• Title/Summary/Keyword: Center Segregation

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A Study of Hydrogen-Induced Metal Atom Rearrangement

  • Noh, Hak;Park, Choong-Nyeon;Flanagan, Ted B.
    • Transactions of the Korean hydrogen and new energy society
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    • v.7 no.1
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    • pp.111-115
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    • 1996
  • Metal atom rearrangement has been shown to take place under the influence of hydrogen-induced atomic diffusion (HIAD) in initially homogeneous fee palladiumalloys by electron microprobe analysis, optical microscopy, mechanical property tests and hydrogen isotherms. HIAD takes place in palladium alloys at moderate to elevated temperatures leading to phase segregation under conditions where segregation does not normally occur, i.e., in the absence of H over the time scale of the experiments. From these results, it is confirmed that dissolved hydrogen plays a dual role in some of these alloys, i.e. it catalyzes metal atom diffusion. This research demonstrates the potential utility of employing H-induced changes for phase diagram determination of Pd alloys and possibly for other alloy system.

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UBV CCD PHOTOMETRY OF INTERMEDIATE AGE OPEN CLUSTER M11 I. STATISTICAL ANALYSIS

  • SUNG HWANKYUNG;LEE SEE-WOO;LEE MYUNG GYOON;ANN HONG BAE
    • Journal of The Korean Astronomical Society
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    • v.29 no.2
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    • pp.269-278
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    • 1996
  • We present the color-magnitude diagrams (CMD) of more than 24,000 stars in the field of an intermediate age open cluster M11, based on wide field CCD imaging. The morphology of the CMDs varies strikingly as the distance from the center of the cluster increases. From the surface number density analysis, we confirm the mass segregation effect in this cluster: the bright, massive stars are centrally more concetrated than the faint, low mass stars. The slope of the field-corrected surface density with respect to magnitude progressively increases as the radius increases, up to r = 5'. Most of the field stars in or near the cluster main sequence band and in the bright part of the red stars in the CMDs appear to be nearly at the same distance as M11, and they are considered to be the major component of disk stars in the Sagittarius-Carina arm.

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Intergranular Corrosion of 316L Stainless Steel by Aging and UNSM (Ultrasonic Nano-crystal Surface Modification) treatment (시효열처리 및 UNSM 처리에 따른 316L 스테인리스강의 입계부식거동)

  • Lee, J.H.;Kim, Y.S.
    • Corrosion Science and Technology
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    • v.14 no.6
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    • pp.313-324
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    • 2015
  • Austenitic stainless steels have been widely used in many engineering fields because of their high corrosion resistance and good mechanical properties. However, welding or aging treatment may induce intergranular corrosion, stress corrosion cracking, pitting, etc. Since these types of corrosion are closely related to the formation of chromium carbide in grain boundaries, the alloys are controlled using methods such as lowering the carbon content, solution heat treatment, alloying of stabilization elements, and grain boundary engineering. This work focused on the effects of aging and UNSM (Ultrasonic Nano-crystal Surface Modification) on the intergranular corrosion of commercial 316L stainless steel and the results are discussed on the basis of the sensitization by chromium carbide formation and carbon segregation, residual stress, grain refinement, and grain boundary engineering.

Microstructural Features of Al Alloy 7N01 Welded by $CO_2$ Laser - Microsturctural Features of Full Penetration Joints - ($CO_2$ 레이저 용접한 7N01 Al합금의 미세조직 특징(I) - 완전용입 용접부의 미세조직 -)

