• Journal of the Korean Crystal Growth and Crystal Technology
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• v.29 no.2
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• pp.61-70
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• 2019

Geopolymer is an eco-friendly construction material that has various advantages such as reduced $CO_2$ emission, fire resistance and low thermal conductivity compared to cement. However, it has not been many studies on the thermal behavior of the surface of the geopolymer panel when flame is applied to the surface. In this study, surface characteristics of hardened geopolymer on flame exposure was investigated to observe its characteristics as heat-resistant architectural materials. External structure changes and crack due to the heat shock were not observed during the exposure on flame. According to the residue of calcite and halo pattern of aluminosilicate gel, decarboxylation and dehydration were extremely limited to the surface and, therefore, it is thought that durability of hardened geopolymer was sustained. Gehlenite and calcium silicate portion was inversely proportional to quartz and calcite and significantly directly proportional to BFS replacement ratio. Microstructure changes due to the thermal shock caused decarboxylation and dehydration of crystallization and it was developed the pore and new crystalline phase like calcium silicate and gehlenite. It is thought that those crystalline phase worked as a densification and strengthening mechanism on geopolymer panel surface.

• Journal of the Korean GEO-environmental Society
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• v.24 no.1
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• pp.15-23
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• 2023

The grouting method is a method of construction for the purpose of waterproofing and reinforcing soft ground. When grout is injected into the ground, there are various types of penetration and diffusion of grout depending on the shape of the ground, the size of soil, the porosity, and the presence or absence of groundwater. the current situation. Therefore, in this study, to investigate the penetration performance of the grouting to conductive material, laboratory tests were performed on the addition of the conductive material. In the injection test, 0%, 3%, and 5% of the mixed water were added as conductive materials to the grout, and the original ground condition was composed of various types of ground composed of gravel and silica sand. Conductive grout is injected by pressure into the model ground using a dedicated injection device, and the injection time (t), pressure (p), flow rate (v) and injection amount (q) are measured, and the hardened body injected in the model ground is collected. Penetration performance was evaluated. In the results of the grout injection experiment, the amount of conductive material used and the grout injection rate showed an inverse relationship, and it was confirmed that the penetration pattern was changed according to the size of the soil particles in the model ground. The grout containing the conductive material has relatively good penetration into the ground and excellent strength and durability of the hardened body, so it was judged that it could be used as an additive for measuring the penetration range of the grout.

• Journal of the Korea Institute of Building Construction
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• v.16 no.3
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• pp.279-288
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• 2016

The fundamental performance of any construction material should cover at least two phases: safety and serviceability. Safety commonly represents adequate strength, while serviceability encompasses the control of cracking and deflections at service loads. With respect to rapid hydraulic binders as a construction material, the above two phases should also be considered. Recent research on rapid cooling ladle furnace slag (RC-LFS) has drawn much attention, particularly given that it shows remarkable rapid hydraulic ability to pulverize to a fineness of $6,300cm^2/g$. This industrial byproduct could contribute to developing the sustainability of the rapidly hardening cementitious material system. This paper aims to expand upon the applicability of an RC-LFS-based binder that is composed of two parts. It also seeks to illustrate the engineering performance of an RC-LFS-based hybrid fiber-reinforced composite and to increase the strength of the RC-LFS-based composite. Each step of this experiment followed ASTM standards. The engineering performance, in both fresh state and hardening state, was tested and discussed in this paper. According to the experimental results for fresh concrete, the air content increased following the addition of polypropylene fiber. For hardened concrete, the toughness and strength improved following the addition of a hybrid fiber. The hybrid fiber mixture, which contains 0.75% of steel fiber and 0.25% of polypropylene fiber, shows even better engineering performance than other mixtures.

• Journal of the Korean Society of Hazard Mitigation
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• v.2 no.1 s.4
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• pp.143-152
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• 2002

The objectives of this paper were to obtain the fundamental data to analyze the causes of deterioration of 39 freeway concrete viaducts in Seoul metropolitan area. To investigate the degree of concrete deterioration, carbonation depth, soluble chloride concentration in hardened concrete and half-cell potentials of reinforcement were measured. The number of structures which carbonation depth penetrates to reinforcement was 25% of total. The model of carbonation .ate was induced to 3.92 $\sqrt{t}$, which was 5% faster than 3.727 $\sqrt{t}$ assumed 60% water-cement ratio, R=1 in that of kishitani. After measuring chloride concentration in concrete, it was concluded that about 24% of all readings on samples from concrete exceed the critical content to minimize the risk of chloride-induced corrosion. About 31% of the freeway viaducts structures had a value lower than -350mV(vs. CSE), so it could conclude that the excessive chloride concentration was the major cause of reinforcement corrosion. Among the structures which measured half-cell potentials less than -350mV, about 50% exceeds the maximum acceptable limit of chloride concentration.

• Resources Recycling
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• v.15 no.2 s.70
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• pp.10-17
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• 2006

The purpose of this study was to evaluate the effects of blast-furnace slag on strength development and durability of latex-modified concrete (LMC) and ordinary portland cement concrete as slag contents. Main experimental variables were performed latex contents (0%, 10%, 15%) and slag contents (0%, 30%). The compressive and flexural strengths, chloride-ion rapid permeability and chemical attacks resistance were measured to analyze the characteristic of the developed LMC and BS-LMC(latex-modified concrete added blast-furnace slag) on hardened concrete. The test results showed that compressive and flexural strength of BS-LMC increased as the slag contents increased from 0% to 30% at the long term of curing. It considers blast furnace slag used when latex content was up to 10%. The permeability resistance of BS-LMC(latex 10%, blast 30%) was extremely good at the curing time 90 days. Also. the effects of added blast furnace slag on OPC and LMC were increased on the permeability and chemical attacks resistance.

