• Journal of the Korea Furniture Society
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• v.19 no.6
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• pp.452-459
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• 2008

The compressed injection yellow ocher soil is the process-technology by drying the product through sunshine, not by firing like pottery and ceramic ware. It is the technology of development being able to achieve the far infrared ray and humidity adjustment by adding recycling paper, Korean paper and bamboo salt, and it corresponds with the construction enforcement ordinance 2007 as an interior-finishing product which is fire-resistant. In case that the yellow ocher soil would be used as lighting device and interior-finishing material and decoration, it could contribute to an improvement of National Health by avoiding the sick house syndrome and adding humidity adjustment, and it has more efficient economic effect due to using recycle-available additives. Through such developments of the yellow ocher soil products the domestic market of lighting device and construction material can be advanced and the replacement effect of imported goods & also export effect can be expected accordingly.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2016.05a
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• pp.124-125
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• 2016

This study is to development of inorganic insulation material using by-product materials. The organic material is due to toxic gas emission, when a fire occurs. And it has lower water resistance. The inorganic material is heavy and worse thermal performance than organic materials.In this study, cullet and fly ash were used as basic materials in order to secure a recycling technology of by-products which was mostly discarded and reclimed, and measure of physical properties of light-weight ceramic insulator.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2016.05a
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• pp.32-33
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• 2016

In this work, pozzolanic activities of various waste materials were compared with those of well-known pozzolanic materials. Uncondensed and densified silica fume, two ASTM class F fly ashes with different calcium contents, and bentonite powder, ceramic powder obtained from wash basin, and waste glass wool, which can possibly possess pozzolanic property were chosen for comparison. Drop in electrical conductivity at 40℃ saturated lime solution was measured for each materials. The amount of Ca(OH)₂ decomposed from cement paste at 450~500℃ was also measured used to evaluate pozzolanic activity. The 28 day compressive strength were used to observe the mechanical property enhanced by various waste materials.

• Journal of Powder Materials
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• v.27 no.4
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• pp.287-292
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• 2020

The subject of this study is a zeolite generated as a by-product of recycling LAS (lithium-aluminum-silicate) resources, a kind of glass and ceramic produced by induction. The zeolite by-product is modified into Mg-zeolite using Mg as a cation to absorb Pb, a heavy metal generated from water pollution caused by recent industrial wastewater. An ion-exchange method is used to carry out the modification process, from zeolite byproduct to Mg-zeolite, and simultaneously absorb the Pb in the heavy-metal solution (99.032 mg/L). It is found that the sodium zeolite in the raw material residue can be modified to magnesium zeolite by reacting it with a mixture solution at 1 M concentration for 24 h. As a result, it is found that the residual Pb (0.130 mg/L) in the heavy metal solution is shown to be absorbed by 99.86%, with successful formation of a Mg-modified zeolite.

• Journal of the Korean Ceramic Society
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• v.39 no.3
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• pp.259-264
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• 2002

In this study, sintering properties of Artificial Lightweight aggregates(ALAs) prepared from coal ash as a function of sintering temperature (900$^{\circ}$C, 1000$^{\circ}$C, 1100$^{\circ}$C) and time (2min, 5min, 10min) when limestone added as lightweight mineral was investigated. Increasing the sintering temperature resulted simultaneously from a decline of quartz mineral as well as growth of mullite mineral. Addition of limestone to ALAs newly formed sintered minerals such as clinoptilolite and plagioclase. Sintering effect of ALAs prepared from coal ash and limestone was more affected by a sintering temperature than time. As sintering temperature and time increae, transition of macropore to micropore and formation of closed pores were happened, consequently shrank the total pore volume of ALAs. The surface of ALAs sintered at 1000$^{\circ}$C for 5min was nearly not detected open pores due toe amalgamation effect of molten slag layer but homogeneous distributions of closed pores with micro-scale were examined in cross sectional area ALAs. Sintering temperature and time which present the most adequate state, in the preparation of ALAs, are corresponded to 1000$^{\circ}$C and 5min, respectively.

• Journal of the Korean Ceramic Society
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• v.39 no.2
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• pp.178-183
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• 2002

Zinc fluosilicate ($ZnSiF_6$, 15% aqueous solution) was prepared using zinc oxide (ZnO) and fluosilicic acid ($H_2SiF_6$) by soluiton synthetic method. The fluidity and hydration properties of cement which was added $ZnSiF_6$ (aq.) as an additive for cement were studied. At water to cement ratio (W/C) equals to 0.45, the initial fluidity and slump loss of cement paste which the addition of $ZnSiF_6$ (aq.) was increased from 1.0% to 4.0% based on cement weight were investigated. Initial fluidity of cement paste was measured by mini-slump test and slump loss was examined by measuring the fluidity variation of cement paste with time elapsed from 0 min to 120 min at intervals 30 min. Also, the effect of $ZnSiF_6$ addition on the setting and hydration of cement paste when $ZnSiF_6$ increased in the addition range 1.0% to 3.0% were investigated. The fluidity of cement paste which was added 2.1% $ZnSiF_6$ (aq.) presented the highest value among all addition ranges. The setting time of cement paste was retarded gradually and the heat evolution of hydrated cement was reduced with the increasing of $ZnSiF_6$ addition.

