• 한국지반신소재학회논문집
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• 제11권3호
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• pp.37-42
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• 2012

국내에 시공되고 있는 매입말뚝의 충전재는 주로 시멘트 페이스트를 사용하고 있다. 시멘트 페이스트를 사용한 충전재는 현장 시공 시 실 주입량이 지나치게 커서 비효율적이며, 설계기준에 비해 지나친 강도를 발현하여 시멘트사용에 따른 환경성 문제를 지니고 있다. 이에 대한 대안으로 매입말뚝 시공 시 발생하는 굴착토사를 활용하여 적정 고화제를 혼합한 고화토를 충전함으로써 폐기물 처리비용 절약과 친환경적인 고화토 충전공법의 현장적용성을 검토하였다. 일축압축강도 시험과 현장 재하시험 결과를 토대로 고화토와 기존 시멘트 페이스트 주입재의 성능을 비교하고 설계기준에 적합한지 여부를 검토하였다. 그 결과 고화토 충전재는 시멘트 페이스트 충전재와 유사한 성능을 나타내며 설계기준에도 적합하여 매입말뚝 충전재로서 고화토의 적용성을 확인하였다.

• 콘크리트학회논문집
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• 제17권6호
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• pp.1019-1024
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• 2005

4종의 콘크리트용 화학 혼화제(리그노 술폰산, 나프탈렌 술폰산 축합물, 멜라민 술폰산 축합물, 폴리카복실레이트계)가 시멘트 수화 반응에 미치는 영향성을 평가하고자, 각각의 고유동화제들이 적용된 시멘트페이스트 경화 시편을 활용해 X-선 회절분석(XRD), 주사전자현미경(SEM), 그리고 열분석(DSC) 분석을 실시하였다. 고유동화제를 사용하지 않은 plain과 비교해 고유동화제를 첨가한 시편의 경우, 고유동화제의 종류 및 사용량에 관계없이 3일까지 수화 반응은 지연되었으나, 이후 재령에서는 고유동화제를 사용하지 않은 plain과 유사한 경향성을 보였다. 특히 고유동화제 사용량이 높아질 경우 수화 지연성은 커졌고, 리그노 술폰산, 폴리카복실레이트, 멜라민, 나프탈렌 술폰산 축합물 순으로 시멘트페이스트 초기 수화를 지연시켰다. 그러나, 이들 고유동화제를 사용할 경우, 시멘트의 분산성을 개선시켜 수화 생성물이 보다 치밀하고 균일했다.

• 한국건축시공학회지
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• 제16권2호
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• pp.185-192
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• 2016

The semi-adiabatic calorimetry technique is a robust and easy technique that can be used to measure the temperature rise of concrete. This method is often used for investigating the maturity of concrete, as well as to predict maximum temperature rise of mass concrete using various heat loss compensating models. Semi-adiabatic calorimetry can also be used for predicting setting time of concrete. However, it has seldom been used to investigate the hydration characteristics of various cement paste samples. In this research, semi-adiabatic calorimetry and X-ray diffraction methods were used to investigate the hydration characteristics of 3 different ASTM type I Portland cements. First derivative of temperature rise (dT/dt) curve was used to isolate individual peaks. Based on the results of the experiments, a combination of dT/dt curve with XRD could be used to successfully identify hydration at a specific time period, showing its potential to be used as an alternative tool for hydration studies of cement-based materials.

• 한국구조물진단유지관리공학회 논문집
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• 제5권4호
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• pp.121-129
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• 2001

The semi-adiabatic temperature rise and the losses of temperature of cement paste, mortar and concrete were measured by an apparatus of semi-adiabatic temperature. Heat of hydration was measured by a conduction calorimeter and adiabatic temperature rise of concrete was measured by an adiabatic calorimeter. The derived equation which can assume the adiabatic temperature was proposed by measuring the semi-adiabatic temperature of concrete. The maximum adiabatic temperature rise of concrete obtained by the derived equation of adiabatic temperature, $T_{ad}(t)=T_{sad}(t)+T_{dis}(t)$, showed $55^{\circ}C$ approximately and it had good relation with the other one obtained by the heat of hydration of cement paste and with maximum value which was measured by the adiabatic calorimeter. The adiabatic temperature rise obtained by derived equation was a different information in comparison with the value obtained by adiabatic temperature rise equations by Hell and et. al. in early age, but it showed similar tendencies with the other one according to elapsed time. Adiabatic temperature rise of lich mix concrete with highly cement content was predicted. The adiabatic temperature rise of cement paste and mortar obtained by derived equation from us showed comparatively matching results to compared with that of obtained by adiabatic temperature equation from concrete standard specification.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2020년도 가을 학술논문 발표대회
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• pp.85-86
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• 2020

