• Title/Summary/Keyword: Ceramic Particle

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Enhancement of Oxygen and Moisture Permeability with Illite-Containing Polyethylene Film

  • Seong, Dong Min;Lee, Hyesun;Chang, Jeong Ho
    • Journal of the Korean Ceramic Society
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    • v.56 no.6
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    • pp.601-605
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    • 2019
  • This work reports the preparation of ceramic hybrid films with illite-polyethylene composites analyzed as a function of concentration of added illite in polyethylene. The enhancement of oxygen and water-vapor transmission rate of illite-polyethylene film was evaluated to determine its influence on the freshness in fruit packaging. Particle size of illite materials was controlled in the range of 1~10 ㎛ and then mixed with LDPE to form the masterbatch. Ceramic hybrid films were prepared through a blown film making process. To determine the dispersity and abundancy of illite materials in the polyethylene matrix, various characterizations of illite-PE hybrid masterbatch and films were performed using SEM, TGA, and FT-IR. The oxygen and water-vapor transmission rate of illite-polyethylene film was found to be two times higher than that of LDPE film.

Sintering and Characterization of SiC-matrix Composite Including TRISO Particles (TRISO 입자를 포함하는 SiC 복합소결체의 소결 및 특성 평가)

  • Lee, Hyeon-Geun;Kim, Daejong;Park, Ji Yeon;Kim, Weon-Ju
    • Journal of the Korean Ceramic Society
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    • v.51 no.5
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    • pp.418-423
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    • 2014
  • Fully ceramic micro encapsulated (FCM) nuclear fuel is a concept recently proposed for enhancing the stability of nuclear fuel. FCM nuclear fuel consists of tristructural-isotropic (TRISO) fuel particles within a SiC matrix. Each TRISO fuel particle is composed of a $UO_2$ kernel and a PyC/SiC/PyC tri-layer which protects the kernel. The SiC ceramic matrix is created by sintering. In this FCM fuel concept, fission products are protected twice, by the TRISO coating layer and by the SiC ceramic. The SiC ceramic has proven attractive for fuel applications owing to its low neutron-absorption cross-section, excellent irradiation resistivity, and high thermal conductivity. In this study, a SiC-matrix composite containing TRISO particles was sintered by hot pressing with $Al_2O_3-Y_2O_3$ additive system. Various sintering conditions were investigated to obtain a relative density greater than 95%. The internal distribution of TRISO particles within the SiC-matrix composite was observed using an x-ray radiograph. The fracture of the TRISO particles was investigated by means of analysis of the cross-section of the SiC-matrix composite.

Thermal Decomposition Synthesis of CoSb3 Nanoparticle by Hot Injection Method (열분해와 Hot Injection법을 이용한 CoSb3 나노분말합성)

  • Kim, Min-Suk;Ahn, Jong-Pil;Kim, Kyung-Ja;Park, Joo-Seok;Kim, Kyoung-Hun;Kim, Hyung-Sun
    • Journal of the Korean Ceramic Society
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    • v.50 no.6
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    • pp.476-479
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    • 2013
  • $CoSb_3$ with its high electrical conductivity, Seebeck coefficient and rather low thermal conductivity is quite a promising material for thermoelectric conversion applications. A potentially high figure of merit (ZT) can be achieved by a nanostructure evolution of thermoelectric materials. In this work, $CoSb_3$ nanoparticles were synthesized through a thermal decomposition method in cooperation with a hot injection technique. Nano-sized $CoSb_3$ particles were obtained through the thermal decomposition reaction between the pre-heated cobalt-oleate at $320^{\circ}C$ and the injected antimony oleate with room temperature. The results showed that the particle size was increased with increasing synthesis temperature and the crystallinity of particles was improved with temperature but the decomposition of $CoSb_3$ was observed at $320^{\circ}C$. The $CoSb_3$ particles synthesized at $300^{\circ}C$ showed a high purity and an homogeneous shape with average particle size of 26 nm.

Regression Analysis on the Effect of Compressive Grinding of Cement Raw Materials and Clinker Granule

  • Kim, Jong-Cheol;Auh, Keun-Ho
    • The Korean Journal of Ceramics
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    • v.6 no.2
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    • pp.96-99
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    • 2000
  • Particle size of the cement raw materials is important not only in clinker burning but also in cement productivity. Model experiment was designed to investigate the effect of compressive grinding on cement raw materials and clinker granule. Compressive grinding was more efficient in reducing hard materials like quartz. Regression model was constructed to explain the effect of compressive grinding on the size reduction of cement raw materials and clinker.

