3Li$_2$O-0.1P$_2$O$_{5}$-0.6V$_2$O$_{5}$Li cells was mixed with SP270. that is discharge capacity of 240mAh/g have been achieved. In addition this battery exhibited good cycling performance. Considering these results we expected utilization of the Li$_2$O-P$_2$O-V$_2$O$_{5}$ glass as a cathode material in a secondary battery.y battery.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2000.05b
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• pp.269-272
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• 2000

Spinel $LiMn_2O_4$ samples are prepared by heating a $LiOH{\cdot}H_2O/MnO_2$ mixture in air at $800^{\circ}C$ for 36h, and their structure and electrochemical performance are studied by using X-ray diffraction, Cyclic Voltammetry, AC Impedance, and Charge-discharge measurements. It was found that the electrochemical properties of the $LiMn_2O_4$ samples are very sensitive to substituted volume of lithium. Initial impedances of all cathode was similar. Initial resistance was $60{\sim}70{\Omega}$. Reaction peak of Cyclic voltammetry was weak by increase of substituted volume of lithium. $Li[Li_{0.08}Mn_{1.92}]O_4$ and $Li[Li_{0.1}Mn_{1.9}]O_4$ cathode materials showed the charge and discharge capacity of about 125mAh/g at first cycle, and about 95mAh/g after 70th cycle. It showed excellent property in sample revealed good structure and other electrochemical property.