• 전기학회논문지
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• 제64권2호
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• pp.208-213
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• 2015

This study presents the estimation method for the optimal capacity of BESS(Battery Energy Storage System) in order to reduce the electric charges of common consumer. The daily optimal charge and discharge plan of BESS which satisfies the given constraints is established using linear programming through the change of rated output/rated capacity of the time that shows the electric charges in the highest reduced rate has been selected. There will be a problem to compare only reduced rate because the bigger the rated capacity, the more reduced rate is increased. Therefore, rated output/rated capacity of the time when the reduced amount of electric charges for a year is higher than the investment cost of BESS was selected.

• 한국수소및신에너지학회논문집
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• 제7권2호
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• pp.165-171
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• 1996

The effect of rolling on the charge-discharge property was studied for metal hydride negative electrode. $(LM)Ni_{3.6}Al_{0.4}Co_{0.7}Mn_{0.3}$(pleateau pressure : below 1 atm at room temperature, volume expansion : 9%, entalpy : $8.7kcal/molH_2$) alloy was prepared by arc melting, and then it was coated with various copper weight percent. The copper coated alloys were then rolled with the different reduction ratio. From the results, it was found that the maximum discharge capacity increased with increasing reduction ratio, and 15wt% copper coated sample shows the highest discharge capacity, 324mAh/g, after rolling with 30% reduction ratio. In view of cycle life for the negative electrode, the 15wt% copper coated electrode which was rolled with 13% reduction ratio showed the longest cycle life compared with other electrodes.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2007년도 하계학술대회 논문집 Vol.8
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• pp.361-362
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• 2007

Phospho-olivine $LiFePO_4$ cathode materials were prepared by hydrothermal reaction. Carbon black was added to enhance the electrical conductivity of $LiFePO_4$. The structural and morphological performance of $LiFePO_4$ and $LiFePO_4$-C powders were characterized by X-ray diffraction (XRD) and FE-SEM. $LiFePO_4/SPE/Li$ and $LiFePO_4$-C/SPE/Li cells were characterized electrochemically by charge/discharge experiments. The results showed that the discharge capacity of $LiFePO_4$-C/SPE/Li cell was 103 mAh/g at the first cycle. The discharge capacity of $LiFePO_4$-C/SPE/Li cell with 5 wt% carbon black was the largest among $LiFePO_4$-C/SPE/Li cells, 126 mAh/g at the first cycle and 123 mAh/g after 30 cycles, respectively. It was demonstrated that cycling performance of $LiFePO_4$-C/SPE/Li cell with 5 wt% carbon black was better than that of $LiFePO_4$/SPE/Li cell.

• Journal of Electrochemical Science and Technology
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• 제3권4호
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• pp.172-177
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• 2012

Mo-doped $LiFePO_4$ was synthesized via co-precipitation method using sucrose as the carbon source. Structure, surface morphology, and the electrochemical properties of the synthesized olivine compounds were investigated using Rietveld refinement of X-ray diffraction data (XRD), scanning electron microscopy (SEM), and electrochemical charge-ischarge tests. Spherical morphology with the particle size of ${\sim}8{\mu}m$ authenticated the enhanced tap density and volumetric energy density of the synthesized materials. Charge-discharge behavior of $LiFePO_4$ and Mo-doped $LiFePO_4$ cells demonstrated a specific capacity of 130 and 145 mAh $g^{-1}$, respectively. Mo-doped $LiFePO_4$ cells exhibited an excellent discharge capacity at 96 mAh $g^{-1}$ at 7 C-rate.

• E2M - 전기 전자와 첨단 소재
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• 제7권4호
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• pp.317-324
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• 1994

In this study, new preparation method of LiCoO$_{2}$ was applied to develop cathode active material for Li rechargeable cell, and followed by X-ray diffraction analysis, electrochemical properties and initial charge/discharge characteristics as function of current density. HC8A72- and CC9A24-LiCoO$_{2}$ were prepared by heating treatment of the mixture of LiOH H$_{2}$O/CoCO$_{3}$(1:1 mole ratio) and the mixture of Li$_{2}$CO$_{3}$/CoCO$_{3}$(1:2 mole ratio) at 850 and 900.deg. C, respectively. Two prepared LiCoO$_{2}$s were identified as same structure by X-ray diffraction analysis. a and c lattice constant were 2.816.angs. and 14.046.angs., respectively. The electrochemical potential of CFM-LiCoO$_{2}$(Cyprus Foote Mineral Co.'s product), HC8A72-LiCoO$_{2}$ and CC9A24 LiCoO$_{2}$ electrode were approximately between 3.32V and 3.42V vs. Li/Li reference electrode. Stable cycling behavior was obtained during the cyclic voltammetry of LiCoO$_{2}$ electrode. According as scan rate increases, cathodic capacity decreases, but redox coulombic efficiency was about 100% at potential range between 3.6V and 4.2V vs. Li/Li reference electrode. Cathodic capacity of HC8A72-LiCoO$_{2}$ was 32% higher than that of CFM-LiCoO$_{2}$ and that of CC9A24-LiCoO$_{2}$ was 47% lower than that of CFM-LiCoO$_{2}$ at 130th cycle in the condition of lmV/sec scan rate. Constant cur-rent charge/discharge characteristics of LiCoO$_{2}$/Li cell showed increasing Ah efficiency with initial charge/discharge cycle. Specific discharge capacities of CFM and HC8A72-LiCoO$_{2}$ cathode active materials were about 93mAh/g correspondent to 34% of theretical value, 110mAh/g correspondent to 40% of theretical value, respectively. In the view of reversibility, HC8A72-LiCoO$_{2}$ was also more excellent than CFM- and CC9A24-LiCoO$_{2}$.

