• 공업화학
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• 제24권6호
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• pp.611-615
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• 2013

본 연구에서는 바나듐 산화물($VO_2$)과 텅스텐이 도핑된 바나듐 산화물(W-$VO_2$) 분말을 바나듐 산화물($V_2O_5$)과 옥살산수화물로부터 수열합성과 하소공정을 통하여 성공적으로 제조하였다. 시료들의 결정구조와 열변색 특성들은 FE-SEM, XRD, XPS, DSC 및 UV-Vis-NIR 분광기를 이용하여 분석하였다. W-$VO_2$ 시료에 W의 도핑량을 증가시키면, W-$VO_2$ 시료의 상전이 온도가 $70^{\circ}C$에서 $42^{\circ}C$로 낮아지는 경향이 있었다. 또한, W-$VO_2$ 시료를 상전이 온도 이상으로 가열시키면 UV-Vis-NIR 곡선이 가시광 영역에서는 변하지 않고 NIR 영역에서는 낮은 투과도 방향으로 이동하는 경향이 있었다.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2000년도 추계학술대회 논문집 학회본부 C
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• pp.479-481
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• 2000

The effect of $Al_{2}O_{3}+Y_{2}O_{3}$ additives on fracture toughness of $\beta-SiC-TiB_2$ composites by hot-pressed sintering were investigated. The f$\beta-SiC-TiB_2$ ceramic composites were hot-presse sintered and annealed by adding 16, 20, 24wt% $Al_{2}O_{3}+Y_{2}O_{3}$(6 : 4wt%) powder as a liquid forming additives at low temperature($1800^{\circ}C$) for 4h. In this microstructures, the relative density is over 95.88% of the theoretical density and the porosity increased with increasing $Al_{2}O_{3}+Y_{2}O_{3}$ contents because of the increasing tendency of pore formation. The fracture toughness showed the highest of $5.88MPa{\cdot}m^{1/2}$ for composites added with 20wt% $Al_{2}O_{3}+Y_{2}O_{3}$ additives at room temperature. The electrical resistivity showed the lowest of $5.22{\times}10^{-4}\Omega{\cdot}cm$ for composite added with 20wt% $Al_{2}O_{3}+Y_{2}O_{3}$ additives at room temperature and is all positive temperature coefficient resistance (PTCR) against temperature up to $700^{\circ}C$.

• Macromolecular Research
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• 제12권4호
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• pp.399-406
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• 2004

Glass-like carbon precursors shrink significantly during curing and carbonization, which leads to crack formation and bending. Cured furan resin powder and ethanol were added to furan resin to diminish the weight loss, to suppress the shrinkage and bending, and to readily release the gases evolved during polymerization and curing. Curing and carbonization were controlled by pressure and slow heating to avoid damage to the samples. The effect of the filler and ethanol on the fabrication process was examined by measuring the properties of the glass-like carbon, such as the specific gravity, bending strength, electrical resistivity, and microstructural change. The specific gravities of the filler-added glass-like carbons were higher than those of the ethanol-added samples because of the formation of macropores from the vaporization of ethanol during the curing and polymerization processes. Although the ethanol-added glass-like carbons exhibited lower bending strengths after carbonization than did the filler-added samples, the opposite result was observed after aging at 2,600$^{\circ}C$. We found that the macropores created from ethanol were contracted and removed upon heat treatment. The electrical resistivity of the glass-like carbon aged at 2,600$^{\circ}C$ was lower than those of the samples carbonized at 1,000$^{\circ}C$. We attribute this phenomenon to the fact that aging at high temperature led to well-developed microstructures, the removal of macropores, and the reduction of the surface area.