  • 윤재정;강정윤;김인배;김대업
    • Journal of Welding and Joining
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    • v.19 no.4
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    • pp.429-436
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    • 2001
  • The effect of welding condition on the microstructures of the weld metal in A7N01 welded by $CO_2$ laser was investigated. The number of ripples was increased with decreasing power and increasing welding speed. In the bead without ripple lines, the subgrain microstructures distribution from the fusion line toward the center of the bead were in the order of cellular, dendritic and equiaxed dendrite. However, in the bead with ripple lines, cellular and dendritic were formed between the fusion boundary and the ripple line. Inaddition, those structures were also observed between the ripple line. Equiaxed dendrites were formed only at the center line region. Cellular and dendritics formed near the ripple line were larger than those formed near the fusion boundary. The cooling rates estimated by the dendrite arm spacing were in the range of 200 to 1150oC/s. Cooling rate was increased with decreasing the power and increasing the welding speed. Mg and Zn segregated at the boundaries of cellulars and dendritics, Mg was segregated more than Zn. The segregation of Mg and Zn decreased with increasing cooling rate. Hardness of the weld metal was lower than that of the base metal in all welding conditions and increased as the cooling rate increased.

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Electrochemical stability of La0.6Sr0.4Co0.2Fe0.8O3-δ as a cathode for SOFC

  • Oh, Mi-Young;Jeong, Yong-Hoon;Oh, Se-Woong
    • Journal of the Korean institute of surface engineering
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    • v.49 no.6
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    • pp.498-506
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    • 2016
  • Electrochemical measurement using a LSCF6428 electrode was performed to estimate the oxygen potential gradient in the electrode layer and a long time stability test was performed by applied potential to learn the overpotential effect on the LSCF6428 electrode. By fitting the observed impedance spectra, it was obtained that the amount of faradic current decreased with distance from cathode/electrolyte interface. Oxygen potential gradient was estimated to occur within 1 um region from the cathode/electrolyte interface at an oxygen partial pressure of 10-1 bar. The segregation of cation rich phases in the LSCF6428 electrode suggests that kinetic decomposition took place. However, impedance response after applying the potential showed no changes in the electrode compared with before applying potential. The obtained results suggest that segregation of a secondary phase in a LSCF6428 cathode is not related to performance degradation for solid oxide fuel cells (SOFCs).

Identification and molecular characterization of a low acid phosphatase 3 (lap3) mutant based on the screening of an Arabidopsis activation-tagged population

  • Jin, Yong-Mei;Won, So-Youn;Jeon, Hye-Sung;Park, Sang-Ryoung;Kim, Min-Kyun
    • Plant Biotechnology Reports
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    • v.5 no.1
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    • pp.45-51
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    • 2011
  • A low acid phosphatase 3 (lap3) mutant was identified and characterized from an Arabidopsis activation-tagged (Weigel) population. The roots of the lap3 plants showed lower acid phosphatase (APase) activity compared to wild-type ones under low-Pi conditions ($10{\mu}M\;Pi$). Plasmid rescue experiments revealed that the activation-tagging vector was inserted into the intergenic region between At4g31540 and At4g31550 in the Arabidopsis genome. The genotypic segregation of the lap3 mutation was tightly linked with the phenotypic segregation of root APase activity in the prgeny of lap3. The transcript level of the At4g31520 (SDA1: SEVERE DEPOLYMERIZATION OF ACTIN 1), located 7.4 kb from the CaMV 35S enhancers in the lap3 mutant, was significantly reduced compared to that in the wild type. It was speculated that cellular actin polymerization may be involved in Pi acquisition in higher plants.

A Case with Emanuel Syndrome Resulting from a Maternal Balanced Translocation

  • Kim, Ja-Hye;Kim, Yoo-Mi;Lee, Beom-Hee;Kim, Ja-Hyung;Seo, Eul-Ju;Yoo, Han-Wook
    • Journal of Genetic Medicine
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    • v.9 no.1
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    • pp.35-37
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    • 2012
  • Emanuel syndrome is a rare genomic syndrome which is characterized by multiple congenital anomalies and developmental disability. This syndrome is related to the presence of the supernumerary derivative chromosome originating from both chromosome 11 and 22. In most cases, one of the parents is a balanced carrier of a translocation. Our case results from 3:1 meiotic segregation of the maternal translocation carrier and is a rare case in Korea confirmed by genetic analysis.