• Journal of the Korean Association of Oral and Maxillofacial Surgeons
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• v.26 no.6
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• pp.672-676
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• 2000

One of the current treatment methods for chronic osteomyelitis is removal of the infected and necrotic tissue to reduce the bacterial concentration as much as possible. This is performed concomitantly with antibiotic therapy. Chronic osteomyelitis(C.O.) implies chronic ischemia of the diseased bone. Thus, the treatment for C.O. requires high systemic level of antibiotics. In some cases, however, inherent undesirable adverse effects(for example, nephrotoxicity, ototoxicity, and others) may render this course of treatment difficult. Knowing that residual monomers are released from hardened bone cement, installation of antibiotic-impregnated PMMA(polymethyl-methacrylate) beads in situ have been one of treatment methods of C.O. When introduced into the wound, they established an exceedingly high level of local antibiotics for prolonged period without high systemic level of antibiotics. We experienced favorable results with vancomycin-impregnated PMMA beads for the treatment of C.O. of the mandible. So, we report it with literature reviews.

• Fire Science and Engineering
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• v.18 no.3
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• pp.51-56
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• 2004

A fire outbreak in a reinforcement concrete structure looses the organism by the different contraction and expansion of hardened cement pastes and aggregate, and causes cracks by thermal stress, leading to the deterioration of the durability. So concrete reinforcement structure is damaged partial or whole structure system. Therefore diagnosis of deterioration is needed based on mechanism of fire deterioration in general concrete structures. Fundamental information and data on the properties of concrete exposed to high temperature are necessary for accurate diagnosis of deterioration. In this study, it was presented data for the accurate diagnosis and selection of repair and reinforcement system for the deteriorated concrete heated highly, various concrete such as standard design compressive strength, fine aggregate and admixture were exposed to a high temperature environment. And fundamental data were measured engineering properties such as explosive spatting, ultrasonic pulse velocity and compressive strength.

• International Journal of Concrete Structures and Materials
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• v.8 no.3
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• pp.213-228
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• 2014

Alkali-activated binder (AAB) is recently being considered as a sustainable alternative to portland cement (PC) due to its low carbon dioxide emission and diversion of industrial wastes and by-products such as fly ash and slag from landfills. In order to comprehend the behavior of AAB, detailed knowledge on relations between microstructure and mechanical properties are important. To address the issue, a new approach to characterize hardened pastes of AAB containing fly ash as well as those containing fly ash and slag was adopted using scanning electron microscopy (SEM) and energy dispersive X-ray spectra microanalyses. The volume stoichiometries of the alkali activation reactions were used to estimate the quantities of the sodium aluminosilicate (N-A-S-H) and calcium silicate hydrate (CSH) produced by these reactions. The 3D plots of Si/Al, Na/Al and Ca/Si atom ratios given by the microanalyses were compared with the estimated quantities of CSH(S) to successfully determine the unique chemical compositions of the N-A-S-H and CSH(S) for ten different AAB at three different curing temperatures using a constrained nonlinear least squares optimization formulation by general algebraic modeling system. The results show that the theoretical and experimental quantities of N-A-S-H and CSH(S) were in close agreement with each other. The $R^2$ values were 0.99 for both alkali-activated fly ash and alkali-activated slag binders.

• Journal of the Korean Ceramic Society
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• v.31 no.5
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• pp.505-512
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• 1994

It has been reported that a biocement obtained by mixing CaO-SiO2-P2O5 glass powder and ammonium phosphate solution has biocompatibility as well as high strength. However, the compositional dependence on its hardening and hydroxyapatite formation phenomena has not been studied. Therefore, the main objective of this work is to study the effects of P2O5, MgO in CaO-SiO2 system glass on the hardening and hydroxyapatite formation. When more than 50 mole% of CaO containing CaO-SiO2 glasses was reacted with ammonium phosphate solution, CaNH4PO4.H2O crystal was formed, but the glass with less than 50 mol% of CaO formed (NH4)2HPO4 and NH4H2PO4 crystals which are derived from ammonium phosphate solution without reacting with the glasses. As the amount of P2O5 in CaO-SiO2-P2O5 glass system was increased, the formation of CaNH4PO4.H2O crystal was enhanced. When those hardened samples were reacted with tris-buffer solution, hydroxyapatite was obtained only for the sample with CaNH4PO4.H2O. While the substitution of MgO for CaO decreased the formation of CaNH4PO4.H2O crystal. MgNH4PO4.H2O crystla was formed in high MgO containing glass, which did not react with tris-buffer solution.

• Land and Housing Review
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• v.7 no.4
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• pp.281-289
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• 2016

Structural experiment result showed that PHC(d=600mm) Pile used as a common compression member could resist 83.6 ~ 91.6 tonf of ultimate tension force, if the adhesion of P.C. bar of PHC pile to the concrete foundation is strengthened. Considering a proper safety factor to ultimate tension strength, PHC pile can substitute the anti-floating anchor, or reduce the number of anchors. For this purpose, pullout resistance behavior of a Bored pile embedded in real ground as well as structural tension strength of PHC pile must be evaluated. This study performed the static pullout tests to evaluate the pullout behavior of bored pile, and compared the test results with design value of side resistance. To evaluate the pullout resistance easily, static pullout test results were compared with dynamic loading test results using PDA. As a result, cement paste of the bored pile was hardened which is after 15 days, LH side resistance design value corresponded well to the Static pullout test results, also to the side resistance evaluated by dynamic loading test.