• Progress in Medical Physics
• /
• v.3 no.2
• /
• pp.23-31
• /
• 1992

The thermally stimulated luminecence (Thermoluminescence:TL) of manufactured beta-eucryptite was studied for dose range of 200cGy-20000Gy. The TL spectrum from cesium irradiated beta-eucryptite was measured over the temperature range of 300K to 600K. The linearity of TL intensity vs irradiation dose is valid up to 50Gy and beyond higher dose supralinearity and saturation come out. At the dose of 2000Gy, the net number of supralinearity is maximum. The net amount of supralinearity form newly formed trapping center by photon irradiation and totally calculated TL intensity are accord with the experimental results except for the 50Gy range that supralinearity appears.

• Journal of Food Hygiene and Safety
• /
• v.35 no.1
• /
• pp.31-36
• /
• 2020

To ensure food safety of berries from radioactive contamination, radioactivity monitoring was conducted with a total 258 samples of the berries and processed berry products distributed in Gyeonggi-do, South Korea, from 2016 to 2018. The concentration of artificial radionuclides, ¹³¹I, ¹³⁴Cs and ¹³⁷Cs, was analyzed using gamma-ray spectrometry. ¹³¹I and ¹³⁴Cs were not detected above the MDA (Minimum Detectable Activity) value from any of the samples. However, the range of radioactivity concentration of ¹³⁷Cs was 0.69-808.90 Bq/kg in 39 cases of berries. ¹³⁷Cs was detected at 0.70-3.29 Bq/kg from 6 cases of domestic berries, which were manufactured from imported raw materials. Among 33 cases of imported berries, ¹³⁷Cs was detected at 0.69-808.90 Bq/kg. The concentrations of ¹³⁷Cs in 1 case of blueberry powder product (808.90 Bq/kg) and 2 cases of lingonberry powder products (103.93, 188.46 Bq/kg) exceed domestic maximum radioactivity limits, and these were detected in the berries from Poland. These results suggest that monitoring system for imported berries and processed berry products should be continuously intensified to secure food safety.

• Korean Journal of Soil Science and Fertilizer
• /
• v.15 no.4
• /
• pp.207-212
• /
• 1982

Soils and sediments have been uniquely tagged by radioactive isotopes as a result of nuclear test explosions in the 1950's and 1960's. Fallout $^{137}Cs$ strongly fixed to fine soil particles, was measured in sediment profiles in Larto Lake to calculate the sedimentation rate as a time dependence. The Lake sediment profiles indicated an average rate of 1.6 to 3.1 cm/yr of sediment deposition since 1958. The rate of sediment depositions clearly decreased with time. Particle size distribution in sediment was reflected almost fine particles in lake.

• Clean Technology
• /
• v.22 no.2
• /
• pp.122-131
• /
• 2016

Caesium radioisotopes, ¹³⁴Cs and ¹³⁷Cs which come from the atmospheric nuclear tests and discharges from nuclear power plants, are very important to study artificial radioactivity. In this work, in order to lower the minimum detection activity (MDA) we investigated environmental radioactivity according to the Environment Measurement Laboratory procedure by ¹³⁷Cs and ¹³⁴Cs which is similar to chemical and environmental behaviors of ¹³⁷Cs. The environmental soils in high mountain areas near nuclear power plant were collected, and an Ammonium Molybdophosphate (AMP) precipitation method, which showed high selectivity toward Cs⁺ ions, was applied to chemically extract and concentrate Caesium radioisotopes. Radioactivity was estimated by a gamma-ray spectrometry. In gamma energy spectrum, with an increasing of ⁴⁰K radioactivity, it increased the MDA of ¹³⁴Cs and ¹³⁷Cs. Therefore, if the natural radionuclides were removed from the soil samples, the MDA of Caesium may be reduced, and the contents of ¹³⁷Cs of in the environmental soils can effectively be estimated. In the standard soil sample of Korea Institute of Nuclear Safety, radioactivity of ⁴⁰K was removed more than 84% on average, and the MDA of ¹³⁴Cs was reduced 2 times. The content of ¹³⁷Cs was recovered over 84%. On the other hand, in environmental soils, AMP precipitation method showed removal ratio of ⁴⁰K up to 180 times, which reduced the MDA about 5 times smaller than those of Direct method. ¹³⁷Cs recovery ratio showed from 54.54% to 70.06%. When considering the MDA and recovery ratio, AMP precipitation method is effective for detection of Caesium radioisotopes in low concentration.

• Journal of Radiation Industry
• /
• v.9 no.3
• /
• pp.127-130
• /
• 2015

Since the accident at the Fukushima Daiichi power plant, Prussian blue (PB) has attracted increasing attention as a material for use in decontaminating the environment. We have focused the fundamental mechanism of specific $Cs^+$ adsorption into PB in order to develop high-performance PB-based $Cs^+$ adsorbents. The ability of PB to adsorb Cs varies considerably according to its origin such as what synthesis method was used, and under what conditions the PB was prepared. It has been commonly accepted that the exclusive abilities of PB to adsorb hydrated $Cs^+$ ions are caused by regular lattice spaces surrounded by cyanido-bridged metals. $Cs^+$ ions are trapped by simple physical adsorption in the regular lattice spaces of PB. $Cs^+$ ions are exclusively trapped by chemical adsorption via the hydrophilic lattice defect sites with proton-exchange from the coordination water. Prussian blue are believed to hold great promise for the clean-up of $^{137}Cs$ contaminated water around nuclear facilities and/or after nuclear accidents.