• 한국재료학회지
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• 제24권2호
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• pp.98-104
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• 2014

Vacuum kinetic spray(VKS) is a relatively advanced process for fabricating thin/thick and dense ceramic coatings via submicron-sized particle impact at room temperature. However, unfortunately, the particle velocity, which is an important value for investigating the deposition mechanism, has not been clarified yet. Thus, in this research, VKS average particle velocities were derived by numerical analysis method(CFD: computational fluid dynamics) connected with an experimental approach(SCM: slit cell method). When the process gas or powder particles are accelerated by a compressive force generated by gas pressure in kinetic spraying, a tensile force generated by the vacuum in the VKS system accelerates the process gas. As a result, the gas is able to reach supersonic speed even though only 0.6MPa gas pressure is used in VKS. In addition, small size powders can be accelerated up to supersonic velocity by means of the drag-force of the low pressure process gas flow. Furthermore, in this process, the increase of gas flow makes the drag-force stronger and gas distribution more homogenized in the pipe, by which the total particle average velocity becomes higher and the difference between max. and min. particle velocity decreases. Consequently, the control of particle size and gas flow rate are important factors in making the velocity of particles high enough for successful deposition in the VKS system.

• 구강회복응용과학지
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• 제32권3호
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• pp.246-254
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• 2016

Direct metal laser sintering (DMLS) 방식은 3D 프린팅 중 한 방식으로, 재료를 쌓아가면서 레이저를 이용하여 선택적으로 sintering하는 방식이다. 이는 주조 방식에서 문제되는 결손과 뒤틀림을 방지할 수 있으며 절삭 가공 방식으로 제작하기 어려운 복잡한 구조물을 제작할 수 있다. 본 증례들은 DMLS 방식을 이용하여 지대치 간 길이가 긴 고정성 보철물, 포스트 등 다양한 고정성 보철물을 제작하여 수복하였고, 주기적인 관찰 결과 심미적, 기능적으로 만족할만한 결과를 얻었기에 이를 보고하는 바이다.

• 한국결정성장학회지
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• 제3권2호
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• pp.176-184
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• 1993

$Li_2O-Al_2O_3-SiO_2$계 유리조성에서, 특히 주결정상으로 $\beta$-spodumene을 석출시킬 수 있는 조성영역에서 $P_2O_5, TiO_2, ZrO_2$ 등을 첨가하여 용융한 후 소결법을 이용하여 이론밀도에 가까운 결정화 유리를 만들기 위한 최적 열처리 조건, 유리 분말의 입도 변화에 따란 영향과 그 때의 물성을 시차열분석, X-선 회절분석, 비중 측정, 열팽창 측정, 전자현미경 관찰 등을 통하여 연구하였다. $P_2O_5$를 첨가하여 소결법으로 결정화할 때 소결을 증진시키는 효과가 있었으며 9wt% 첨가한 경우가 가장 치밀한 것으로 나타났다. 최적의 열처리 조건은 $740^{\circ}C$에서 소결하여 치밀화를 시키고$ 950^{\circ}C$에서 결정화를 시켰을 때로서 상대밀도는 90% 이상이었으며 열팽창계수는 $-1{\times}10^{-7}/^{\circ}C$ 정도로서 부팽창인 것으로 나타났다.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1999년도 춘계학술대회 논문집
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• pp.291-294
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• 1999

The effect of AI$_2$O$_3$+Y$_2$O$_3$additives on fracture toughness of $\beta$-SiC-ZrB$_2$composites by hot-pressed sintering were Investigated. The $\beta$-SiC-ZrB$_2$ ceramic composites were hot-presse sintered and annealed by adding 1, 2, 3wt% AI$_2$O$_3$+Y$_2$O$_3$(6:4wt%) powder as a liquid forming additives at 195$0^{\circ}C$ for 4h. In this microstructures, no reactions were observed between $\beta$-SiC and ZrB$_2$, and the relative density Is over 90.79% of the theoretical density and the porosity decreased with increasing AI$_2$O$_3$+Y$_2$O$_3$ contents. Owing to crack deflection and crack bridging of fracture toughness mechanism, the fracture toughness showed the highest of 5.5328MPa . m$^{1}$2/ for composites added with 2wt% AI$_2$O$_3$+Y$_2$O$_3$ additives at room temperature. But the standard deviation of fracture toughness of specimens decreased with increasing AI$_2$O$_3$+Y$_2$O$_3$ contents and showed the highest of 0.8624 for composite tilth 1wt%, AI$_2$O$_3$+Y$_2$O$_3$additives.

