• Title/Summary/Keyword: Ceramic products

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Synthesis of Hydroxyapatite Powders by Homogeneous Precipitation Method and Their Thermal Changes (균일침전법을 이용항 Hydroxyapatite 분말의 제조 및 가열변화)

  • Lee, Jin-Ho;Park, Hoon;Kim, Chang-Eun
    • Journal of the Korean Ceramic Society
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    • v.33 no.1
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    • pp.7-16
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    • 1996
  • ${CO_3}^{2-}$ containing whisker-like hydroxyapatite powders were synthesized byhomogeneous precipitation method using urea, Dicalcium phosphate anhdrate[DCPA; $CaHPO_4$] and octacalcium phosphate [OCP; $Ca_8H_2(PO_4_)6\cdot5H_20$]were obtained as precursors and they transformed to high crystalline hydroxyapatites at pH 5.62, and 6.54 respectively. According to the condition of the final pH in the solutions for the solution products and urea contents OCP was remained. When the solution product of $Ca^{2-}$ and ${PO_4}^{3-}$ was $1.5\times 10^4$[$mM^2$] and the content of urea was 0.25 mol.$dm^{-3}$ well crystallized whisker-like hydroxyapatite tens of micrometer in length was obtained. By heat treatment DCPA and OCP were decomposed into $\beta$-tricalcium phosphate [$\beta$-TCP ; $\beta$-$Ca_3{PO_4}_2$] and $\beta$-dicalcium phosphate [$\beta$-DCP ;$\beta$-$Ca_2P_2O_4}_2$]. And well-crystallized hydroxyapatite was partially decomposed into $\beta$-TCP at $800^{\circ}C$.

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The Properties of Synthetic Calcium Ferrite for Ironmaking and Steelmaking using Industrial By-products - (2) (산업부산물을 활용한 제철·제강용 합성 칼슘 페라이트 특성 - (2))

  • Park, Soo Hyun;Chu, Yong Sik;Seo, Sung Kwan;Park, Jae Wan
    • Resources Recycling
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    • v.23 no.5
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    • pp.12-20
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    • 2014
  • Calcium ferrite is a major bonding material self-fluxed sintered ore, and it is used as a flux in the steelmaking process. Calcium ferrite is more effective binder for making sintered ore and flux for steel making because of it's low melting temperature. In this Study, calcium ferrite was made by using variety industrial by-products from steel plant. The property of calcium ferrites was investigated on the basis of test method using in the cement manufacturing process. Crystal analysis, compression test as well as thermal analysis were carried out to evaluate physical properties of calcium ferrite.

The Oxygen Potential of Urania Nuclear Fuel During Irradiation

  • Park, Kwang-Heon
    • The Korean Journal of Ceramics
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    • v.4 no.2
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    • pp.72-77
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    • 1998
  • A defect model for UO$_2$ fuel containing soluble fission products was devised based on the defect structure of pure and doped uranias. Using the equilibrium between fuel solid-solution and fission-products and the material balance within the fuel, a tracing method to get the stoichiometry change of urania fuel with burnup was made. This tracing method was applied to high burnup urania fuel and DUPIC fuel. The oxygen potential of urania fuel turned out to increase slightly with burnup. The stoichiometry change was calculated to be negligible due to the buffering role f Mo. The oxygen potential of DUPIC fuel out to be sensitive to the initial chemical state of Mo in the fuel.

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Loose and Dense Aggregate Particle Packing Models in Cement and Concrete

  • Kim, Jong-Cheol;Lim, Chang-Sung;Auh, Keun-Ho
    • The Korean Journal of Ceramics
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    • v.6 no.1
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    • pp.1-5
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    • 2000
  • Particle packing properties are important to develop high technology products in the field of cement and concrete. Two types of particle packing models for aggregates with sand and cement were introduced: the loose and the dense aggregate packing. Aggregate packing models with randomly generated sand and cement particles in the interstices of aggregates fit the Furnas model very well. Different aggregate models show different packing properties with the experimental results. Main reason for the difference with the experimental results is due to sand rearrangement in the loose aggregate packing model and to aggregate relaxation in the dense aggregate packing model. In the experimental situation, aggregates seem to be more disordered and have a relaxed packing structure in the dense packing, and sands seem to have a more rearranged packing structure in the loose packing model.

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Characteristics of Porous Wollastonite Ceramics Fabricated by Hydrothermal Synthesis (수열 합성에 의해 제조된 다공성 Wollastonite Ceramics의 특성)

  • 김병훈;나용한
    • Journal of the Korean Ceramic Society
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    • v.32 no.8
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    • pp.893-900
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    • 1995
  • The porous wollastonite ceramics were fabricated after firing calcium silicates, obtained using natural resources and by-products of power plants by hydrothermal synthesis, without organic fibers or asbestos for reinforcement agent. A specimen from diatomite as a SiO2 staring raw material had the highest strength owing to normal grain growth and good densification from homogeneous sperhcial C-S-H hydrates. A specimen from SiO2 sol as a SiO2 starting raw material showed tobermolite, but fly ash and mixed system did xonotlite after hydrothermal synthesis. The specimen from fly ash showed the lowest firing shirikage and strength changes in the firing range from 50$0^{\circ}C$ to 120$0^{\circ}C$. The other phases in all specimens changed to wollastonite phase after firing at 100$0^{\circ}C$. Also the average pore size was distributed from 0.2${\mu}{\textrm}{m}$ to 2${\mu}{\textrm}{m}$.