• Journal of Radiation Industry
• /
• v.18 no.1
• /
• pp.89-93
• /
• 2024

Accidents at nuclear facilities and nuclear power plants led to leaks of large amounts of radioactive substances. Of the various radioactive nuclides released, ¹³⁷Cs are radioactive substances generated during the fission of uranium. Therefore, due to the high fission yield (6.09%), strong gamma rays, and a relatively long half-life (30 years), a rapid and efficient removal method and a study of adsorbents are needed. Accordingly, an adsorbent was prepared using Prussian blue (PB), a material that selectively adsorbs radioactive cesium. As a result of evaluating the adsorption performance with the prepared adsorbent, it was confirmed that 82% of the removal efficiency was obtained, and most of the cesium was rapidly adsorbed within 10 to 15 minutes. The purpose of this study was to adsorb cesium using the Prussian blue alginate bead and to compare the change in detection efficiency according to the amount of adsorbent added for quantitative evaluation. However, in this case, it is difficult to determine the detection efficiency using a standard source with the same conditions as the measurement sample, so the efficiency change of the HPGe detector according to the different heights of Prussian blue was calculated through MCNP simulation using certified standard materials (1 L, Marinelli beaker) for radioactivity measurement. It is expected to derive a relational equation that can calculate detection efficiency through an efficiency curve according to the volume of Prussian blue, quantitatively evaluate the activity at the same time as the adsorption of radioactive nuclides in actual contaminated water and use it in the field of nuclear facility operation and dismantling in the future.

• Nuclear Engineering and Technology
• /
• v.22 no.4
• /
• pp.315-325
• /
• 1990

The analytical repository source term (REPS) computer code is developed for the safety assessment of radioactive waste geologic repository. For reliable prediction of the leach rates for various radionuclides, degradation of concrete structures, corrosion rate of waste container, degree of corrosion on the container surface, and the characteristics of radionuclides are considered in this REPS code. For the validation of the radionuclide leach rates predicted by the REPS model, the calculated leach rates of Cs-137, Sr-85, and Co-60 are compared with two reported leaching test results. Cesium and strontium leach congruently, and the leaching test results of these species can be reproduced by the congruent leaching model included in the REPS model. In case of cobalt, the solid diffusion model is in good agreement with the leaching test results.

• Nuclear Engineering and Technology
• /
• v.5 no.3
• /
• pp.240-248
• /
• 1973

The present report concerns measurement of environmental radioactivity in the Ko-ri nuclear power plant site area. Gross beta measurements have been performed on soil, water, pine needle, and fallout samples collected during the period of December 1970-November 1972. Radioactivities of Strontium-90 and Cesium-137 have been measured by radiochemical analyses on samples of vegetables and marine products collected in 1972. Apparent seasonal variations and overall decrease by the year was also observed from the results of soil, pine needle, and fallout sample measurements respectively.

• Nuclear Engineering and Technology
• /
• v.49 no.3
• /
• pp.592-597
• /
• 2017

Three plastic scintillators of 4.5 cm diameter and 2.5-cm length were fabricated for comparison with commercial plastic scintillators using polymerization of the styrene monomer 2.5-diphenyloxazole (PPO) and 1,4-bis benzene (POPOP). Their maximum emission wavelengths were determined at 426.06 nm, 426.06 nm, and 425.00 nm with a standard error of 0.2% using a Varian spectrophotometer (Agilent, Santa Clara, CA, USA). Compton edge spectra were measured using three gamma ray sources [i.e., cesium 137 ($^{137}Cs$), sodium 22 ($^{22}Na$), and cobalt 60 ($^{60}Co$)]. Energy was calibrated by analyzing the Compton edge spectra. The fabricated scintillators possessed more than 99.7% energy linearity. Light output was comparable to that of the BC-408 scintillator (Saint-Gobain, Paris, France). The fabricated scintillators showed a light output of approximately 59-64% of that of the BC-408 scintillator.

• Economic and Environmental Geology
• /
• v.31 no.1
• /
• pp.11-20
• /
• 1998

The effects of the major cations ($Ca^{2+}$, $Mg^{2+}$, $K^+$, $Na^+$), complex-forming anions ($SO_4{^{2-}}$, $HCO_3{^-}$), and solution pH on the adsorption of $^{137}Cs$ and $^{90}Sr$ by kaolinite in groundwater chemistry were investigated. Three-dimensional Kd modelling designed by a statistical method was attempted to compare the relative effect among hydrated radii, charge and concentration of competing cations on the adsorption of Cs and Sr. The modelling results indicate that the hydrated radii of competing cations is the most important factor, and then their charges and concentrations are also important factors in order. The property of zeta potential of kaolinite particles was discussed in terms of the amphoteric reactions of a kaolinite surface affecting the adsorption of Cs and Sr. The ionic strength of competing cations on the adsorption of Cs and Sr exerts a greater effect than the solution pH. The sorption behaviour of Sr on kaolinite is also highly dependent on the concentration of bicarbonate. The speciation of Sr and the saturation state of a secondary phase were thermodynamically calculated by a computer program, WATEQ4F. This indicates that the change in solution pH with the concentration of bicarbonate and the precipitation of a strontianite ($SrCO_3$) are major factors controlling Sr adsorption behaviour in the presence of bicarbonate ion.