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Fabrication and Piezoelectric Strain Characteristics of PLZT Functionally Gradient Piezoelectric Actuator by Doctor Blade Process (닥터블레이드법에 의한 PLZT계 경사기능 압전 엑튜에이터의 제조와 압전 변위 특성)

  • 김한수;최승철;이전국;정형진
    • Journal of the Korean Ceramic Society
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    • v.29 no.9
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    • pp.695-704
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    • 1992
  • In (Pb, La)(Zr, Ti)O3 ceramic system, the functionally gradient material (FGM) was developed, and its processing and properties were investigated. The FGMs were successfully prepared through doctor blade method with acrylic binder system as well as mold stacking press method. The ultrasonic treatment was very effective for particle dispersion in slurry, and it lead to form clack-free green films. The strain-voltage characteristics of the FGM system was significantly improved which fabricated between a high piezoelectric-low dielectric and a low piezoelectric-high dielectric composition layer.

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Fabrication of Ag doped Hydroxyapatite and its Antimicrobial Effects with the Particle Size

  • Oh, Kyung-Sik;Kim, Kyung-Ja;Jeong, Young-Keun
    • Journal of Powder Materials
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    • v.8 no.3
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    • pp.192-196
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    • 2001
  • Ag doped Hydroxyapatite powder in nano-scale was successfully synthesized either by co-precipitation or by ion exchange route. The fabricated powder was successfully dispersed through freeze drying due to the prevention of secondary particles. The antimicrobial effects of nano-HAp against E.coli was superior to micron ones not only in its strength but also in duration.

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Characteristics of $\alpha$-$Fe_2O_3$ Thick Film Fabricated by Screen Printing Method

  • Kim, Byung-Soo;Chung, Yong-Sun;Auh, Keun-Ho
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 1998.09a
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    • pp.65-70
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    • 1998
  • Fine powders of $\alpha$-Fe2O3 were prepared by precipitation method using iron (III) nitrate in ethanol solvent and the thick film using this powder was made by the screen printing technology. Effects of the reaction temperature and concentration of the iron (III) nitrate on the particle size and specific surface area were studied. Also, the relationship between the powder size and properties of the thick film was discussed.

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The Kinetics of Volatilization of P2O5 From Sol-Gel Derved Phosphosilicate Glass-Ceramic Powder (졸-겔법으로 제조된 Phosphosilicate 유리-요업체 분말로부터 $P_2O_5$ 휘발 반응 속도론)

  • ;Richard E, Tressler
    • Journal of the Korean Ceramic Society
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    • v.29 no.2
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    • pp.89-94
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    • 1992
  • The kinetics of volatilization of phosphorous oxide from phosphosilicate glassceramic powders prepared by a sol-gel process were investigated at a given temperature. The rate of P2O5 vaporization increased with the P2O5 concentration in the phosphosilicate powder. Vaporization from the powder containing 46% P2O5 was analyzed using a kinetic model for diffusion limited evaporation. The diffusion through phosphosilicate glass in the surface of each particle in the temperature range 800~85$0^{\circ}C$ are presented.

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Effect of Variation in Particle Size of WC and Co Powder on the Properties of WC-Co Alloys (WC와 Co원료 입자크기 변화에 따른 WC-Co계 초경합금의 특성 변화)

  • Chung, Tai-Joo;Ahn, Sun-Yong;Paek, Yeong-Kyeun
    • Journal of the Korean Ceramic Society
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    • v.42 no.3 s.274
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    • pp.171-177
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    • 2005
  • The effect of variation in particle size of WC and Co powder on the properties of WC-Co alloys was investigated. WC and Co powders having different particle sizes were used in the fabrication of $WC-10\;wt\%$Co composites. High hardness and low fracture toughness alloy was obtained with the decrease in WC particle size regardless of Co particle size. It was newly found in this investigation that the initial particle size of Co as well as WC had a great role in the microstructure and properties of WC-Co hard materials. The average grain size and fracture toughness of WC-Co alloys using same WC powder size increased and their hardness decreased with the use of relatively finer Co binder.

Measurement of Coarse Particle Mass in Alumina Powders Using Wet Sieve Method (습식 체분리법을 이용한 알루미나분말 중의 조대입자 함량평가)

  • Jung, Sang-Jin;Lim, Hyung-Mi;Lee, Seung-In;Kim, Young-Hee;Kim, Soo-Ryong;Cho, Yong-Ick
    • Journal of the Korean Ceramic Society
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    • v.39 no.8
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    • pp.775-782
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    • 2002
  • The effects of solid and dispersant concentration was investigated by wet-sieving method for knowing the amount of coarse particle in fine powders. In the work alumina powders, sodium hexametaphosphate and sodium polyacrylate were used for preparing slurry. It was confirmed that the coarse particle mass increased by increasing alumina concentration and decreasing dispersant concentration. With systematic measurements we know that the alumina powder and dispersant of one weight percent(1.0wt%) were proper quantity for coarse particle mass measuring, respectively. Sodium polyacrylate as dispersant showed higher coarse particle mass than sodium hexametaphosphate. The sieve mass was decreased according to increase of experiment number. Based on experiments it was considered that wet-sieving method is good tool for measuring a coarse particle mass in fine powders.