• 반도체디스플레이기술학회지
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• 제6권1호
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• pp.53-57
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• 2007

In this paper, the intelligent estimation algorithm is developed for residual quantity estimate of lithium secondary cell and we suggest the control algorithm to get battery SOC through thermal modeling of electric cell. Lithium secondary cell gives cycle life, charge characteristic, discharge characteristic, temperature characteristic, self-discharge characteristic and the capacity recovery rate etc. Therefore, we make an accurate estimate of the capacity of battery according to thermal modeling to know the capacity of electric cell that is decreased by various special quality of lithium secondary cell. And we show effectiveness through comparison of value as result that use simulation and fuzzy logic.

• 전기화학회지
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• 제2권1호
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• pp.46-49
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• 1999

Electron-beam 증발장치를 이용하여 리튬 박막 2차 전지 양극용 lithium cobalt oxide 박막을 제조하였다. Stainless steel -기판 위에 입혀진 $LiCoO_2$ 박막은 열처리 과정을 거쳐 잘 발달된 hexagonal 구조의 (003)면을 나타냈으며, 3.9 V 부근에서 전위 평탄 영역이 나타났다. $LiCoO_2$, 박막은 증착속도가 증가함에 따라 Li/co 조성비가 양론비에 근접하였으며, $15{\AA}/s$의 증착속도로 제작한 경우 높은 방전용량을 나타내었다. 열처리 온도가 증가함에 따라 용량이 증가하여 $700^{\circ}C$에서 최대 값을 나타내었으나, 그 이상의 온도에서는 기판과의 반응 때문에 방전용량이 현저히 감소하였다. 박막 내부의 리튬과 코발트의 불균일한 조성은 초기 방전용량의 감소를 가져왔다.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2000년도 추계학술대회 논문집
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• pp.359-362
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• 2000

The purpose of this study is to research and develop graphene composite for lithium polymer battery. VO(graphene) composite is one of the promising material as a electrode active material for lithium polymer battery(LPB). We investigated AC impedance response and charge/discharge cycling of VO(graphene)/SPE/Li cells. The first discharge capacity of VO(graphene) cathode with 50wt.% V$_2$O$\sub$5/ was 150mAh/g, while that of VO(graphene) cathode with 85wt.% V$_2$O$\sub$5/ was 248mAh/g. The Ah efficiency was above 98% after the 2nd cycle. The discharge capacity of VO(graphene) anode with 3wt.% V$_2$O$\sub$5/ was 718 and 266mAh/g at cycle 1 and 10 at room temperature, respectively. The VO(graphene) anode with 3wt.% V$_2$O$\sub$5/ in PVDF-PAN-PC-EC-LiC1O$_4$ electrolyte showed good capacity with cycling.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2003년도 춘계학술대회 논문집 센서 박막재료 반도체 세라믹
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• pp.88-90
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• 2003

The purpose of this study is to research and develop tin oxide-flash composite for lithium Ion polymer battery. Tin oxide is one of the promising material as a electrode active material for lithium Ion polymer battery (LIPB). Tin-based oxides have theoretical volumetric and gravimetric capacities that are four and two times that of carbon, respectively. We investigated cyclic voltammetry and charge/discharge cycling of SnO-flyash/SPE/Li cells. The first discharge capacity of SnO-flyash composite anode was 720 mAh/g. The discharge capacity of SnO-flyash composite anode 412 and 314 mAh/g at cycle 2 and 10 at room temperature, respectively. The SnO-flyash composite anode with PVDF-PMMA-PC-EC-$LiClO_4$ electrolyte showed good capacity with cycling.

• 전기화학회지
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• 제19권3호
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• pp.114-121
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• 2016

본 연구에서는 리튬이온전지의 충방전시 발생하는 발열특성을 CFD 모델링하고, 발열에 따른 충방전 특성을 해석하였다. 리튬이온전지는 직교 파우치형 구조로서 두께방향으로의 1차원계로 설정하여, 전류밀도 방정식, 열 및 물질전달 지배방정식을 도입하였다. Cut-off 전압이 3 V에서 충방전 전류밀도가 1C($17.5A/m^2$), 3C($52.5A/m^2$) 와 5C($87.5A/m^2$)에 대하여, 298K의 등온계와 충방전 전류밀도 별 발열계로 각각 설정하였다. 등온계와 발열계에서 모두 충방전 전류밀도가 높을수록 전지의 용량은 감소되는 것으로 나타났다. 등온계에 비하여 발열계에서 충방전 시간이 증가하였으며, 이는 발열에 의한 온도의 증가로 인해 전극의 평형전위가 감소하고, 리튬이온의 확산계수가 증가하기 때문인 것으로 고려된다. 또한, 리튬이온전지의 충전과 방전에 의한 열 발생 영향을 제어하기 위한 냉각효과를 분석하였다.