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An Improved Density and Heat insulation of Light-weight Ceramic Insulator Using Cullet and Fly-ash (밀도 및 단열성능이 개선된 경량 세라믹 단열재의 물성)

  • Shin, Hyeon-Uk;Song, Hun;Chu, Yong-Sik;Lee, Jong-Kyu
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2015.05a
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    • pp.90-91
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    • 2015
  • Heat insulator materials can be classified inorganic and organic. The organic material is due to toxic gas emission, when a fire occurs. And it has lower water resistance. The inorganic material is heavy and worse thermal performance than organic materials. In this study, cullet and fly ash were used as basic materials in order to secure a recycling technology of by-products which was mostly discarded and reclimed, and measure of physical properties of light-weight ceramic insulator.

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Manufacturing Technique of Light-weight Ceramic Insulator Using Cullet and Fly-ash (유리분말과 플라이애시를 사용한 경량 세라믹 단열재 제조)

  • Shin, Hyeon-Uk;Song, Hun;Chu, Yong-Sik;Lee, Jong-Kyu
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2014.11a
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    • pp.180-181
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    • 2014
  • Heat insulator materials can be classified inorganic and organic. The organic material is due to toxic gas emission, when a fire occurs. And it has lower water resistance. The inorganic material is heavy and worse thermal performance than organic materials. In this study, cullet and fly ash were used as basic materials in order to secure a recycling technology of by-products which was mostly discarded and reclimed, and measure of physical properties of light-weight ceramic insulator.

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Rheological behavior and ink-jet printing characteristics of aqueous ceramic complex ink (수계 세라믹 복합잉크의 유변학적 거동 및 잉크젯 프린팅 특성)

  • Kwon, Jong-Woo;Lee, Jong-Heun;Hwang, Kwang-Taek;Kim, Jin-Ho;Han, Kyu-Sung
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.28 no.3
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    • pp.123-129
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    • 2018
  • Ink-jet printing technology with ceramic ink of the four digital primary colors (cyan, magenta, yellow, and black; CMYK) can provide stable coloration even in the high-temperature firing process. Ceramic ink-jet printing can be widely applied in construction and ceramic industries due to the advantages of accurate and fast printing process of digital images for various products. Generally, organic solvent with proper viscosity and surface tension has been used in digital ink-jet printing process. However, the needs of ceramic ink without VOCs emission is increasing. In the present study, eco-friendly ceramic ink was synthesized by combining alumino boro-silicate glass frit and $CoAl_2O_4$ inorganic pigment based on an aqueous solvent that does not generate VOCs. The rheological properties and dispersion stability of aqueous ceramic ink were optimized. Jetting behavior and printing characteristics of the ceramic ink were also investigated in detail. As a result, the formulated aqueous ceramic complex ink showed a suitable jetting behavior without satellite drop by adjusting viscosity and surface tension. The ceramic ink can be printed on glass substrate with minimized spreading phenomena duo to high contact angle.

The concentrations of airborne dust in non-metallic products factories and problems associated with the application of the occupational exposure limits (비금속광물 제품제조업에서 발생하는 분진 농도와 분진 노출기준 적용에 따른 문제점 고찰)

  • Kim, Hyunwook;Phee, Young Gyu;Won, Jung Il;Ko, Won Kyung;Roh, Young Man;Shin, Chang Sub
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.10 no.1
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    • pp.104-114
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    • 2000
  • This study was carried out to estimate current status of dust concentrations in the factories producing non-metallic products in Korea. Data were gathered from the environmental monitoring reports by 40 workplace environmental monitoring institutes and the questionnaire designed for the study by the authors. A total of 1838 dust samples from 368 plants were obtained from the reports and were analyzed with no data modifications. But data on asbestos, rock wool, and welding fumes were excluded in this evaluation. The factories were classified into eight groups according to the standard industrial classification scheme in Korea. The results of this study were as follows; 1. The factories included were glass, non-refractory ceramic, refractory ceramic ware, structural non-refractory clay and ceramic, cement and lime, articles of concretes, and stone. Mean(geometric mean) concentrations of total dust samples ranged from $1.75(0.84)mg/m^3$ to $5.87(2.84)mg/m^3$. Statistically significantly higher dust concentrations were found in the cement and lime industries compared with other industries. 2. The non-compliance rates were 15.2% in glass and 20.6% in other non-metallic mineral products industries. Although all institutions surveyed utilized the identical sampling and classification scheme for dusts as specified in the current occupational exposure limits, wide discrepancies were found in collecting samples and classifying dusts. Further problems were discovered in classifying dusts. A dust sample collected could be classified into any of the three groups regardless of silica content. The results of this study showed that dust concentrations in the non-metallic products industries varied widely. Also discovered was classification errors of dust types among workplace monitoring institutes. These errors could adversely affect the results of exposure assessments and the true nature of dust hazards. Further, no institutions performed respirable dust sampling and analysis of crystalline silica. In order to correct these malpractices, current standards of occupational exposure limits should be revised and tight supervision by the Ministry of Labour be suggested.

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