• Korean Journal of Materials Research
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• v.25 no.2
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• pp.75-80
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• 2015

The carbon dioxide($CO_2$) released while producing building materials is substantial and has been targeted as a leading contributor to global climate change. One of the most typical method to reducing $CO_2$ for building materials is the addition of slag and fly ash, like pozzolan material, while another method is reducing $CO_2$ production by carbon negative cement development. The MgO-based cement was from the low-temperature calcination of magnesite required less energy and emitted less $CO_2$ than the manufacturing of Portland cements. It is also believed that adding reactive MgO to Portland-pozzolan cements could improve their performance and also increase their capacity to absorb atmospheric $CO_2$. In this study, the basic research for magnesia cement using $MgCO_3$ and magnesium silicate ore (serpentine) as main starting materials, as well as silica fume, fly ash and blast furnace slag for the mineral admixture, were carried out for industrial waste material recycling. In order to increase the hydration activity, $MgCl_2$ was also added. To improve hydration activity, $MgCO_3$ and serpentinite were fired at $700^{\circ}C$ and autoclave treatment was conducted. In the case of $MgCO_3$ as starting material, hydration activity was the highest at firing temperature of $700^{\circ}C$. This $MgCO_3$ was completely transferred to MgO after firing. This occurred after the hydration reaction with water MgO was transferred completely to $Mg(OH)_2$ as a hydration product. In the case of using only $MgCO_3$, the compressive strength was 3.5MPa at 28 days. The addition of silica fume enhanced compressive strength to 5.5 MPa. In the composition of $MgCO_3$-serpentine, the addition of pozzolanic materials such as silica fume increased the compression strength. In particular, the addition of $MgCl_2$ compressive strength was increased to 80 MPa.

• Journal of the Korea Institute of Building Construction
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• v.22 no.3
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• pp.251-258
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• 2022

In the cement industry, in order to reduce CO₂ emissions, technology for raw materials substitution and conversion, technology for improving process efficiency of utilizing low-carbon new heat sources, and technology for collecting and recycling process-generated CO₂ are being developed. In this study, we conducted a basic experiment to contribute to the development of CSC that can store CO₂ as carbonate minerals among process-generated CO₂ capture and recycling technologies. Three types of CSC clinker with different SiO₂/(CaO+SiO₂) molar ratios were prepared with the clinker raw material formulation, and the characteristics of the clinker were analyzed. As a result of analysis and observation of CSC clinker, wollastonite and rankinite were formed. In addition, as a result of the carbonation test of the CSC paste, it was confirmed that calcite was produced as a carbonation product. The lower the SiO₂/(CaO+SiO₂) molar ratio in the CSC clinker chemical composition, the lower the wollastonite production amount, and the higher the rankinite production amount. And the amount of calcite production increased with the progress of carbonation of the CSC paste specimen. It is judged that rankinite is more reactive in mineralizing CO₂ than wollastonite.

• Resources Recycling
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• v.19 no.3
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• pp.9-15
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• 2010

Domestic gold mine tailings, generally, contain a lot of non-metallic silica and clay minerals. These minerals can be separated from the tailings by various physical separation methods and used as raw materials for cements and ceramic products. In these physical separation procedures, metallic complex sulfides, in which Au and metallic constituents such as Pb, As and Fe were concentrated, were obtained as a by-product. These metallic constituents should be removed or separated from the by-product to extract Au efficiently. In this work, removal and separation processes of Pb, As, and Fe from the by-product were investigated. Pb was removed to under 3% by using alkaline oxidative leaching at the leaching condition of $120^{\circ}C$, 2M NaOH, 100psi $Po_2$, 250r.p.m., 4 wt.% solid and 30 min. leaching time. The leached residue was roasted and separated magnetically to obtain a non-magnetic product contained <0.2% As, <3% Fe and high concentrated Au more than 8,000 ppm.

• Resources Recycling
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• v.24 no.6
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• pp.38-44
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• 2015

It studies that effect of limestone of physicochemical characteristic on the performance of flue gas desulfurization (FGD) and application examination for technology of wet type FGD process and to utilize the limestone in Donghae-Samcheok. The experiment method was measured total neutralizing capability (TNC) using the lab scale experimental apparatus based on the HCl titration test. The results of TNC of limestone samples were more dependent on the physical characteristics including particle size rather than chemical compositions such as CaO content and particle size of limestone get smaller, TNC is increased.