• 한국식품저장유통학회지
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• 제5권4호
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• pp.331-334
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• 1998

기능성 MA필름을 생산하여 이를 골판지 상자의 내부에 첨합시킨 FC상자의 활용가능성을 조사하고자 골판지 상자와 기능성 MA필름대를 골판지 상자 내부에 첨합시킨 FC포장구와 LDPE 및 기능성필름과 대조구로 골판지 상자만으로 포도를 포장하여 25 C에 저장하여 품질변화를 조사한 결과, FC 상자와 LDPE와 CE포장구는 대조구 보다는 중량감소율이 현저히 낮았으며 비타민C의 함량도 33% 높게 유지되고 있었다. 산도와 환원당 함량은 포장구들간에는 큰차이가 없었다. 외관 및 부패를 조사한 결과 대조구에 비해 개발포장구에서 품질이 더 높게 유지되고 있어 FC 포장재를 포도 포장용 상자로 활용가능성이 확인되었다.

• 한국수소및신에너지학회논문집
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• 제24권1호
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• pp.29-35
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• 2013

A dense mixed ionic and electronic conducting ceramic membrane is one of the most promising materials because it can be used for separation of oxygen from the mixture gas. The $ABO_3$ perovskite structure shows high chemical stability at high temperatures under reduction and oxidation atmospheres. $BaCo_{1-x-y}Fe_xZr_yO_{3-{\delta}}$ (BCFZ) was well-known material as high mechanical strength, low thermal conductivity and stability in the high valence state. Glycine Nitrate Process (GNP) is rapid and effective method for powder synthesis using glycine as a fuel and show higher product crystallinity compared to solid state reaction and citrate-EDTA method. BCFZ was fabricated by modified glycine nitrate process. In order to control the burn-up reaction, $NH_4NO_3$ was used as extra nitrate. According to X-Ray Diffraction (XRD) results, BCFZ was single phase regardless of Zr dopants from y=0.1 to 0.3 on B sites. The green compacts were sintered at $1200^{\circ}C$ for 2 hours. Oxygen permeability, methane partial oxidation rate and hydrogen production ability of the membranes were characterized by using Micro Gas Chromatography (Micro GC) under various condition. The high oxygen permeation flux of BCFZ 1-451 was about $1ml{\cdot}cm^{-2}s^{-1}$. Using the humidified Argon gas, BCFZ 1-433 produced hydrogen about $1ml{\cdot}cm^{-2}s^{-1}$.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2000년도 하계학술대회 논문집
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• pp.873-876
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• 2000

Characteristics of piezoelectric thick films prepared by screen printing method were investigated. The piezoelectric thick films were printed using Pb(Mg,Nb)O$_3$-Pb(Zr,Ti)O$_3$system. The lower electrodes were coated with various thickness of Ag-Pd by screen printing to investigate the effect as a diffusion barrier and deposited with Pt by sputtering on Ag-Pd. The ceramic paste was prepared by mixing powder and binder with various ratios using three roll miller. The fabricated thick films were burned out at 650$^{\circ}C$ and sintered at 950$^{\circ}C$ in the O$_2$condition for each 20, 60min after printing with 350mesh screen. The thickness of piezoelectric thick film was 15∼20 $\mu\textrm{m}$ and the Ag-Pd electrode acted as a diffusion barrier above 3 $\mu\textrm{m}$ thickness. When the lower electrode Ag-Pd was 6 $\mu\textrm{m}$ and the piezoelectric thick films were sintered by 2nd step (650$^{\circ}C$/20min and 950$^{\circ}C$/1h) using paste mixed Pb(Mg,Nb)O$_3$-Pb(Zr,Ti)O$_3$$.$ MnO$_2$+ Bi$_2$O$_3$. V$_2$O$\_$5/ and binder in the ratio of 70:30, the remnant polarization of thick film was 9.1 ${\mu}$C /cm$^2$.