With the increasing importance of environmental issues, the cementitious materials with self-cleaning or photocatalytic properties by introducing TiO₂ materials have been gaining a lot of attention. In this work, the influence of TiO₂ particle size and structure on its photocatalytic effect in cement paste was investigated. The degradation of methylene blue solution was used as the parameter for evaluating the photocatalytic effect of micro-TiO2 (m-TiO₂), nano-TiO2 (n-TiO₂), and TiO₂ nanotube (TNT). Moreover, the effect of these three TiO₂ materials on the cement hydration products was characterized by X-ray diffraction (XRD) and thermgravimetric analysis (TG). According to the results, it can be found that all of the TiO₂ materials promoted the formation of hydration products, especially TNT. On the other hand, the m-TiO₂ exhibited a better photocatalytic effect compared to other materials.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1991년도 가을 학술발표회 논문집
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• pp.11-14
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• 1991

Apparent diffusion coefficients of Cl-ions through hardened cement paste(HCP), which were partly substituted blending materials, were determined. Also, pore solution was extracted from HCP which were immersed in NaCl solution, and Cl- concentration of the solution were analyzed. Partly substitution of pozzolanic materials considerably reduced the diffusion rate for Cl-ions and Cl- concentration of pore solution. Binding capacity of Cl- is related to the content of Al2O3 and pozzolanic reactivity.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2023년도 가을학술발표대회논문집
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• pp.87-88
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• 2023

In this study, as a fundamental research to establish the mechanism of carbonate precipitation, we compared and evaluated the mechanical properties of cement paste under different carbonation conditions. The research results showed that as the CO₂ concentration increased, the compressive strength also increased.

• 한국건축시공학회지
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• 제17권3호
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• pp.269-277
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• 2017

본 연구에서는 원전 콘크리트로부터 분리된 페이스트 미분말을 이용 방사성폐기물 처분용 고화재로 활용하기 위하여 기초 특성을 검토하고자 하였다. 실험 결과 수화반응한 페이스트는 시멘트보다 비중이 낮고 수화회복을 위한 소성과정에서 온도증가에 따라 비중이 다르게 나타나 그에 따른 부피도 고려되어야 할 것으로 판단된다. 수화회복을 위한 소성온도에서 압축강도가 가장 우수한 온도조건은 $600^{\circ}C$로 나타났으며, $700^{\circ}C$ 이상에서는 CaO의 생성량이 과도하여 높은 수화열, 유동성 저하 및 낮은 강도가 발현되는 것을 확인하였다. 따라서 본 연구 범위 내에서 고화재로 활용 가능한 적정 수화회복 온도는 $600^{\circ}C$로 판단되며 폐콘크리트 페이스트가 적정한 열처리를 거치는 경우 방사성 폐기물 고화재료로서 활용될 수 있는 가능성을 보였다는 점에 의의를 둔다.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1999년도 학회창립 10주년 기념 1999년도 가을 학술발표회 논문집
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• pp.85-88
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• 1999

We tested the limestone powder as a filler powder for the effective use of slag cement. Hydration process were investigated by measuring the thermal differential analysis(DTA), compressive strength, XRD patterns, calorimeter of slag cement-limestone powder paste prepared by mixing limestone powder-slag cement. The results obtained in this study, there were no significant difference between the cases of adding up to 5% limestone powder, but the reaction time was accelerated. Also the compressive strength was increased for adding up to 5% limestone powder. The min hydrated paste products were Ca(OH)2 and calcium silicate hydrates. In the case of mixed limestone powder peak appear tricalcium carboaluminate hydrate in the sample of 7 days hydration.

• 콘크리트학회논문집
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• 제17권5호
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• pp.853-856
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• 2005

A low water/cement ratio leads to autogenous shrinkage of cement paste at an early age. This autogenous shrinkage is related to the change of relative humidity in the pore structure that is formed during the hydration process. The relationship between autogenous shrinkage and relative humidity change are relatively well defined today, but the effects of temperature on autogenous shrinkage, relative humidity, and pore structures have been studied less systematically. This study focused on correlating alterations of these properties of cement paste hydrated at constant temperatures of 20, 40, and $60^{\circ}C$. The test results clearly indicate that increasing curing temperature resulted in increased porosity, particularly for pores between 5 to 50 nm as measured by MIP, and increased autogenous shrinkages, as a consequence of a reduction of relative humidity at early ages.