Marker-assisted Genotype Analysis of Bulb Colors in Segregating Populations of Onions (Allium cepa)

  • Kim, Sunggil;Bang, Haejeen;Yoo, Kil-Sun;Pike, Leonard M.
    • Molecules and Cells
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    • v.23 no.2
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    • pp.192-197
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    • 2007
  • Bulb color in onions (Allium cepa) is an important trait whose complex inheritance mechanism involves epistatic interactions among major color-related loci. Recent studies revealed that inactivation of dihydroflavonol 4-reductase (DFR) in the anthocyanin synthesis pathway was responsible for the color differences between yellow and red onions, and two recessive alleles of the anthocyanidin synthase (ANS) gene were responsible for a pink bulb color. Based on mutations in the recessive alleles of these two genes, PCR-based markers for allelic selection were developed. In this study, genotype analysis of onions from segregating populations was carried out using these PCR-based markers. Segregating populations were derived from the cross between yellow and red onions. Five yellow and thirteen pink bulbs from one segregating breeding line were genotyped for the two genes. Four pink bulbs were heterozygous for the DFR gene, which explains the continuous segregation of yellow and pink colors in this line. Most pink onions were homozygous recessive for the ANS gene, except for two heterozygotes. This finding indicated that the homozygous recessive ANS gene was primarily responsible for the pink color in this line. The two pink onions, heterozygous for the ANS gene, were also heterozygous for the DFR gene, which indicated that the pink color was produced by incomplete dominance of a red color gene over that of yellow. One pink line and six other segregating breeding lines were also analyzed. The genotyping results matched perfectly with phenotypic color segregation.

The Effect of Internal Chills on the Solidified Structure and Chemical Segregation (응고조직 및 성분편석에 미치는 내부냉금의 효과)

  • Kim, Myeong-Han;Jo, Hyeon-Nam;Kim, Jeong-Gyeom;Jo, Hyeong-Ho
    • Korean Journal of Materials Research
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    • v.9 no.9
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    • pp.883-889
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    • 1999
  • The pure Al or-(1,2,3wt%)Cu alloy internal chill with 4,6,8,12 and 15mm ø, respectively, was inserted at the center of a graphite mold with the size of 95mm ø$\times$200mm H. The molten metal with the same composition as the internal chill was poured into the mold at the pouring temperature of $750^{\circ}C$ and the cooling rates, solidified structures and chemical segregation were analyzed. The results represented that there was remarkable increased in cooling rate as well as decrease in grain size, secondary dendrite arm spacing and chemical segregation as the ratio of ingot to internal chill diameter was increased to 8. However there was a considerable drop of the internal chill effect when this ratio exceeded 8, resulting from incomplete melting of internal chills. The optimum ratio for the maximum internal chill effect of pure Al and-(1,2,3wt%)Cu allolys was 8 at the given pouring temperature.

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Effects of Phosphorus and in-situ Post-heat Pulse Conditions on Resistance Spot Weldability of High Si DP980 Steel Sheet (고Si DP980강 스폿 용접 특성에 미치는 Phosphorus (P) 및 in-situ 후열처리 펄스 조건의 영향)

  • Choi, Du-Youl
    • Journal of Welding and Joining
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    • v.33 no.6
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    • pp.21-26
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    • 2015
  • Recently, application of UHSS(Ultra High Strength Steels) whose tensile strength is over 1000MPa to car body structure are growing due to great needs for light weighting and improved crash worthiness. However, their poor weldability is one of obstacles to expand selecting to car body. In this study, effect of Phosphorus contents on resistance spot weldability of high elongation DP980 steel whose Si content is over 1% was investigated. The cross tension strength (CTS) was decreased showing partial interface fracture as Phosphorus content increase because of solidification segregation of Phosphorus. In order to improve resistance spot weldability by modification of welding condition, in-situ post-weld heating pulse was introduced after main pulse. The optimum cooling time between main and post pulse and post-pulse current condtion were determined through FEM welding simulation and DOE tests. The CTS was increased about 1.5 time showing plug fracture. The decrease of Phosphorus segregation was found to be a major reason for weld ductility and CTS improvement.